Abstract
Historical mining dumps are useful archives for the investigation of weathering processes. The objective of this study was to investigate the weathering behavior of waste-rock material derived from the 800-year-old silver ore mining in Freiberg, Germany. For identifying time-dependent weathering indices, dumped material of four dumps of different ages and corresponding rock was examined regarding the geochemical composition. The dumped material is characterized by high contents of heavy metal containing sulfidic ores, such as pyrite, arsenopyrite, sphalerite and galena. Acid mine drainage is produced by the oxidative weathering of the sulfide minerals and causes the increased dissolving of soluble metals with increasing age of dumps. As a result of these weathering processes, a clear depletion of chalcophile elements in the older dump material (800 years) compared to the youngest dump (100 years) was observed. In the soil horizons downstream the dumps, high quantities of heavy metals (e.g., up to 12,000 ppm As, 3,300 ppm Pb, 640 ppm Zn), mainly adsorbed on organic matter, were determined and indicate a time-dependent element transfer from the dumps into their surrounding soils.
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References
Akoto O, Ephrain JH, Darco G (2008) Heavy metals pollution in surface soils in the vicinity of abundant railway servicing workshop in Kumasi, Ghana. Int J Environ Res 2(4):359–364
Aleksander-Kwaterczak U, Ciszewski D (2012) Groundwater hydrochemistry and soil pollution in a catchment affected by an abandoned lead–zinc mine: functioning of a diffuse pollution source. Environ Earth Sci 65:1179–1189
Anderson SP, Dietrich WE, Brimhall GH (2002) Weathering profiles, mass-balance analysis, and rates of solute loss: linkages between weathering and erosion in a small, steep catchment. Geol Soc Am Bull 114:1143–1158
Asta M, Ayora C, Román-Ross G et al (2010) Natural attenuation of arsenic in the Tinto Santa Rosa acid stream (Iberian Pyritic Belt, SW Spain): the role of iron precipitates. Chem Geol 271:1–12
Baake D (2000) Geochemisches Verhalten umweltrelevanter Elemente in stillgelegten Polysulfiderzgruben am Beispiel der Grube “Himmelfahrt” in Freiberg/Sachsen. Dissertation, TU Bergakademie Freiberg
Baumann L, Kuschka E, Seifert T (2000) Lagerstätten des Erzgebirges. Enke, Stuttgart
Beak Consultants GmbH (1997) Radiologische Erfassung, Untersuchung und Bewertung bergbaulicher Altlasten, Untersuchungsgebiet UG 20a/2 Freiberg. Report to GRS
Beckhoff B, Kanngießer B, Langhoff N et al (2006) Handbook of practical X-ray fluorescence analysis. Springer, Berlin
Benvenuti M, Mascaro I, Corsini F et al (1995) Mine waste dumps and heavy metal pollution in abandoned mining district of Boccheggiano southern Tuscany, Italy. Environ Geol 30:238–243
Bernstein KH (1985) Geologischer Lehrpfad Freiberg. VEB Geol Forschung und Erkundung Freiberg
Beuge P, Dunger C, Mibus J, Starke R (1998) Untersuchungen gewässerrelevanter Einflüsse von Bergbauhalden in Abhängigkeit von der Standzeit—Teilprojekt 1. Report 02WA9366/1, TU Bergakademie Freiberg
Böhmer A (1999) Ökologische Bewertung des Einflusses von Erzbergbauhalden im Freiberger Bergbaurevier auf ihre Umgebung unter Berücksichtigung der landwirtschaftlichen Nutzung. Diploma thesis, TU Dresden
Boulet MP, Larocque ACL (1998) A comparative mineralogical and geochemical study of sulfide mine tailings at two sites in New Mexico, USA. Environ Geol 33:30–142
Brümmer GW, Gerth J, Herms U (1986) Heavy metal species, mobility and availability in soils. Z Pflanzenernährung-Bodenkunde 149
