Abstract
Postdepositional history of the Sanganeh Formation (Lower Cretaceous), in eastern Kopet-Dagh Basin in northeast of Iran was considered. The Sanganeh Formation mainly composed of shale, marl, siltstone, and interbeds of limestone. The study of limestone interbeds led to recognizing several diagenetic processes including micritization, cementation (including isopachous rim, syntaxial overgrowth, equant mosaic spary, blocky, and poikilotopic cements), neomorphism, compaction (including physical and chemical), dolomitization, pyritization, fracturing, and vein filling. Limestone samples were analyzed for major (Ca, Mg) and minor (Na, Sr, Fe, and Mn) elements as well as oxygen and carbon isotopic compositions (δ 18O and δ 13C). Many of diagenetic processes such as cementation, neomorphism, dolomitization, and pyritization happen in several diagenetic environments. In order to differentiate them, geochemical data (including element and isotopic) have been used. In addition, blocky, mosaic spar, and poikilotopic cements show different luminescence under the cathodoluminescence microscope that is accordant to their geochemical contents. Therefore, the luminescence was a guide for recognizing cements and neomorphed lime muds of different diagenetic environments of studied samples. The neomorphed lime muds and lime muds were differentiated by geochemical data. The marine lime muds and micrites includes mean δ 18O 0.04 ‰, δ 13C 1.95 ‰, Na mean 1491.21 ppm, Sr mean 5233.68 ppm, Fe mean 61.34 ppm, and Mn mean 35.96. The meteoric cements and includes mean δ 18O −1.02 ‰, δ 13C 8.85‰, Na mean 126.34 ppm, Sr mean 300.03 ppm, Fe mean 2883.88 ppm, and Mn mean 382.88. The burial cements and neomorphed lime mud samples contained mean δ 18O −9 ‰, δ 13C −6.33‰, Na mean 308.29 ppm, Sr mean 731.72 ppm, Fe mean 816.02 ppm, and Mn mean 37.28. Paragenetic sequence of the Sanganeh Formation carbonate rocks was interpreted and depicted using integration of petrographic, major and trace elements, and isotopic data in three phases including (i) eogenesis, (ii) mesogenesis, and (iii) telogenesis.
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References
Adabi MH, MehmanDousti E (2008) Microfacies and geochemistry of the Ilam Formation in the Tang-E Rashid area, Izeh, S.W. Iran. J Asian Earth Sci 33:267–277
Afshar-Harb A (1979) The stratigraphy, tectonics and petroleum geology of the Kopet-Dagh region, Northern Iran., PhD Thesis, Imperial Collage of science and Technology, University of London, London, 316 p
Afshar-Harb A (1982) Geological map of the Sarakhs area, scale 1:250,000, Geological Survey of Iran
Afshar-Harb A (1994) Geology of the Kopet-Dagh Iran (in Persian). Geology Survey, Tehran, 265 p
Ahmad AHM, Bhat GMM, Azim Khan H (2006) Depositional environments and diagenesis of the kuldhar and Keera Dome carbonates (Late Bathonian–Early Callovian) of Western India. J Asian Earth Sci 27:765–778
Alavi M (1996) Tectonostratigraphy synthesis and structural style of the Alborz Mountain system in northern Iran. Geodynamic 21:1–33
Allameh A, Ariaei AA, Vaziri SM, Moradian F (2008) Palynology and sedimentary environment of the Sanganeh Formation at Qhareh-Su area based on dinoflagellates, 4th Geology and Environmental Congress, Iran
Allan JR, Matthews RK (1982) Isotope signatures associated with early meteoric diagenesis. Sedimentology 29:797–817
Armstrong-Altrin JS, YongIlLee YI, Verma SP, Worden RH (2009) Carbon, oxygen, and strontium isotope geochemistry of carbonate rocks of the upper Miocene Kudankulam Formation, southern India: Implications for paleoenvironment and diagenesis. Chemie der erde 69:45–60
