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Influence of Preparation Conditions on the Dispersion Parameters of Sprayed In2S3films

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Abstract

In2S3 films were prepared by spray pyrolysis technique at various substrate temperatures (T sub) and the spray solutions were mixtures of indium chloride (InCl3) and thiourea (SC(NH2)2). The films are preferentially oriented along the (220) plane and are of polycrystalline In2S3 with a cubic crystal structure. The refractive index dispersion curves of the films obey the single oscillator model and oscillator parameters changed with substrate temperature. The most significant result of the present study is to indicate that substrate temperature of the film can be used to modify the optical band gaps and optical constants of In2S3 films. The effect of T sub on the optical dispersion of these films has been investigated.

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References

  1. Teny Theresa, J.; Meril, M.; Sudha Kartha, C.; Vijayakumar, K.P.; Abe, T.; Kashiwaba, Y.: CuInS2/In2S3 thin film solar cell using spray pyrolysis technique having 9.5 % efficiency. Sol. Energy Mater. Sol. Cells. 89, 27 (2005)

    Google Scholar 

  2. Herrero J., Ortega J.: n-Type In 2S 3 thin films prepared by gas chalcogenization of metallic electroplated indium: photoelectrochemical characterization. Sol. Energy Mater. 17, 357 (1988)

    Article  Google Scholar 

  3. Maissel L.I., Glang R.: Handbook of Thin Film Technology. McGraw Hill, New York (1970)

    Google Scholar 

  4. Vossen J.L., Kern W.: Thin Films Processes. Academic Press, New York (1978)

    Google Scholar 

  5. Oktik S.: Low cost, non-vacuum techniques for the preparation of thin/thick films for photovoltaic applications. Prog. Cryst. Growth Charact. 17, 171 (1988)

    Article  Google Scholar 

  6. Madelung, O.: Data in Science and Technology: Semiconductors other than Group IV elements and III–V Compounds. Springer-Verlag, Berlin-Heidelberg (1992)

  7. Nair, P.K.; Nair, M.T.S.; Garcia, V.M.; Arenas, O.L.; Pena, Y.; Castillo, A.; Ayala, I.T.; Gomez-Daza, O.; Sanchez-Juarez, A.; Campos, J.; Hu, H.; Suarez, R.; Rincon, M.E.: Semiconductor thin films by chemical bath deposition for solar energy related applications. Sol. Energy Mater. Sol. Cells. 52, 313 (1998)

    Google Scholar 

  8. Barreau, N.; Berne‘de, J.C.; Marsillac, S.; Amory, C.; Shafarman, W.N.: New Cd-free buffer layer deposited by PVD: In2S3 containing Na compounds. Thin Solid Films. 431–432, 326 (2003)

    Google Scholar 

  9. Bouguila, N.; Bouzouita, H.; Lacaze, E.; Belhadj Amara, A.; Bouchriha, H.; Dhouib, A.: Effet de la température de fabrication sur les propriétés structurales et morphologiques des couches épaisses de In 2S 3 “spray”. J. Phys. III. 7, 1647 (1997)

    Google Scholar 

  10. Kim W.T., Kim C.D.: Optical energy gaps of β-In2S3 thin films grown by spray pyrolysis. J. Appl. Phys. 60(7), 2631 (1986)

    Article  Google Scholar 

  11. Nomura, R.; Konishi, K.; Matsuda, H.: Single-source organometallic chemical vapour deposition process for sulphide thin films: introduction of a new organometallic precursor BunIn(SPri)2 and preparation of In2S3 thin films. Thin Solid Films. 198(1–2), 339 (1991)

    Google Scholar 

  12. Asenjo B., Chaparro A.M., Gutiérrez M.T., Herrero J., Maffiotte C.: Quartz crystal microbalance study of the growth of indium(III) sulphide films from a chemical solution. Electrochim. Acta. 49, 737 (2004)

    Article  Google Scholar 

  13. Buecheler, S.; Corica, D.; Guettler, D.; Chirila, A.; Verma, R.; Müller, U.; Niesen, T.P.; Palm, J.; Tiwari, A.N.: Ultrasonically sprayed indium sulfide buffer layers for Cu(In,Ga)(S,Se)2 thin-film solar cells. Thin Solid Films. 517, 2312 (2009)

    Google Scholar 

  14. John, T.T.; Bini, S.; Kashiwaba, Y.; Abe, T.; Yasuhiro, Y.; Sudha Kartha, C.; Viljayakumar, K.P.: Characterization of spray pyrolysed indium sulfide thin films. Semicond. Sci. Technol. 18, 491 (2003)

