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Synthesis of sodium dodecyl sulfate-supported nanocomposite cation exchanger: removal and recovery of Cu2+ from synthetic, pharmaceutical and alloy samples

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Abstract

A new surfactant-based nanocomposite cation exchanger, sodium dodecyl sulfate–Th(IV) tungstate (SDS–TT) was prepared by the sol–gel method. The SDS–TT was characterized by FTIR, XRD, TGA, SEM, EDS and TEM. The distribution studies for various metal ions on SDS–TT were performed in different acidic mediums. On the basis of distribution coefficient values, SDS–TT was found to be selective for Cu2+ metal ion. SDS–TT was successfully used for the quantitative separation of Cu2+ from the synthetic mixture, pharmaceutical formulation and brass sample. The regeneration studies were performed which showed a decrease in the recovery of Cu2+ from 88 to 70 % after seven consecutive cycles.

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Acknowledgments

The authors extend their appreciation to the Deanship of Scientific Research at King Saud University for funding the work through the research group project No. RGP-VPP-130.

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Authors and Affiliations

  1. Department of Chemistry, College of Science, Bld#5, King Saud University, Riyadh, Kingdom of Saudi Arabia

    Mu. Naushad, Zeid Abdullah ALOthman, Mohammad Mezbaul Alam & Gaber E. Eldesoky

  2. Actinide Coordination Chemistry Group, Quantum Beam Science Centre, Japan Atomic Energy Agency (SPring-8), Hyogo, 679-5148, Japan

    Md. Rabiul Awual

  3. Department of Chemistry, Purushottam Institute of Engineering and Technology, Rourkela, 770034, Orissa, India

    Mahamudur Islam

Authors
  1. Mu. Naushad
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  2. Zeid Abdullah ALOthman
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  3. Mohammad Mezbaul Alam
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  4. Md. Rabiul Awual
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  5. Gaber E. Eldesoky
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  6. Mahamudur Islam
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Correspondence to Mu. Naushad.

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Naushad, M., ALOthman, Z.A., Alam, M.M. et al. Synthesis of sodium dodecyl sulfate-supported nanocomposite cation exchanger: removal and recovery of Cu2+ from synthetic, pharmaceutical and alloy samples. J IRAN CHEM SOC 12, 1677–1686 (2015). https://doi.org/10.1007/s13738-015-0642-8

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  • DOI: https://doi.org/10.1007/s13738-015-0642-8

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