Abstract
Homogeneous-reinforced (HR) polyvinyl chloride (PVC) hollow fiber membranes consisting of coating and matrix layers were fabricated via coating process. The mixtures of polymer solutions were uniformly coated on the homogeneous PVC matrix membrane which was prepared by melt-spinning method. The influence of various pre-wetting solutions on interface structure and performance of HR membranes were investigated. The results showed that the HRPVC membranes had a dense and smooth outer surface with no obvious pores. A dense interface was formed in the HR membrane between the coating layer and the matrix membrane without pre-wetting process. Due to the filling of the pores of the outer edge of the matrix membrane by pre-wet solutions, the HRPVC hollow fiber membranes formed porous interface in the coating process. The pure water flux of the pre-wet HR membranes was higher than that of the un-pre-wet HR membrane, but lower than that of the matrix membrane. The optimum properties of HRPVC membranes were obtained as the ethanol weight fraction reached 60 wt% in the pre-wet solutions. In the optimum pre-wetting conditions, the tensile strength of HRPVC hollow fiber membranes was 9.5 MPa, while the elongation-at-break value was 97.4 %.
Similar content being viewed by others
References
Ding XL, Cao YM, Zhao HY, Wang LN, Yuan Q (2008) Fabrication of high performance matrimid/polysulfone dual-layer hollow fiber membranes for O2/N2 separation. J Membr Sci 323:352–361
Yang Q, Wang KY, Chung TS (2009) Dual-layer hollow fibers with enhanced flux as novel forward osmosis membranes for water production. Environ Sci Technol 43:2800–2805
Setiawan L, Wang R, Shi L, Li K, Fane AG (2012) Novel dual-layer hollow fiber membranes applied for forward osmosis process. J Membr Sci 421–422:238–246
Hosseini SS, Peng N, Chung TS (2010) Gas separation membranes developed through integration of polymer blending and dual-layer hollow fiber spinning process for hydrogen and natural gas enrichments. J Membr Sci 349:156–166
Wang Y, Goh SH, Chung TS, Na P (2009) Polyamide-imide/polyetherimide dual-layer hollow fiber membranes for pervaporation dehydration of C1-C4 alcohols. J Membr Sci 326:222–233
Bonyadi S, Chung TS (2007) Flux enhancement in membrane distillation by fabrication of dual layer hydrophilic-hydrophobic hollow fiber for membranes. J Membr Sci 306:134–146
Wang P, Teoh MM, Chung TS (2011) Morphological architecture of dual-layer hollow fiber for membrane distillation with higher desalination performance. Water Res 45:5489–5500
Sun SP, Wang KY, Peng N, Hatton TA, Chung TS (2010) Novel polyamide-imide/cellulose acetate dual-layer hollow fiber membranes for nanofiltration. J Membr Sci 363:232–242
Li Y, Chung TS (2008) Exploration of highly sulfonated polyethersulfone (SPES) as a membrane material with the aid of dual-layer hollow fiber fabrication technology for protein separation. J Membr Sci 309:45–55
Rajabzadeh S, Liang C, Ohmukai Y, Maruyama T, Matsuyama H (2012) Effect of additives on the morphology and properties of poly(vinylidene fluoride) blend hollow fiber membrane prepared by the thermally induced phase separation method. J Membr Sci 423–424:189–194
Liu HL, Xiao CF, Hu XY, Liu MT (2013) Post-treatment effect on morphology and performance of polyurethane-based hollow fiber membranes through melt-spinning method. J Membr Sci 427:326–335
Zhang XL, Xiao CF, Hu XY, Bai QQ (2013) Preparation and properties of homogeneous-reinforced polyvinylidene fluoride hollow fiber membrane. Appl Surf Sci 264:801–810