Banerjee S, Jeevankumar S, Sanyal S, Bhattacharyya SK (2006) Stable Isotope ratios and nodular limestone of the Proterozoic Rohtas limestone: Vindhyan basin, India. Carbonates Evaporites 21(2):133–143
Banerjee S, Bhattacharya SK, Sarkar S (2007) Carbon and oxygen isotopic variations in peritidal stromatolite cycles, Paleoproterozoic Kajrahat Limestone, Vindhyan basin of central India. J Asian Earth 29:823–831
Berberian M, King GCP (1981) Toward a paleogeography and tectonic evolution of Iran. Can J Earth Sci 18:210–265
Brigaud B, Christophe Durlet C, Deconinck JF, Benoît Vincent B, Thierry J, Trouiller A (2009) The origin and timing of multiphase cementation in carbonates: Impact of regional scale geodynamic events on the Middle Jurassic Limestones diagenesis (Paris Basin, France). Sediment Geol 222:161–180
Budd DA, Land LS (1990) Geochemical imprint of meteoric diagenesis in Holocene ooid sands, Schooner Cays, Bahamas: correlation of calcite cement geochemistry with extent ground waters. J Sedimentary Petrology 60:361–378
Budd D, Park A, Ortoleva P (2002) Diagenesis and compaction of limestones associated with early burial and meteoric and sea water infiltrations: a Basin, RTM simulation of the Florida carbonate platform., Geologic Society of America Annual Meeting, Abstract, Denver
Calvo R, Ayalon A, Bein A, Eytan Sass E (2011) Chemical and isotopic composition of diagenetic carbonate cements and its relation to hydrocarbon accumulation in the Heletz-Kokhav oil field (Israel). J Geochem Explor 108:88–98
Cantrell DL (2006) Cortical fabrics of Upper Jurassic ooids, Arab Formation, Saudi Arabia, Implications for original carbonate mineralogy. Sediment Geol 186:157–170
Chacon EE, Berrendero E, Pichel FG (2006) Biogeological signatures of microboring cyanobacterial communities in marine carbonates from Cabo Rojo, Puerto Rico. Sediment Geol 185:215–228
Choquette PW, James NP (1987) Diagenesis in Limestone-3, the deep burial environment. Geosci Can 14:3–35
Choquette PW, James NP (1990) Limestones-the burial diagenetic environment, In, I.A., Mcllreath, D. W., Morrow (Editors), Diagenesis., Geoscience Canada, Reprint Series, 4, p. 75–112
Czerniakowski LA, Lohmann K, Wilson JL (1984) Closed-system marine burial diagenesis: isotopic data from the Austin Chalk and its components. Sedimentology 31:863–877
Dickson JAD (1965) A modified staining technique for carbonate in thin section. Nature 205:285
Flügel E (2010) Microfacies of Carbonate Rocks Analysis Interpretation and Application., Springer-Verlag, 976 pp
Folk RL (1980) Petrology of Sedimentary Rocks., Hemphill Publishing Co., Austin, Texas, 182 pp
Fu Q, Qing H (2011) Medium and coarsely crystalline dolomites in the Middle Devonian Ratner Formation, southern Saskatchewan, Canada: origin and pore evolution. Carbonates Evaporites 26(2):111–125
Fu Q, Qing H, Bergman KM (2006) Dolomitization of the Middle Devonian Winnipegosis carbonates in south-central Saskatchewan, Canada. Sedimentology 53:825–848
Habermann D, Neuser RD, Richter DK (1998) Low limit of Mn++ activated cathodoluminescence of calcite, state of the art. Sediment Geol 116:13–24
Haijun Z, Lin D, Xunlian W, Qingshan W, Guoying X (2006) Carbonate diagenesis controlled by glacioeustatic sea-level changes: a case study from the Carboniferous-Permian Boundary Section at Xikou, China. J China Univ Geosci 17(2):103–114
Heidari A, Gonzalez LA, Mahboubi A, Moussavi-Harami R, Ludvigson GA, Chakrapani GJ (2014) Accepted, Diagenetic Model of Carbonate Rocks of Guri Member of Mishan Formation (Lower to Middle Miocene) SE Zagros Basin Iran., Journal of the Geological Society of India
