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Synthesis, spectral, magnetic, thermal and biological aspects of pyromellitic dianhydride based co-ordination polymers

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International Journal of Plastics Technology

Abstract

A ligand, 2, 5-bis (4-nitrophenylcarbamoyl) terephthalic acid (bnpctpa) was synthesized by using dianhydride of 1, 2, 4, 5-benzenetetracarboxylic (pyromellitic dianhydride–abbreviated PMDA) with 4-nitro aniline. Novel Co-ordination polymers of this bis-ligand were prepared with Cu(II), Ni(II), Co(II), Mn(II) and Zn(II) metal salts. The co-ordination polymers and parent ligand were characterized by elemental analysis, spectral studies, thermogravimetry, number-average molecular weights (Mn), diffuse reflectance spectral studies and magnetic susceptibilities. The biological activity of all the samples has also been monitored against plant pathogens.

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Acknowledgement

One of the authors Yogesh S. Patel is greatly thankful to UGC for sanctioning his Teacher Fellowship Under the Scheme of Faculty Improvement Programme for the research work.

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Authors and Affiliations

  1. Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar, Gujarat, India

    Yogesh S. Patel & Hasmukh S. Patel

  2. Central Institute of Plastics Engineering and Technology, Ahmedabad, Gujarat, India

    Bolishetti Srinivasulu

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  1. Yogesh S. Patel
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  2. Hasmukh S. Patel
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  3. Bolishetti Srinivasulu
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Correspondence to Hasmukh S. Patel.

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Patel, Y.S., Patel, H.S. & Srinivasulu, B. Synthesis, spectral, magnetic, thermal and biological aspects of pyromellitic dianhydride based co-ordination polymers. Int J Plast Technol 16, 117–124 (2012). https://doi.org/10.1007/s12588-012-9035-3

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  • DOI: https://doi.org/10.1007/s12588-012-9035-3

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