Brüschke K (2001) Herkunft, Migrationsformen und Verbleib von Haupt- und Spurenelementen in Sicker- und Porenwässern des ehemaligen Braunkohletagebaus Zwenkau/Cospuden. Dissertation, Georg-August-University of Goettingen
Cappuyns V, Swennen R, Vandamme A, Niclaes M (2006) Environmental impact of the former Pb–Zn mining and smelting in East Belgium. J Geochem Explor 88:6–9
Date AR, Gray AL (1985) Determination of trace elements in geological samples by inductively coupled plasma source mass spectrometry. Spectrochim Acta 40B:115–122
Dold B, Fontboté L (2001) Element cycling and secondary mineralogy in porphyry copper tailings as a function of climate, primary mineralogy, and mineral processing. J Geochem Explor 74:3–55
Fiedler HJ, Hofmann W (1976) Standortskundlicher Exkursionsführer “Tharandt—Grillenburger Wald”. Department of Forest Sciences, TU Dresden
Fiedler HJ, Thalheim K, Hofmann W et al (1990) Chemische Zusammensetzung von Böden über unterschiedlichen Grundgesteinen des Osterzgebirges. Chem Erde 50:269–277
Franke K (2003) Radioanalytische Untersuchung von geochemischen Barrieren für toxische und radiotoxische Stoffe im Bereich von Altbergbauhalden. Dissertation, University of Leipzig
Franke K, Rößler D, Gottschalch U, Kupsch H (2000) Mobilization and retardation of uranium DOC species at three mine piles in Schlema/Alberoda, Saxony, Germany. Isotopes Environ Health Stud 36:223–239
Göhler Y (1999) Boden, Vegetation und Blattspiegelwerte auf Erzbergbauhalden bei Freiberg in Sachsen. Diploma thesis, FH for Forestry, Schwarzburg
Goldschmidt VM (1937) The principles of distribution of chemical elements in minerals and rocks. J Chem Soc, London, pp 655–673
Graham GE, Kelley KD (2009) The Drench water deposit, Alaska: an example of a natural low pH environment resulting from weathering of an undisturbed shale-hosted Zn–Pb–Ag deposit. Appl Geochem 24:232–245
Hämmann M, Desaules A (2003) Handbuch: Probenahme und Probenvorbereitung für Schadstoffuntersuchungen in Böden. Federal Office for the Environment (BUWAL)
Havlova V, Laciok A, Vopálka D, Andrlík M (2006) Geochemical study of uranium mobility in tertiary argillaceous system at rupprechtov site, Czech Republic. Czechoslov J of Phys 56
Jambor JL (1994) Mineralogy of sulfide-rich tailings and their oxidation products. In: Jambor JL, Blowes DW (eds) Short course handbook on environmental geochemistry of sulfide mine waste, 22. Mineralogical Association of Canada, Nepean, pp 59–102
Järup L (2003) Hazards of heavy metal contamination. Br Med Bull 68:167–182
Kardel K, Rank G, Pälchen W (1996) Geochemischer Atlas des Freistaates Sachsen, Teil 1: Spurenelement-gehalte in Gesteinen. Sächsisches Landesamt für Umwelt und Geologie
Keskin T, Toptas S (2012) Heavy metal pollution in the surrounding ore deposits and mining activity: a case study from Koyulhisar (Sivas-Turkey). Environ Earth Sci (online). doi:10.1007/s12665-012-1541-2
Klinger T (1995) Mengen- und Spurenelemente in Waldböden über unterschiedlichen Grundgesteinen des Osterzgebirges. Dissertation, TU Dresden
Kördel W, Dassenakis M, Lintelmann J, Padberg S (1997) The importance of natural organic material for environmental processes in water and soils. Pure Appl Chem 69:1571–1600
Kupsch H, Scheinert M, Franke K, Schreck P (2004) Verwitterungsverhalten von Bergbaurückständen in einer mittelalterlichen Schlackehalde im Erzgebirge. Z Angew Geol 51(2):61–65
LABO (Bund-Länder-Arbeitsgemeinschaft Bodenschutz) (2003) Hintergrund- und Referenzwerte für Böden-Sachsen. http://www.labo-deutschland.de/documents//LABO-HGW-Anhang_340.pdf