Hood AVS, Wallace MW (2012) Synsedimentary diagenesis in a Cryogenian reef complex: ubiquitous marine dolomite precipitation. Sediment Geol 255–256:56–71
Immel H, Seyed-Emami K, Afshar-Harb A (1997) Kreide-Ammoniten aus dem iranischen teil des Koppeh-Dagh (NE Iran). Zitteliana 21:159–190
Immenhauser A, Kenter JAM, Ganssen G, Bahamonde JR, Van Vliet A, Saher MH (2002) Origin and significance of isotope shifts in Pennsylvanian carbonates (Asturias, NW Spain). J Sediment Res 72:82–92
Immenhauser A, Della Porta G, Kenter JAM, Bahamonde JR (2003) An alternative model for positive shifts in shallow-marine carbonate δ13C and δ18O. Sedimentology 50:953–959
Immenhauser A, Holdmden C, Patterson WP (2007) Interpreting the carbon-isotope record of ancient epeiric seas: lessons from the Recent. In Dynamics of Epeiric Seas B.R. Pratt., C. Holmden (editors)., Geological Association of Canada, Special Paper no. 48, p. 137–74
Joachumski MM (1994) Subaerial exposure and deposition of shallowing-upward sequences: evidence from stable isotopes of Purbeckianperitidal carbonates (basal Cretaceous), Swiss and French Jura Mountains. Sedimentology 41:805–824
Kalantari A (1969) Foraminifera from the middle Jurassic-Cretaceous succession of Kopet Dagh region (NE Iran), 298 pp. Exploration and Production, NIOC, Geological Laboratory Publication 3, Tehran (Ph.D. thesis, London university).
Khosravi Alghar R, Ghasemi-Nejad E (2006) Consideration of the sedimentary environments during sedimentation of the Sanganeh Formation at Qaleh Now area (east Kopet-Dagh Basin) using organic maters (organofacies), 10th Congress of Iranian Society of Geology, Iran
Lohmann KC (1988) Geochemical patterns of meteoric diagenetic systems and their application to studies of paleokarst. In: James NP, Choquette PW (eds) Paleokarst. Springer, New York, pp 58–80
Mabrouk A, Belayouni H, Jarvis I, Moody RTJ (2006) Strontium, δ18O and δ13C as palaeo-indicators of unconformities: Case of the Aleg and Abiod formations (Upper Cretaceous) in the Miskar Field, southeastern Tunisia. Geochem J 40:405–424
Machel HG (2004) Concepts and models of dolomitization, a critical reappraisal., Geological Society, London, Special Publications, v. 235, p. 7–63
MacNeil A, Jones B (2003) Dolomitization of the Pedro Castle Formation (Pliocene), Cayman Brac, British West Indies. Sediment Geol 162:219–238
Mahboubi A, Moussavi-Harami R, Carpenter SJ, Aghaei A, Collins LB (2010) Petrographical and geochemical evidences for paragenetic sequence interpretation of diagenesis in mixed siliciclastic carbonate sediments: Mozduran Formation (Upper Jurassic), south of Agh-Darband, NE Iran. Carbonate and Evaporites 25:231–246
McGill MM, Walker KR (1982) Diagenetic study of the Holston Limestone, paragenesis of cements and evaluation of geochemistry (abstracts)., Geolological Society of America Abstract with Programme, p. 40
Milliman JD (1974) Marine carbonates. Springer- Verlag, New York, 375pp
Moore CH (2001) Carbonate reservoirs, porosity evolution and diagenesis in a sequence stratigraphic framework, Developments in Sedimentology. Elsevier, Amsterdam, p 55, 452 pp
Motamedalshariati M, Sadeghi A, Moussavi-Harami R (2010) New foraminifera and morphogroups from Sanganeh Formation in Takal Kuh Section, western Kopet-Dagh Basin. Stratigr and Sediment Res 40(3):137–150
Moussavi-Harami R, Brenner RL (1992) Geohistory analysis and petroleum reservoir characteristics of Lower Cretaceous (Neocomian) Sandstone, eastern portion of Kopet-Dagh basin, northeast Iran. Am Assoc Petrol Geol Bull 76:1200–1208
Nabavieh SM (1998) Geological map of the Kalat area, scale 1:100,000, Geological Survey of Iran
