Abstract
In this study, total heavy metal content of soil and their spatial distribution in Sarıseki-Dörtyol district were analyzed and mapped. Variable distance grids (0.5, 1.0 and 2.0 km) were established, with a total of 102 soil samples collected from two different soil depths (0–5 and 5–20 cm) at intersections of the grids (51 sampling point). Soil samples were analyzed for heavy metals (Cd, Co, Cr, Cu, Pb, Zn, Mn, Fe, and Ni). The most proper variogram models for the contents of all heavy metal were spherical and exponential ones. The ranges of semivariograms were between 1.9 and 31.1 km. According to the calculated geoaccumulation (I geo) values, samples from both soil depths were classified as partly to highly polluted with Cd and Ni and partly polluted with Cr and as partly polluted-to-not polluted with Pb and not polluted with Cu, Fe and Mn. Similar results were also obtained when evaluated by the enrichment factor. The contamination levels of the heavy metals were Ni > Cd > Cr > Pb > Zn > Cu > Co > Fe > Mn in decreasing order. The soils in the study area are contaminated predominantly by Cd and Ni, which may give rise to various health hazards or diseases. Cadmium pollution results primarily from industrial activities and, to a lesser extent, from vehicular traffic, whereas Ni contents in the study area result from parent material, phosphorus fertilizer, industries, and vehicles.
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References
Ahsan DA, DelValls TA, Blasco J (2009) Distribution of arsenic and trace metals in the floodplain agricultural soil of Bangladesh. Bull Environ Contam Toxicol 82:11–15
Ali SM, Malik RN (2011) Spatial distribution of metals in top soils of Islamabad city, Pakistan. Environ Monit Assess 172:1–16
Alloway BJ (1995) Heavy metals in soils. Blaskie Academic and Professional, London
Anonymous (1972) Soil map of Turkey. Republic of Turkey Ministry of Agriculture and Rural Affair, General Directorate for Rural Service (In Turkish)
Anonymous (2004) Agricultural master plan of Hatay city. Ministry of Agriculture and Rural Affairs- Agricultural Directorate of Hatay (in Turkish)
Anonymous (2010) The map of Annual Average Daily Traffic. General Directorate of Highways. http://www.kgm.gov.tr/SiteCollectionImages/trafikharita2009.jpg (in Turkish)
Cambardella CA, Moorman TB, Parkin TB, Karlen DL, Novak JM, Turco RF, Konopka AE (1994) Field-scale variability of soil properties in central Iowa soils. Soil Sci Soc Am J 58:1501–1511
Çevik F, Göksu MZL, Derici OB, Fındık Ö (2009) An assessment of metal pollution in surface sediments of Seyhan dam by using enrichment factor, geoaccumulation index and statistical analyses. Environ Monit Assess 152:309–317
Çolak M (2012) Heavy metal concentration in sultana-cultivation soils and sultana raisins from Manisa (Turkey). Environ Earth Sci 67:695–712
Dantu S (2009) Heavy metals concentration in soils of Southeastern part Ranga Reddy district, Andhra Pradesh, India. Environ Monit Assess 149:213–222
Doygun H, Alphan H (2006) Monitoring urbanization of İskenderun, Turkey, and its negative implications. Environ Monit Assess 114:145–155
Doyuran V (1982) Geological and hydrogeological features of Erzin and Dörtyol Plains. Bull Geol Soc Turk 25:151–160 (in Turkish, abstract in English)
EPA (1996) Method 3050B. Acid digestion of sediments, sludges and soils. http://www.epa.gov/sw-846/pdfs/3050b.pdf
Fong FT, Chee PS, Mahmood AA, Tahir NM (2008) Possible source and pattern distribution of heavy metals content in urban soil at Kuala Terengganu town center. Malays J Anal Sci 12(2):458–467
Ghrefat HA, Abu-Rukhan Y, Rosen MA (2011) Application of geoaccumulation index and enrichment factor for assessing metal contamination in the sediments of Kafrain Dam, Jordan. Environ Monit Assess 178:95–109