Huang QL, Xiao CF, Hu XY, An SL (2011) Fabrication and properties of poly(tetrafluoroethylene-co-hexafluoropropylene) hollow fiber membranes. J Mater Chem 21:16510–16516
Liu HL, Xiao CF, Huang QL, Hu XY (2013) Structure design and performance study on homogeneous-reinforced polyvinyl chloride hollow fiber membranes. Desalination 331:35–45
Chen HZ, Xiao YC, Chung TS (2011) Multi-layer composite hollow fiber membranes derived from poly(ethylene glycol) (PEG) containing hybrid materials for CO2/N2 separation. J Membr Sci 381:211–220
Bikson B, Miller JE, Nelson JK (1989) Permeable membranes for enhanced gas separation. US Patent 4881954A
Blume I, Pinnau I (1990) Composite membrane, method of preparation and use. US Patent 4963165A
Chung TS, Kafchinski ER, Kohn RS, Foley P, Straff RS (1994) Fabrication of composite hollow fibers for air separation. J Appl Polym Sci 53:701–708
Zhang XZ, Chen YS, Konsowa AH, Zhu XS, Crittenden JC (2009) Evaluation of an innovative polyvinyl chloride (PVC) ultrafiltration membrane for wastewater treatment. Sep Purif Technol 70:71–78
Guo XY, Zhang ZJ, Fang L, Su LG (2009) Study on ultrafiltration for surface water by a polyvinylchloride hollow fiber membrane. Desalination 238:183–191
Khayet M, Garcia-Payo MC, Qusay FA, Zubaidy MA (2009) Structural and performance studies of poly(vinyl chloride) hollow fiber membranes prepared at different air gap lengths. J Membr Sci 330:30–39
Mei S, Xiao CF, Hu XY (2011) Preparation of porous PVC membrane via a phase inversion method from PVC/DMAc/water/addibives. J Appl Polym Sci 120:557–562
Jones CA, Gordeyev SA, Shilton SJ (2011) Poly(vinyl chloride) (PVC) hollow fibre membranes for gas separation. Polymer 52:901–903
Xu J, Xu ZL (2002) Poly(vinyl chloride) (PVC) hollow fiber ultrafiltration membranes prepared from PVC/additives/solvent. J Membr Sci 208:203–212
Hajibaba A, Naderi G, Ghoreishy M, Bakhahandeh G, Nouri MR (2012) Effect of single-walled carbon nanotubes on morphology and mechanical properties of NBR/PVC blends. Iran Polym J 21:505–511
Kadam P, Kute R, Mhaske S (2013) Effect of nano-alumina concentration on the properties of poly(vinyl chloride)/thermoplastic polyester elastomer blend system. Iran Polym J 22:549–560
Nihul PG, Mhaske ST, Shertukde VV (2014) Epoxidized rice bran oil (ERBO) as a plasticizer for poly(vinyl chloride) (PVC). Iran Polym J 23:599–608
Liu HL, Xiao CF, Hu XY (2013) Fabrication and properties of polyvinyl chloride hollow fiber membranes plastified by dioctyl phthalate. Desalin Water Treat 51:3786–3793
Ran S, Burger C, Sics I, Yoon K, Fang D, Kim K, Avila-Orta C, Keum J, Chu B, Hsiao BS, Cookson D, Shultz D, Lee M, Viccaro J, Ohta Y (2004) In situ synchrotron SAXS/WAXD studies during melt spinning of modified carbon nanofiber and isotactic polypropylene nanocomposite. Colloid Polym Sci 282:802–809
Acknowledgments
The authors gratefully acknowledge the research funding provided by the 973 Program (2012CB722706) and 863 Program (2012AA03A603) of China, the National Natural Science Foundation of China (21274109), the Science and Technology Plans of Tianjin (12JCZDJC26600), and also the Basic Research Program of China National Textile and Apparel Council.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Liu, H., Xiao, C., Huang, Q. et al. Study on interface structure and performance of homogeneous-reinforced polyvinyl chloride hollow fiber membranes. Iran Polym J 24, 491–503 (2015). https://doi.org/10.1007/s13726-015-0340-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13726-015-0340-5