Skip to main content
Log in

Influence of (La, Cu) Doping on the Room Temperature Multiferroic Properties of BiFeO3 Ceramics

  • Research Article - Physics
  • Published:
Arabian Journal for Science and Engineering Aims and scope Submit manuscript

Abstract

A series of Bi1-x La x Fe0.98Cu0.02O3 (x = 0.01, 0.03 and 0.05) ceramics were synthesized by sol–gel method. The prepared ceramics were characterized by X-ray diffractometer (XRD), vibrating sample magnetometer (VSM) and dielectric measurement. XRD patterns reveal that Bi1-x La x Fe0.98Cu0.02O3 (x = 0.01, 0.03 and 0.05) ceramics crystallize in single-phase rhombohedral structure with R3c space group without distortion, and the average crystallite size was in the range of 31–92 nm. VSM exhibited a weak ferromagnetism for La- and Cu-co-doped BiFeO3 ceramics. The squareness ratio of the hysteresis loop decreases as La concentration increases in Bi1-x La x Fe0.98Cu0.02O3. However, these materials show improved dielectric properties compared to undoped BiFeO3 ceramic.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Cheng Z.X., Li A.H., Wang X.L., Dou S.X., Ozawa K., Kimura H., Zhang S.J., Shrout T.R.: Structure, ferroelectric properties, and magnetic properties of the La-doped bismuth ferrite. J. Appl. Phys. 103, 07E507 (2008)

    Google Scholar 

  2. Shami M.Y., Awan M.S., Rehman M.A.U.: Phase pure synthesis of BiFeO3 nanopowders using diverse precursor via co-precipitation method. J. Alloys Compd. 509, 10139–10144 (2011)

    Article  Google Scholar 

  3. Wang Y.P., Yuan G.L., Chen X.Y., Liu J.M., Liu Z.G.: Electrical and magnetic properties of single-phased and highly resistive ferroelectromagnet BiFeO3 ceramic. J. Phys. D Appl. Phys. 39, 2019–2023 (2006)

    Article  Google Scholar 

  4. Priya A.S., Banu I.B.S., Anwar S.: Investigation of multiferroic properties of doped BiFeO3 – BaTiO3 composite ceramics. Mater. Lett. 142, 42–44 (2015)

    Article  Google Scholar 

  5. Layek S., Verma H.C.: Magnetic and dielectric properties of multiferroic BiFeO3 nanoparticles synthesized by a novel citrate combustion method. Adv. Mater. Lett. 3, 533–538 (2012)

    Google Scholar 

  6. Fiebig M., Loltermoser T., Frohlich D., Goltsev A.V., Pisarev R.V.: Observation of coupled magnetic and electric domains. Nature 419, 818–820 (2002)

    Article  Google Scholar 

  7. Hur N., Park S., Sharma P.A., Ahn J.S., Guha S., Cheong S.W.: Electric polarization reversal and memory in a multiferroic material induced by magnetic fields. Nature 429, 329 (2004)

    Article  Google Scholar 

  8. Kim W.S., Jun Y.K., Kim K.H., Hong S.H.: Enhanced magnetization in Co and Ta-substituted BiFeO3 ceramics. J. Magn. Magn. Mater. 321, 3262–3265 (2009)

    Article  Google Scholar 

  9. Neaton J.B., Ederer C., Waghmare U.V., Spaldin N.A., Rabe K.M.: First-principles study of spontaneous polarization in multiferroic BiFeO3. Phys. Rev. B 71, 014113 (2005)

    Article  Google Scholar 

  10. Sosnowska I., Prezenioslo R., Fischer P., Murashov V.A.: Neutron diffraction studies of the crystal and magnetic structures of BiFeO3 and Bi0.93 La0.07 FeO3. J. Magn. Magn. Mater. 160, 384–385 (1996)

    Article  Google Scholar 

  11. Li Y., Fan Y., Zhang H., Teng X., Dong X., Liu H., Ge X., Li Q., Chen W., Li X., Ge Z.: Structural, thermal and magnetic properties of Cu-doped BiFeO3. J. Supercond. Nov. Magn. 27, 1239–1243 (2014)

    Article  Google Scholar 

  12. Qian F.Z., Jiang J.S., Zhang W.G., Liu J.H.: Multiferroic properties of Bi0.8 Dy0.2-x La x FeO3 nanoparticles. J. Phys. D. Appl. Phys. 43, 025403 (2010)

    Article  Google Scholar 

  13. Yuan G.L., Or S.W., Liu J.M., Liu Z.G.: Structural transformation and ferroelectromagnetic behavior in single-phase Bi1-x Nd x FeO3 multiferroic ceramics. Appl. Phys. Lett. 89, 052905 (2006)