Giarratano E, Amin OA (2010) Heavy metals monitoring in the southernmost mussel farm of world (Beagle Channel, Argentina). Ecotoxicol Environ Saf 73:1378–1384
Golia EE, Dimirkou A, Mitios IK (2008) Levels of heavy metals pollution in different types of soil of Central Greece. Bull Environ Contam Toxicol 80:206–210
Goovaerts P (1999) Geostatistics in soil science: state-of-the-art and perspectives. Geoderma 89:1–45
Imperato M, Adamo P, Naimo D, Arienzo M, Stanzione D, Violante P (2003) Spatial distribution of heavy metals in urban soils of Naples city (Italy). Environ Pollut 124:247–256
Isaaks HE, Srivastava RM (1989) Applied geostatistics. Oxford University Press, New York
Karanlık S, Ağca N, Yalçın M (2011) Spatial distribution of heavy metals content in soils of Amik Plain (Hatay, Turkey). Environ Monit Assess 173:181–191
Khairiah J, Habibah HJ, Anizan I, Maimon A, Aminah A, Ismail BS (2009) Content of heavy metals in soils collected from selected paddy cultivation areas in Kedah and Perlis, Malaysia. J Appl Sci Res 5:2179–2188
Koç Ş, Değer MA (1991) The formation of iron with bauxite ore deposits in Payas (Hatay) district. MTA J 113:113–126 (in Turkish)
Koç Ş, Değer MA (1992) Karstik Payas (Hatay) cehverleşmesinin kaynağına yönelik jeokimyasal veriler. MTA Dergisi 114:95–110
Li J, Lu Y, Yin W, Gan H, Zhang C, Deng X, Lian J (2009) Distribution of heavy metals in agricultural soils near a petrochemical complex in Guangzhou, China. Environ Monit Assess 153:365–375
Lin YP, Cheng BY, Chu HJ, Chang TK, Yu HL (2011) Assessing how heavy metal pollution and human activity are related by using logistic regression and kriging methods. Geoderma 163:275–282
Liu D, Wang Z, Zhang B, Song K, Li X, Li J, Li F, Duan H (2006) Spatial distribution of soil organic carbon and analysis of related factors in croplands of the black soil region, northeast China. Agric Ecosyst Environ 113:73–81
Loska K, Wiechula D, Korus I (2004) Metal contamination of farming soils affected by industry. Environ Int 30:159–165
Lurenço RW, Landim PMB, Rosa AH, Roveda JAF, Martins ACG, Fraceto LF (2010) Mapping soil pollution by spatial analysis and fuzzy classification. Environ Earth Sci 60:495–504
Martínez J, Liamas JF, de Miguel E, Rey J, Hidalgo MC (2008) Soil contamination from urban and industrial activity: example of the mining district of Linares (Southern Spain). Environ Geol 54:669–677
Martley E, Gulson BL, Pfeifer HR (2004) Metal concentrations in soils around the copper smelter and surrounding industrial complex of Port Kembla, NSW, Australia. Sci Total Environ 325:113–127
Massas I, Ehaliotis C, Gerontidis S, Sarris E (2009) Elevated heavy metal concentrations in top soils of an Aegean island town (Greece): total and available forms, origin and distribution. Environ Monit Assess 151:105–116
Mehrjardi RT, Jahromi MZ, Mahmodi S, Heidari A (2008) Spatial distribution of groundwater quality with geostatistics (case study: Yazd-Ardakan plain). World Appl Sci J 4(1):09–17
Morton-Bermea O, Hernandez E, Martinez-Pichardo E, Soler-Arechalde AM, Santa-Cruz RL, Gonzalez-Hernandez G, Beramendi-Orosco L, Urrutia-Fucugauchi J (2009) Mexico City top soils: heavy metals vs. magnetic susceptibility. Geoderma 151:121–125
Morton-Bermea O, Hernández-Álvarez E, Lozano R, Guzmán-Morales J, Martínez G (2010) Spatial distribution of heavy metals in top soils around the industrial facilities of Cromatos de México, Tultitlan Mexico. Bull Environ Contam Toxicol 85:520–524
Mulla DJ, McBratney AB (2000) Soil spatial variability. In: Summer ME (ed) Handbook of Soil Science. CRS Press, UK, pp A321–A351