Lewandowski J, Leitschuh S, Koß V (1997) Schadstoffe im Boden—Eine Einführung in Analytik und Bewertung. Springer, Berlin
Lide D (1992) CRC handbook of chemistry and physics, 73rd edn. CRC Press, Boca Raton, FL
Liu J, Yu JW, Neretnieks I (1996) Transport modeling in the natural analogue study of the Cigar Lake uranium deposit (Saskatchewan, Canada). J Contam Hydrol 21:19–34
Manning TJ, Grow WR (1997) Inductively coupled plasma-atomic emission spectrometry. The chemical educator 2/1. Springer, New York
Marescotti P, Azzali E, Servida D et al (2010) Mineralogical and geochemical spatial analyses of a waste-rock dump at the Libiola Fe–Cu sulphide mine (Eastern Liguria, Italy). Environ Earth Sci 61:187–199
Martin M, Beuge P, Kluge A, Hoppe T (1994) Grubenwässer des Erzgebirges—Quellen von Schwermetallen in der Elbe. Spektrum der Wiss pp 102–107
Mason B, Moore CB (1985) Grundzüge der Geochemie. Enke, Stuttgart
Matschullat J, Tobschall HJ, Voigt HJ (eds) (1997) Geochemie und Umwelt—Relevante Prozesse in Atmo-, Pedo- und Hydrosphäre. Springer, Berlin
Merkel BJ (2006) Long term fate of uranium tailings in mountain areas. In: Merkel BJ, Hasche-Berger A (eds) Uranium in the environment: mining impact and consequences. Springer, Berlin
Möller D, Horváth L (1988) Estimation of natural acidity of precipitation water on global scale. Idöjaras 93:324–335
Müller G (1969) Index of geoaccumulation in sediments of the Rhine River. GeoJournal 2(3):108–118
Müller G (1981) Die Schwermetallbelastung der Sedimente des Neckars und seiner Nebenflüsse—Eine Be-standsaufnahme. Chem Ztg 105:157–164
Müller C (1999) Stoffbestand des Bodens—Einträge, Austräge auf landwirtschaftlichen Flächen am Beispiel Schwermetalle, In: Bodenschutz und Altlastensanierung, Marktredwitzer Bodenschutztage, 27–29 Oct 1999, Marktredwitz
Müller N (2008) Georadiochemische Untersuchungen zur Wechselwirkung und Verteilung von Tracerelementen zwischen Mineralien und NOM-Spezies im Kupferschiefer. Dissertation, University of Leipzig
Müller N, Franke K, Schreck P et al (2008) Georadiochemical evidence to weathering of mining residues of the Mansfeld mining district, Germany. Environ Geol 54:869–877
Munendra S, Muller G, Singh B (2002) Heavy metals in freshly deposited stream sediments of rivers associated with urbanization of the Ganga plain, India. Water Air Soil Poll 141:35–54
Nava-Martínez EC, Flores-García E, Espinoza-Gomez H, Wakida FT (2012) Heavy metals pollution in the soil of an irregular urban settlement built on a former dumpsite in the city of Tijuana, Mexico. Environ Earth Sci 66:1239–1245
Oberfranken (2001) Probenahme bei Bauschutt und Erdaushub (Haufwerksbeprobung). Instructional material supplied by the Government of Upper Franconia, Bayreuth
Ossenkopf P, Pälchen W, Barth N, Rank G, Kardel K (1993) Geogene Belastung der Böden im Raum Freiberg mit Schwermetallen und Arsen. Sächsisches Landesamt für Umwelt und Geologie, Freiberg
Pälchen W, Rank G, Lange H, Tischendorf G (1987) Regionale Clarkewerte-Möglichkeiten und Grenzen ihrer Anwendung am Beispiel des Erzgebirges (DDR). Chem Erde 47:1–17
Reimer L (1985) Scanning electron microscopy: physics of image formation and microanalysis. Springer, Berlin
Salminen R, Batista MJ, Bidovec M et al (2005) Geochemical Atlas of Europe. Part 1. Background information, methodology and maps. Geological Survey of Finland, Espoo
Scheffer F, Schachtschabel P (2010) Lehrbuch der Bodenkunde. Springer, Heidelberg
