Skip to main content
SpringerLink
Log in

RETRACTED ARTICLE: Microstructure of poly(vinyl acetate)-block-poly(methyl acrylate-co-methyl methacrylate) block terpolymers. 2D NMR and thermal study

  • Articles
  • Published:
Macromolecular Research Aims and scope Submit manuscript

An Erratum to this article was published on 24 June 2011

Abstract

Structural analysis of the poly(vinyl acetate)-block-poly(methyl acrylate-co-methyl methacrylate) with different MA/MMA ratios was characterized by 1D and 2D NMR. The effect of the sequence distribution, composition and stereoregularity on the unknown signals of α-CH3, backbone methylene and methin carbons were analyzed by 1D (13C/DEPT-135) and 2D HSQC NMR. Furthermore, the theoretical values of triad, dyad and triad fractions of these carbons confirmed the spectral assignments. The sensitivity of the vicinal and geminal couplings of methin and methylene protons to the sequence distribution and composition were characterized using the 2D TOCSY NMR method. The influence of the sequence distribution on the theoretical glass transition temperatures of the MA/MMA copolymers was also examined using the Johnston (extended Fox) equation and experimental T g .

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. K. Matyjaszewski, Prog. Polym. Sci., 30, 858 (2005).

    Article  CAS  Google Scholar 

  2. N. Hadjichristidis, H. Iatroua, M. Pitsikalisa, and J. Mays, Prog. Polym. Sci., 31, 1068 (2006).

    Article  CAS  Google Scholar 

  3. N. A. Lynda, A. J. Meulerb, and M. A. Hillmyer, Prog. Polym. Sci., 33, 875 (2008).

    Article  Google Scholar 

  4. G. Kwak, H. Kim, M.-W. Kim, S.-H. Hyun, Ch.-H. Baek, and W.-S. Kim, Macromol. Res., 18, 67 (2010).

    Article  CAS  Google Scholar 

  5. B. J. Busche, A. E. Tonelli, and C. M. Balik, Polymer, 51, 454 (2010).

    Article  CAS  Google Scholar 

  6. S. V. Dvinskikh, U. H. N. Dürr, K. Yamamoto, and A. Ramamoorthy, J. Am. Chem. Soc., 129, 794 (2007).

    Article  CAS  Google Scholar 

  7. M. K. Nguyen and D. S. Lee, Macromol. Res., 18, 284 (2010).

    Article  CAS  Google Scholar 

  8. Y. Nishiyama, T. Tanaka, T. Yamazaki, and T. Iwata, Macromolecules, 39, 4086 (2006).

    Article  CAS  Google Scholar 

  9. A. Ramakrishnan and R. Dhamodharan, Macromolecules, 36, 1039 (2003).

    Article  CAS  Google Scholar 

  10. M. A. Semsarzadeh and M. R. Rostami Daronkola, Iran. Polym. J., 15, 829 (2006).

    CAS  Google Scholar 

  11. A. Debuigne, J.-R. Caille, N. Willet, and R. Jérôme, Macromolecules, 38, 9488 (2005).

    Article  CAS  Google Scholar 

  12. M. A. Semsarzadeh and M. Abdollahi, Polymer, 49, 3060 (2008).

    Article  CAS  Google Scholar 

  13. M. R. Rostami Daronkola and M. A. Semsarzadeh, J. Polym. Res., 15, 403 (2008).

    Article  Google Scholar 

  14. P. Li, Z. Xia, A. Zerroukhi, J. Chen, Y. Chalamet, and T. Jeanmaire, J. Appl. Polym. Sci., 115, 1958 (2010).

    Article  CAS  Google Scholar 

  15. M. A. Semsarzadeh and M. R. Rostami Daronkola, Iran. Polym. J., 16, 47 (2007).

    CAS  Google Scholar 

  16. L. Wang, J. Lin, and L. Zhang, Macromolecules, 43, 1602 (2010).

    Article  CAS  Google Scholar 

  17. D. P. Christy, R. F. Barlow, and D. A. Shipp, J. Polym. Sci. Part A: Polym. Chem., 46, 7200 (2008).

    Article  Google Scholar 

  18. S. Mendrek, A. Mendrek, H.-J. Adler, A. Dworak, and D. Kuckling, J. Polym. Sci. Part A: Polym. Chem., 47, 1782 (2009).

