Abstract
In this work, molecular self-assembled monolayers (SAM) of 2-(2,3-dihydroxy phenyl) benzothiazole (HPB) on gold electrode are prepared for the first time and described by cyclic voltammetry (CV), electrochemical impedance spectroscopy, scanning electron microscopy (SEM) and quartz crystal microbalance techniques. The redox properties of the modified electrode were investigated by CV at various scan rates, and the apparent charge transfer rate constant (k s) and transfer coefficient (α) were calculated for HPB-SAM/Au. Then, electro oxidation of dopamine (DA) on a HPB-SAM-modified gold electrode has been studied by cyclic voltammetry, chronoamperometry and differential pulse voltammetry (DPV). The mediated oxidation of DA at the modified electrode in CV occurs at a potential of about 180 mV less positive than that of the unmodified gold electrode. The values of electron transfer coefficients (α), catalytic rate constant (k) and diffusion coefficient (D) were calculated for DA, using electrochemical methods. DPV exhibited a linear dynamic range over the concentration range of 0.1–500.0 µM and a detection limit (3 s) of 0.03 µM for DA in pH 7.0.
Similar content being viewed by others
References
A. Ulman, Chem. Rev. 96, 1553 (1996)
R.G. Nuzzo, D.L. Allara, J. Am. Chem. Soc. 105, 4481–4483 (1983)
J.C. Love, L.A. Estroff, J.K. Kriebel, R.G. Nuzzo, G.M. Whitesides, Chem. Rev. 105, 1103 (2005)
S.K. Arya, P. Pandey, S.P. Singh, M. Datta, B.D. Malhotra, Analyst 132, 1005 (2007)
P.G. Lustemberg, C. Vericat, G.A. Benitez, M.E. Vela, N. Tognalli, A. Fainstein, M.L Martiarena, R.C. Salvarezza, J. Phys. Chem. C 112, 11394 (2008)
Y. Zhang, J. Xia, X. Feng, B. Tong, J. Shi, J. Zhi, Y. Dong, Y. Wei, Sens. Actuat. B 1616, 587 (2012)
J.J. Gooding, D.B. Hibbert, Trends Anal. Chem. 18, 525 (1999)
E. Katz, A.F. Buckmann, I. Willner, J. Am. Chem. Soc. 123, 10725 (2001)
T. Wink, S.J. van Zuilen, A. Bult, W.P. van Bennekom, Analyst 122, 43R (1997)
R. K. Shervedani, R Yaghoubi, F. Bagherizadeh, J Iran Chem Soc. 6, 104 (2009)
D. Mandler, I. Turyan, Electroanalysis 8, 207 (1996)
V. Ganesh, S. Kumar Pal, S. Kumar, V. Lakshminarayanan, Electrochim. Acta 52, 2987 (2007)
R.K. Shervedani, A. Farahbakhsh, M. Bagherzadeh, Anal. Chim. Acta 587, 254 (2007)
A. John Jeevagan, S. Abraham John, Electrochim. Acta 77, 189 (2012)
R. Karimi Shervedani, Z. Akrami, H. Sabzyan, J. Phys. Chem. C 115, 8042 (2011)
R. Karimi Shervedani, F. Yaghoobi, A. Hatefi-Mehrjardi, S. M. Siadat-Barzoki, Electrochim. Acta 53, 4185 (2008)
X.L. Su, Y. Li, Biosens. Bioelectron. 19, 563 (2004)
R.M. Wightman, L.J. May, A.C. Michael, Anal. Chem. 60, 769A (1988)
H.R. Zare, N. Nasirizadeh, J. Iran Chem. Soc. 8, 55 (2011)
S. Thiagarajan, S.M. Chen, Talanta 74, 212 (2007)
U. Oesch, J. Janata, Electrochim. Acta 28, 1237 (1983)
S.E. Creager, L.A. Hockett, G.K. Rowe, Langmuir 8, 854 (1992)
A.J. Bard, L.R. Faulkner, Electrochemical Methods: Fundamentals and Applications, 2nd edn (Wiley, New York, 2001)
E. Laviron, J. Electroanal. Chem. 101, 19 (1979)
Z. Galus, Fundamentals of Electrochemical Analysis (Ellis Horwood, NewYork, 1976)
L. Codognoto, E. Winter, J.A.R. Paschoal, H.B. Suffredini, M.F. Cabral, S.A.S. Machado, S. Rath, Talanta 72, 427 (2007)
T. Liu, M. Li, Q. Li, Talanta 63, 1053 (2004)
M. Mazloum-Ardakani, H. Beitollahi, M. Kazem Amini, F. Mirkhalaf, B.B.F Mirjalili, A. Akbari, Analyst 136, 1965 (2011)
Q. Wang, D. Dong, N. Li, Bioelectrochemistry 54, 169 (2001)
M. Mazloum-Ardakani, Z. Taleat, H. Beitollahi, H. Naeimi, Anal. Methods 2, 149 (2010)
X. Zhou, N. Zheng, S. Hou, X. Li, Z. Yuan, J. Electroanal. Chem. 642, 30 (2010)
Acknowledgments
The authors wish to thank the Yazd University Research Council, IUT Research Council and Excellence in Sensors for financial support of this research.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mazloum-Ardakani, M., Dehghani-Firouzabadi, A., Benvidi, A. et al. Characterization of new molecular self-assembled monolayers on gold electrode by QCM, EIS, SEM and CV techniques: application for electrocatalytic determination of dopamine in the presence of acetaminophen. J IRAN CHEM SOC 12, 677–685 (2015). https://doi.org/10.1007/s13738-014-0526-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13738-014-0526-3