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Selective transport of cadmium(II) through hollow fiber-supported liquid membrane microextraction using diaza-18-crown-6 in ionic liquids as carrier

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Abstract

A hollow fiber-supported liquid membrane microextraction (HF-SLME) system using diaza-18-crown-6 (DA18C6) in ionic liquid (IL) 1-butyl-3-methylimidazolium hexafluorophosphate ([C4MIM]PF6) as an efficient carrier for the selective transport of cadmium(II) is described. The Cd(II) is ion paired with chlorine ion as a suitable counter into the membrane phase and then complexed with DA18C6; sodium thiosulfate (Na2S2O3) is injected in the lumen of membrane as an acceptor phase to trap the Cd(II) into the acceptor phase. The influence of various experimental parameters in the extraction procedure is discussed using a three-level Box–Behnken experimental design with three factors to optimize. Under the optimum conditions, the selectivity and efficiency of Cd(II) transport from an aqueous sample containing different mixtures of Co2+, Ni2+, Fe3+, Cr3+, Mn2+, and Cd2+ are investigated. The enrichment factor of Cd2+ is 172, the limit of detection is 0.13 ng L−1, and the relative standard deviation is 5.1 %. The method has been successfully applied to the determination of Cd(II) in food and cosmetic samples.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Nos. 31470434, 21406090, 21206059 and 21576124), the Special Financial Grant from the China Postdoctoral Science Foundation (2015T80510), and the Science Foundation of Jiangsu Entry-exit Inspection Quarantine Bureau of China (Nos. 2015KJ27 and 2015KJ28).

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Authors and Affiliations

  1. School of Municipal and Environmental Engineering, Henan University of Urban Construction, Pingdingshan, 467036, People’s Republic of China

    Yanli Mao

  2. School of the Environment, Jiangsu University, Zhenjiang, 212013, People’s Republic of China

    Hui Chen

  3. School of Food and Biological Engineering, Jiangsu University, Zhenjiang, 212013, People’s Republic of China

    Juan Han

  4. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, People’s Republic of China

    Yun Wang, Xu Tang, Liang Ni & Lei Wang

Authors
  1. Yanli Mao
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  2. Hui Chen
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  3. Juan Han
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  4. Yun Wang
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  5. Xu Tang
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  6. Liang Ni
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  7. Lei Wang
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Corresponding authors

Correspondence to Juan Han or Yun Wang.

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Mao, Y., Chen, H., Han, J. et al. Selective transport of cadmium(II) through hollow fiber-supported liquid membrane microextraction using diaza-18-crown-6 in ionic liquids as carrier. J IRAN CHEM SOC 13, 403–410 (2016). https://doi.org/10.1007/s13738-015-0767-9

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  • DOI: https://doi.org/10.1007/s13738-015-0767-9

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