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Titanium nitride hollow nanospheres with strong lithium polysulfide chemisorption as sulfur hosts for advanced lithium-sulfur batteries

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Abstract

Lithium-sulfur batteries are promising electrochemical energy storage devices because of their high theoretical specific capacity and energy density. An ideal sulfur host should possess high conductivity and embrace the physical confinement or strong chemisorption to dramatically suppress the polysulfide dissolution. Herein, uniform TiN hollow nanospheres with an average diameter of ~160 nm have been reported as highly efficient lithium polysulfide reservoirs for high-performance lithium-sulfur batteries. Combining the high conductivity and chemical trapping of lithium polysulfides, the obtained S/TiN cathode of 70 wt.% sulfur content in the composite delivered an excellent long-life cycling performance at 0.5C and 1.0C over 300 cycles. More importantly, a stable capacity of 710.4 mAh·g−1 could be maintained even after 100 cycles at 0.2C with a high sulfur loading of 3.6 mg·cm−1. The nature of the interactions between TiN and lithium polysulfide species was investigated by X-ray photoelectron spectroscopy studies. Theoretical calculations were also carried out and the results revealed a strong binding between TiN and the lithium polysulfide species. It is expected that this class of conductive and polar materials would pave a new way for the high-energy lithium-sulfur batteries in the future.

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Acknowledgements

This work is supported by the National Nature Science Foundation of China (No. 21471091), 111 Project (No. B12015), the Fundamental Research Funds of Shandong University (No. 2015JC007), Academy of Sciences large apparatus United Fund (No. 11179043), and the Taishan Scholar Project of Shandong Province (No. ts201511004).

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Authors and Affiliations

  1. Key Laboratory of Colloid & Interface Chemistry (Shandong University), Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, China

    Chuanchuan Li, Lin Zhu, Yingyue Zhao & Liqiang Xu

  2. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin, 300071, China

    Liqiang Xu

  3. Faculty of Science, Beijing University of Chemical Technology, Beijing, 100000, China

    Jingjing Shi & Jun Lu

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  1. Chuanchuan Li
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  2. Jingjing Shi
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  3. Lin Zhu
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Correspondence to Jun Lu or Liqiang Xu.

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Titanium nitride hollow nanospheres with strong lithium polysulfide chemisorption as sulfur hosts for advanced lithium-sulfur batteries

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Li, C., Shi, J., Zhu, L. et al. Titanium nitride hollow nanospheres with strong lithium polysulfide chemisorption as sulfur hosts for advanced lithium-sulfur batteries. Nano Res. 11, 4302–4312 (2018). https://doi.org/10.1007/s12274-018-2017-9

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