    Article  Google Scholar 

  14. Zhang S.T., Zhang Y., Lu M.H., Du C.L., Chen Y.F., Liu Z.G., Zhu Y.Y., Ming N.B.: Substitution-induced phase transition and enhanced multiferroic properties of Bi1-x La x FeO3 ceramics. Appl. Phys. Lett. 88, 162901 (2006)

    Article  Google Scholar 

  15. Chaudhuri A., Mandal K.: Enhancement of ferromagnetic and dielectric properties of lanthanum doped bismuth ferrite nanostructures. Mater. Res. Bull. 47, 1057–1061 (2012)

    Article  Google Scholar 

  16. Yan X., Chen J., Qi Y., Cheng J., Meng Z.Z.: Hydrothermal synthesis and characterization of multiferroic Bi1-x La x FeO3 crystallites. J. Eur. Ceram. Soc. 30, 265–269 (2010)

    Article  Google Scholar 

  17. Yang C., Jiang J.S., Wang C.M., Zhang W.G.: A unique magnetic behavior and dielectric properties of Bi0.9-x La0.1 Ca x FeO3 nanoparticles at room temperature. J. Phys. Chem. Solids 73, 115–119 (2012)

    Article  Google Scholar 

  18. Biasotto G., Simoes A.Z., Foschini C.R., Antonio S.G., Zaghete M.A., Varela J.A.: A novel synthesis of perovskite bismuth ferrite nanoparticles. Process. Appl. Ceram. 5, 171–179 (2011)

    Article  Google Scholar 

  19. Hussain A., Begum A., Rahman A.: Characterization of nanocrystalline leas sulphide thin films prepared by chemical bath deposition technique. Arab. J. Sci. Eng. 39, 169–174 (2013)

    Article  Google Scholar 

  20. Begum A., Hussian A., Rahman A.: Structural and optical studies of bismuth sulphide nanocrystalline thin films prepared from acid aqueous bath. Arab. J. Sci. Eng. 38, 163–168 (2013)

    Article  Google Scholar 

  21. Mahdi E.M., Hamdi M., Meor Yusoff M.S.: The effect of sintering on the physical and optical properties of nano-TiO2 synthesized via modified hydrothermal route. Arab. J. Sci. Eng. 38, 1701–1711 (2013)

    Article  Google Scholar 

  22. Dutta D.P., Mandal B.P., Naik R., Lawes G., Tyagi A.K.: Magnetic, ferroelectric and magnetocapacitive properties of sonochemically synthesized Sc doped BiFeO3 nanoparticles. J. Phys. Chem. C 117, 2382–2389 (2013)

    Article  Google Scholar 

  23. Chand J., Singh M.: Electric and dielectric properties of MgGd0.1 Fe1.9 O4 ferrite. J. Alloys Compd. 486, 376–379 (2009)

    Article  Google Scholar 

  24. Arya G.S., Negi N.S.: Effect of In and Mn co-doping on structural, magnetic and dielectric properties of BiFeO3 nanoparticle. J. Phys. D Appl. Phys. 46, 095004 (2013)

    Article  Google Scholar 

  25. Vadivel M., Babu R.R., Sethuraman K., Ramamurthi K., Arivanandhan M.: Synthesis, structural, dielectric, magnetic and optical properties of Cr substituted CoFe2 O4 nanoparticles by co-precipitation method. J. Magn. Magn. Mater. 362, 122–129 (2014)

    Article  Google Scholar 

  26. Idrees M., Nadeem M., Atif M., Siddique M., Mehmood M., Hassan M.M.: Origin of colossal dielectric response in LaFeO3. Acta Mater. 59, 1338–1345 (2011)

    Article  Google Scholar 

  27. Qiu Y., Luo Y.S., Zou Z.J., Tian Z.M., Yuan S.L., Xi Y., Huang L.Z.: Size effect on magnetic and dielectric properties in nanocrystalline LaFeO3. J. Mater. Sci. Mater. Electron 25, 760–764 (2014)

    Article  Google Scholar 

  28. Pandit P., Satapathy S., Gupta P.K.: Effect of La substitution on conductivity and dielectric properties of Bi1-x La x FeO3 ceramics: an impedance spectroscopy analysis. Phys. B 406, 2669–2677 (2011)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Sathiya Priya.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Priya, A.S., Banu, I.B.S. & Chavali, M. Influence of (La, Cu) Doping on the Room Temperature Multiferroic Properties of BiFeO3 Ceramics. Arab J Sci Eng 40, 2079–2084 (2015). https://doi.org/10.1007/s13369-015-1668-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13369-015-1668-z

Keywords

Navigation