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Synthesis, characterization, and investigations of some luminescent and catalytic properties of coordination polymers assembled from 5-(Pyridin-3-yl)isophthalic acid

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Abstract

The reactions of a semirigid carboxylic ligand 5-(Pyridin-3-yl)isophthalic acid(H2pyip) with Mn(CH3COO)2/Zn(NO3)2/Pb(NO3)2 afforded three new complexes: [Mn(pyip)(H2O)2]n(1), [Zn(pyip)(H2O)2]n(2), and [Pb(pyip)]n(3). Their structures have been determined by single-crystal X-ray diffraction analyses and further characterized by elemental analyses, IR spectra, powder X-ray diffraction (PXRD), and thermogravimetric (TG) analyses. X-ray structure analysis reveals that complexes 1-2 showed identical 3D supramolecular architecture that just connect different metal centers. They all crystallize in hexagonal space group P6(5) and exhibit the same coordination mode. One of the H2pyip adopts bidentate chelate coordination mode, and the other coordinate carboxylate oxygen atom adopts the single dentate-bridging mode. Complex 3 adopts different coordination modes crystallized in monoclinic space group P2(1)/c compared to 1-2, combined bidentate chelate and chelating–bridging tetradentate coordination modes. A noticeable point in this paper is that compounds 1-3 exhibit preferable catalytic properties on degradation of Rhodamine B (RhB). Moreover, the luminescent properties were investigated.

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Acknowledgments

The authors thank the National Natural Science Foundation of China (21267003), PR China, the Natural Science Foundation of Guangxi (053020), P.R. China, and Guangxi University for Nationalities and Chemical and Biological Transformation Process New Technology of Guangxi Key Laboratory of Colleges and Universities.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning, 530008, People’s Republic of China

    Kai-Fei Wu, Fen Jiang, Xian-Li Bai, Shao-Yin Mo, Gui-Fang Qin & Yu Feng

  2. Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, Nanning, 530008, China

    Kai-Fei Wu, Fen Jiang, Xian-Li Bai, Shao-Yin Mo, Gui-Fang Qin & Yu Feng

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  1. Kai-Fei Wu
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Correspondence to Yu Feng.

Supplementary material

Supplementary material

Crystallographic data for the structures reported here have been deposited with CCDC (Deposition No. CCDC-1008027 (1), No. CCDC-1008030 (2), No. CCDC-1008028 (3)). These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html or from CCDC, 12 Union Road, Cambridge CB2 1EZ, UK, E-mail: deposit@ccdc.cam.ac.uk.

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Wu, KF., Jiang, F., Bai, XL. et al. Synthesis, characterization, and investigations of some luminescent and catalytic properties of coordination polymers assembled from 5-(Pyridin-3-yl)isophthalic acid. J IRAN CHEM SOC 12, 2149–2159 (2015). https://doi.org/10.1007/s13738-015-0692-y

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