    Article  CAS  Google Scholar 

  19. H.-C. Kim, S.-M. Park, and W. D. Hinsberg, Chem. Rev., 110, 146 (2010).

    Article  CAS  Google Scholar 

  20. W. Z. Wang, W. Song, R. Wang, and T. X. Liu, J. Polym. Sci. Part A: Polym. Chem., 47, 1478 (2009).

    Article  CAS  Google Scholar 

  21. I. Noda, J. Molecul. Struct., 799, 2 (2006).

    Article  CAS  Google Scholar 

  22. A. Malinowskab, P. Vlčeka, J. Křiža, L. Tomana, P. Látalováa, M. Janataa, and B. Masařa, Polymer, 46, 5 (2005).

    Article  Google Scholar 

  23. H. Wickel, S. Agarwal, and A. Greiner, Macromolecules, 36, 2397 (2003).

    Article  CAS  Google Scholar 

  24. S.-C. Lim, S.-W. Kim, M.-H. Jung, M.-K. Cho, J.-H. Kim, H.-S. Cho, and J.-H. Ok, J. Molecul. Struct., 886, 166 (2008).

    Article  CAS  Google Scholar 

  25. A. S. Brar and M. Markanday, Polymer, 46, 11527 (2005).

    Article  CAS  Google Scholar 

  26. A. S. Brar, A. K. Goyal, S. Hooda, and R. Shankar, J. Polym. Sci. Part A: Polym. Chem., 47, 25 (2009).

    Article  CAS  Google Scholar 

  27. S. Hooda, A. K. Goyal, and A. S. Brar, J. Molecul. Struct., 920, 424 (2009).

    Article  CAS  Google Scholar 

  28. D. M. Savant, D. V. Reddy, E. F. McCord, and P. L. Rinaldi, Macromolecules, 40, 4199 (2007).

    Article  CAS  Google Scholar 

  29. F. Ziaee, H. Bouhendi, and F. Ziaie, Iran. Polym. J., 18, 947 (2009).

    CAS  Google Scholar 

  30. X. H. Qiu, D. Redwine, and G. Gobbi, Macromolecules, 40, 6879 (2007).

    Article  CAS  Google Scholar 

  31. S. Hooda, A. K. Goyal, and A. S. Brar, J. Appl. Polym. Sci., 111, 2381 (2009).

    Article  CAS  Google Scholar 

  32. S. Hooda, A. K. Goyal, and A. S. Brar, J. Molecul. Struct., 963, 27 (2010).

    Article  CAS  Google Scholar 

  33. Y. Kim and H. J. Harwood, Polymer, 43, 3229 (2002).

    Article  CAS  Google Scholar 

  34. R. Aggarwal, J. Sumran, R. M. Claramunt, D. Sanz, and J. Elguero, J. Molecul. Struct., 934, 96 (2009).

    Article  CAS  Google Scholar 

  35. R. Ramachandran, M. Rani, and S. Kabilan, J. Molecul. Struct., 970, 42 (2010).

    Article  CAS  Google Scholar 

  36. A. S. Brar, G. Singh, and R. Shankar, J. Appl. Polym. Sci., 99, 1437 (2006).

    Article  CAS  Google Scholar 

  37. M. A. Semsarzadeh, M. R. Rostami Daronkola, and M. Abdollahi, J. Mac. Sci. Part A: Pure Appl. Chem., 44, 953 (2007).

    Article  CAS  Google Scholar 

  38. K. Katsuraya, K. Hatanaka, K. Matsuzaki, and K. Yamaura, Macromol. Rapid Commun., 21, 697 (2000).

    Article  CAS  Google Scholar 

  39. M. Matlengiewicz, M. Pasich, P. Bujak, and N. Henzel, Inter. J. Polym. Analys. Charac., 14, 686 (2009).

    Article  CAS  Google Scholar 

  40. A. S. Brar, G. Singh, and R. Shankar, Eur. Polym. J., 40, 2679 (2004).

    Article  CAS  Google Scholar 

  41. M. A. Semsarzadeh and M. R. Rostami-Daronkola, Iran. J. Polym. Sci. Technol., 22, 197 (2009).

    CAS  Google Scholar 

  42. S.-W. Kuo, H.-C. Kao, and F.-C. Chang, Polymer, 44, 6873 (2003).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Polymer Group, Chemical Engineering Department, Tarbiat Modares University, Jalal Al Ahmad Highway, P.O. Box, 14115-143, Tehran I.R., Iran

    Mahdi Moeud Ajjalallah & Mohammad Reza Rostami Daronkola

Authors
  1. Mahdi Moeud Ajjalallah
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mohammad Reza Rostami Daronkola
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mohammad Reza Rostami Daronkola.

Additional information

This article has been retracted due to a dispute over authorship of the paper and ownership of the data.

An erratum to this article can be found at http://dx.doi.org/10.1007/s13233-011-0617-2

About this article

Cite this article

Ajjalallah, M.M., Daronkola, M.R.R. RETRACTED ARTICLE: Microstructure of poly(vinyl acetate)-block-poly(methyl acrylate-co-methyl methacrylate) block terpolymers. 2D NMR and thermal study. Macromol. Res. 19, 156–165 (2011). https://doi.org/10.1007/s13233-011-0213-5

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13233-011-0213-5

Keywords

Search

Navigation