    Google Scholar 

  15. Calixto-Rodriguez, M.; Tiburcio-Silver, A.; Ortiz, A.; Sanchez-Juarez, A.: Optoelectronical properties of indium sulfide thin films prepared by spray pyrolysis for photovoltaic applications. Thin Solid Films. 480–481, 133 (2005)

  16. Kim, W.T.; Kim, C.-D.: Optical energy gaps of β-In2S3 thin films grown by spray pyrolysis. J. Appl. Phys. 60, 2631 (1986)

    Google Scholar 

  17. Otto K., Katerski A., Mere A., Volobujeva O., Krunks M.: Spray pyrolysis deposition of indium sulphide thin films. Thin Solid Films. 519(10), 3055 (2011)

    Article  Google Scholar 

  18. Kamoun, N.; Belgacem, S.; Amlouk, N.; Bennaceur, R.: Structure, surface composition, and electronic properties of β-In2S3 and β-In2-x Al x S3. J. Appl Phys. 89, 2766 (2001)

    Google Scholar 

  19. Kamoun N., Bennaceur R., Amlouk M., Belgacem S., Mliki N., Frigerio J.M., Theye M.L.: Optical properties of InS layers deposited using an airless spray technique. Phys. Status Solidi A. 169, 97 (1998)

    Article  Google Scholar 

  20. Oztas M., Yazıcı A.N.: The effect of pre-irradiation heat treatment on TL glow curves of ZnS thin film deposited by spray pyrolysis. J. Lumin. 110, 31 (2004)

    Article  Google Scholar 

  21. Masahiro T., Narumi I., Yoshizumi Y.: Annealing effect of vacuum evaporated InSb thin films. Vacuum. 47, 239 (1996)

    Article  Google Scholar 

  22. Oztas M.: Influence of grain size on electrical and optical properties of InP films. Chin. Phys. Lett. 25(11), 4090 (2008)

    Article  Google Scholar 

  23. Swanepoel, R.: Determination of the thickness and optical constants of amorphous silicon. J. Phys. E: Sci. Instrum. 16, 1214 (1983)

    Google Scholar 

  24. Marquez, E.; Ramirez-Malo, J.B.; Villares, P.; Jimenez-Garay, R.; Ewen, P.J.S.; Owen, A.E.: Calculation of the thickness and optical constants of amorphous arsenic sulphide films from their transmission spectra. J. Phys. D: Appl. Phys. 25, 535 (1992)

    Google Scholar 

  25. Calixto-Rodriguez, M.; Tiburcio-Silver, A.; Ortiz, A.; Sanchez-Juarez, A.: Optoelectronical properties of indium sulfide thin films prepared by spray pyrolysis for photovoltaic applications. Thin Solid Films. 480–481, 133 (2005)

  26. Murali K.R., Swaminathan V., Trivedi D.C.: Characteristics of nanocrystalline CdSe films. Sol. Energy Mater. Sol. Cells. 81, 113 (2004)

    Article  Google Scholar 

  27. Cortes A., Gómez H., Marotti R.E., Riveros G., Dalchiele E.A.: Grain size dependence of the bandgap in chemical bath deposited CdS thin films. Sol. Energy Mater. Sol. Cells. 82, 21 (2004)

    Article  Google Scholar 

  28. John T., Bini S., Kashiwaba Y., Abe T., Yasuhiro Y., Sudha Kartha C., Vijayakumar K.P.: Characterization of spray pyrolysed indium sulfide thin films. Semicond. Sci. Technol. 18, 491 (2003)

    Article  Google Scholar 

  29. Marquez E., Ramirez-Malo J.B., Villares P., Jimenez-Garay R., Swanepoel R.: Optical characterization of wedge-shaped thin films of amorphous arsenic trisulphide based only on their shrunk transmission spectra. Thin Solid Films, 254, 83 (1995)

    Article  Google Scholar 

  30. Soliman, H.S.; Abdel-Hady, D.; Ibrahim, E.: Optical properties of thermally vacuum evaporated. AgSbSe2 thin films. J. Phys.: Condens. Matter. 10, 647 (1998)

    Google Scholar 

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Correspondence to Mustafa Öztaş.

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Bedir, M., Öztaş, M., Korkmaz, D. et al. Influence of Preparation Conditions on the Dispersion Parameters of Sprayed In2S3films. Arab J Sci Eng 39, 503–509 (2014). https://doi.org/10.1007/s13369-013-0877-6

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  • DOI: https://doi.org/10.1007/s13369-013-0877-6

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