Raisossadat SN (2002) Lower Cretacous (Upper Barremian-Lower Albian) Ammonite faunas of the Kopet-Dagh Basin, NE Iran., Unpublished Ph.D. Thesis, University College London, London, UK, 337 pp
Raisossadat SN (2006) The ammonite family Parahoplitidae in the Sanganeh Formation of the Kopet-Dagh basin, north-eastern Iran. Cretac Res 27:907–922
Raisossadat SN, Shokri MH (2011) Biostratigraphic studies of Lower Cretaceous (Upper Baremian - Lower Aptian) Sarcheshmeh and Sanganeh Formations in Kopet-Dagh, NE Iran: an integration of calcareous nannofossils and ammonites stratigraphies. Stratigr Geol Correl 19(2):70–86
Ruttner AW (1993) Southern borderland of Triassic Laurasia in northeast Iran. Geol Rund 82:110–120
Samankassou E, Tresch J, Strasser A (2005) Origin of peloids in Early Cretaceous deposits, Dorset. South England Facies 51:264–273
Sanders D (2001) Burrow-mediated carbonate dissolution in rudistbiostromes (Aurisina, Italy), implications for taphonomy in tropical, shallow subtidalarbonate environments. Palaeogeogr Palaeoclimatol Palaeoecol 168:39–74
Shokri, N., Heidari., A, 2012, Palynofacies of the Sanganeh Formation (Lower cretaceous) in the east of Kopet-Dagh basin, NE Iran, the 45th annual meeting of AASP, p. 45.
Sibley DF, Gregg JM (1987) Classification of dolomite rock texture. J Sediment Petrol 57:967–975
South DL, Talbot MR (2000) The sequence stratigraphic framework of carbonate diagenesis within transgressive fan-delta deposits, Sant Lorenc Ë del Munt fan-delta complex, SE Ebro Basin, NE Spain. Sediment Geol 138:179–198
Taylor KG, Macquaker JHS (2000) Early diagenetic pyrite morphology in a mudstone-dominated succession: the Lower Jurassic Cleveland Ironstone Formation, eastern England. Sediment Geol 131:77–86
Tucker ME, Wright VP (1990) Carbonate sedimentology. Blackwell Scientific Publications., 482pp
Ufnar D, Gonzalez L, Ludvigson G (2004) Diagenetic overprinting of the sphaero siderite palaeoclimate proxy: are records of pedogenic groundwater δ 18O values preserved? Sedimentology 51:127–144
Veizer J (1983) Chemical diagenesis of carbonates, theory and application of trace element technique. SEPM Short Course 10:3.1–3.100
Veizer J, Ala D, Azmy K, Bruckschen P, Buhl D, Bruhn F, Carden GAF, Diener A, Ebneth S, Godderis Y, Jasper T, Korte C, Pawellek F, Podlaha OG, Strauss H (1999) 87Sr/86Sr, δ13C and δ18O evolution in Phanerozoic seawater. Chem Geol 161:59–88
Winefield PR, Nelson CS, Hodder APW (1996) Discriminating temperate carbonates and their diagenetic environments using bulk elemental geochemistry, a reconnaissance study based on New Zealand Cenozoic Limestones. Carbonates Evaporites 11:19–31
Acknowledgment
The authors appreciate the financial support of the Ferdowsi University of Mashhad and The University of Kansas. We are grateful for the Keck Paleoenvironmental and Environmental Stable Isotope Laboratory (KPESIL) at the KU, USA. Special thanks for Gregory Cane in KPESIL (The United States) and Masato in the XRF laboratory of KU for their valuable and kindly helps in the Laboratory. We acknowledge the thin section laboratory and SEM laboratory in the Ferdowsi University of Mashhad.
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Heidari, A., Shokri, N., Ghasemi-Nejad, E. et al. Application of petrography, major and trace elements, carbon and oxygen isotope geochemistry to reconstruction of diagenesis of carbonate rocks of the Sanganeh Formation (Lower Cretaceous), East Kopet-Dagh Basin, NE Iran. Arab J Geosci 8, 4949–4967 (2015). https://doi.org/10.1007/s12517-014-1548-y
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DOI: https://doi.org/10.1007/s12517-014-1548-y