Scheinert M (2007) Georadiochemische Untersuchungen zur Wechselwirkung und Verteilung von NOM-Spezies der Lanthaniden und chalkophilen Schwermetalle im Bereich historischer Bergbauhalden. Dissertation, University of Leipzig
Scheinert M, Kupsch H, Bletz B (2009) Geochemical investigations of slags from the historical smelting in Freiberg, Erzgebirge (Germany). Chem Erde 69(1):81–90
Scherchan O (1980) Methodische Untersuchungen zur geochemischen Bilanz zwischen Muttergestein, Böden und Umweltbelastung in der Umgebung Freiberg. Dissertation, TU Bergakademie Freiberg
Singer PC, Stumm W (1970) Acidic mine drainage: the rate-determining step. Science 167:1121–1123
Smuda J, Dold B, Friese K, Morgenstern P, Glaesser W (2007) Mineralogical and geochemical study of element mobility at the sulfide-rich Excelsior waste rock dump from the polymetallic Zn–Pb–(Ag–Bi–Cu) deposit, Cerro de Pasco, Peru. J Geochem Explor 92:97–110
Steuer H (1993) Bergbau auf Silber und Kupfer im Mittelalter. In: Steuer H, Zimmermann U (eds) Alter Bergbau in Deutschland, Stuttgart, pp 75–91
Strosnider WHJ, López FSL, Nairn RW (2011) Acid mine drainage at Cerro Rico de Potosí I: unabated high-strength discharges reflect a five century legacy of mining. Environ Earth Sci 64:899–910
Taylor MP, Mackay AK, Hudson-Edwards KA, Holz E (2010) Soil Cd, Cu, Pb and Zn contaminants around Mount Isa city, Queensland, Australia: potential sources and risks to human health. Appl Geochem 25:841–855
Tichomirowa M, Heidel C, Junghans M et al (2010) Sulfate and strontium water source identification by O, S and Sr isotopes and their temporal changes (1997–2008) in the region of Freiberg, central-eastern Germany. Chem Geol 276:104–118
TK10 (2010) Topographic map 1:10,000, sheet 5046-SW Freiberg, © Staatsbetrieb Geobasisinformation und Vermessung Sachsen
Ullrich SM, Ramsey MH, Helios-Rybicka E (2000) Total and exchangeable of heavy metals in soils near Bytom, an area of Pb/Zn mining and smelting in Upper Silesia, Poland. App Geochem 14:187–196
Vaughan BJ, Craig JR (1978) Mineral chemistry of metal sulfides. Cambridge University Press, Cambridge
Wagenbreth O, Wächtler E (1986) Der Freiberger Bergbau: Technische Denkmale und Geschichte. Deutscher Verlag für Grundstoffindustrie, 1 edn, Leipzig
Wakida FT, Lara D, Temores-Pená J et al (2008) Heavy metals in sediments of the Tecate River. Environ Geol 54:637–642
Wedepohl KH (1995) The composition of the continental crust. Geochim Cosmochim Acta 59:1217–1232
Wolf BM (1999) Mobilisierung und Migration von anthropogen eingetragenem Uran und Thorium in ehemaligen Bergbaugebieten in Thüringen und Sachsen. Dissertation, University of Mainz
Schmidt-Hammel T (undated) Übersicht über die Bodentypen des Ost-Erzgebirges. http://www.vychodnikrusnohori.org/uploads/media/17_Boden_farbig.pdf
Ziechmann W, Müller-Wegener U (1990) Bodenchemie. BI Wissenschafts, Mannheim
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The author thanks all colleagues from the HZDR (formerly IIF) and the University of Leipzig for the support during the doctoral and subsequent scientific work. Thanks to the reviewers, R. Kryza and O. Kolditz, for their constructive comments.
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Stockmann, M., Hirsch, D., Lippmann-Pipke, J. et al. Geochemical study of different-aged mining dump materials in the Freiberg mining district, Germany. Environ Earth Sci 68, 1153–1168 (2013). https://doi.org/10.1007/s12665-012-1817-6
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DOI: https://doi.org/10.1007/s12665-012-1817-6