Nwachukwu MA, Feng H, Alinnor J (2010) Assessment of heavy metal pollution in soil and their implications within and around mechanic villages. Int J Environ Sci Tech 7:347–358
Özer MA (1996) Stratigraphy of the Payas-İskenderun area of the Toprakkale-İskenderun Motorway. MSc Thesis, Department of Geological Engineering, Institute of Natural and Applied Sciences, Çukurova University (In Turkish)
Özyılmaz G (1999) Air and soil pollution caused industrial zone in İskenderun bay. MSc Thesis, Department of chemistry, Institute of Natural and Applied Sciences, Mustafa Kemal University (In Turkish)
Paz-González A, Vieira SR, Castro MTT (2000) The effect of cultivation on the spatial variability of selected properties of an umbric horizon. Geoderma 97:273–292
Rashed MN (2010) Monitoring of contaminated toxic and heavy metals, from mine tailings through age accumulation, in soil and some wild plants at Southeast Egypt. J Hazard Mater 178:739–746
Romic M, Romic D (2003) Heavy metals distribution in agricultural topsoils in urban area. Environ Geol 43:795–805
Sayadi MH, Sayyed MRG (2011) Comparative assessment of baseline concentration of the heavy metals in the soils of Tehran (Iran) with the comprisable reference data. Environ Earth Sci 63:1179–1188
Schiff KC, Weisberg SB (1999) Iron as a reference element for determining trace metal enrichment in Southern California coastal shelf sediments. Mar Environ Res 48:161–176
Sehgal M, Garg A, Suresh R, Dagar P (2012) Heavy metal contamination in the Delhi segment of Yamuna basin. Eniviron Monit Asssess 184:1181–1196
Simasuwannarong B, Satapanajaru T, Khuntong S, Pengthamkeerati P (2012) Spatial distribution and risk assessment of As, Cd, Cu, Pb, and Zn in Topsoil at Rayong Province, Thailand. Water Air Soil Pollut 223:1931–1943
Škrbić B, Duršić-Mladonević N (2013) Distribution of heavy elements in urban and rural surface soils: the Novi Sad city and the surrounding settlements, Serbia. Environ Monit Assess 185:457–471
Sohrabi T, Ismail A, Nabavi MB (2010) Distribution and normalization of some metals in surface sediments from South Caspian Sea. Bull Environ Contam Toxicol 85:502–508
Sutherland RA (2000) Bed sediment-associated trace metals in an urban stream, Oahu, Hawaii. Environ Geol 39(6):611–627
Taylor SR, Mclennan SM (1995) The geochemical evolution of the continental crust. Rev Geophys 33:611–627
Valdés J, Vargas G, Sifeddine A, Ortlieb L, Guiňez M (2005) Distribution and enrichment evaluation of heavy metals in Mejillones Bay (23°S), Northern Chile: geochemical and statistical approach. Mar Pollut Bull 50:1558–1568
Webster R, Oliver M (2001) Geostatistics for environmental scientists. John Willey and Sons, Ltd., New York
Wu Y, Xu Y, Zhang J, Hu S, Liu K (2011) Heavy metals pollution and the identification of their sources in soil over Xiaoqinling gold-mining region, Shaanxi, China. Environ Earth Sci 64:1585–1592
Yin H, Deng J, Shao S, Gao F, Gao J, Fan C (2011) Distribution characteristics and toxicity assessment of heavy metals in the sediments of Lake Chaohu, China. Environ Monit Assess 179:431–442
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This work was financially sported by Mustafa Kemal University Research Foundation (Project number: MKÜ BAP 08 M 1102). Authors thank to Prof. Dr. M. Rıfat Derici for proofreading in language of this article.
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Ağca, N., Özdel, E. Assessment of spatial distribution and possible sources of heavy metals in the soils of Sariseki-Dörtyol District in Hatay Province (Turkey). Environ Earth Sci 71, 1033–1047 (2014). https://doi.org/10.1007/s12665-013-2507-8
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DOI: https://doi.org/10.1007/s12665-013-2507-8