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Catalytic wet air oxidation of aromatic compounds: degradation in molybdovanadophosphoric polyoxometalates micellar system under room temperature conditions

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Abstract

Catalytic wet air oxidation process, enable to eliminate organic pollutants with non toxic by-product formation, was investigated in micellar system under room condition. Degradation of a series of aromatic compounds, including aromatic hydrocarbons, benzyl alcohol, benzaldehyde, benzoic acid, and some N-containing compounds was carried out based on molybdovanadophosphoric polyoxometalates [(C16H33)N(CH3)3]3+x PV x Mo12−x O40 (x = 1, 2, 3) catalysts and surfactants. Outstanding results (60–96 % degradation efficiencies) were achieved for most of the tested substrates. And the POM micellar catalysts have an excellent stability and can be used as heterogeneous catalysts for about six times.

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Authors and Affiliations

  1. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094, China

    Jie Zhu, Peng-cheng Wang & Ming Lu

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  1. Jie Zhu
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  2. Peng-cheng Wang
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  3. Ming Lu
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Correspondence to Ming Lu.

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Zhu, J., Wang, Pc. & Lu, M. Catalytic wet air oxidation of aromatic compounds: degradation in molybdovanadophosphoric polyoxometalates micellar system under room temperature conditions. J IRAN CHEM SOC 10, 123–129 (2013). https://doi.org/10.1007/s13738-012-0132-1

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  • DOI: https://doi.org/10.1007/s13738-012-0132-1

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