Skip to main content
Log in

Functional nanogenerators as vibration sensors enhanced by piezotronic effects

  • Research Article
  • Published:
Nano Research Aims and scope Submit manuscript

Abstract

ZnO nanomaterials have been shown to have novel applications in optoelectronics, energy harvesting and piezotronics, due to their coupled semiconducting and piezoelectric properties. Here a functional nanogenerator (FNG) based on ZnO nanowire arrays has been fabricated, which can be employed to detect vibration in both self-powered (SP) and external-powered (EP) modes. In SP mode, the vibration responses of the FNG can be measured through converting mechanical energy directly into an electrical signal. The FNG shows consistent alternating current responses (relative error < 0.37%) at regular frequencies from 1 to 15 Hz. In EP mode, the current responses of FNG are significantly enhanced via the piezotronic effect. Under a forward bias of 3 V, the sensor presented a sensitivity of 3700% and an accurate measurement (relative error < 0.91%) of vibration frequencies in the range 0.05–15 Hz. The results show that this type of functional nanogenerator sensor can detect vibration in both SP and EP modes according to the demands of the applications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Wang, Z. L.; Song, J. Piezoelectric nanogenerators based on zinc oxide nanowire arrays. Science 2006, 312, 242–246.

    Article  Google Scholar 

  2. Fan, F. R.; Lin, L.; Zhu, G.; Wu, W.; Zhang, R.; Wang, Z. L. Transparent triboelectric nanogenerators and self-powered pressure sensors based on micropatterned plastic films. Nano Lett. 2012, 12, 3109–3114.

    Article  Google Scholar 

  3. Yang, Y.; Pradel, K. C.; Jing, Q.; Wu, J. M.; Zhang, F.; Zhou, Y.; Zhang, Y.; Wang, Z. L. Thermoelectric nanogenerators based on single Sb-doped ZnO micro/nanobelts. ACS Nano 2012, 6, 6984–6989.

    Article  Google Scholar 

  4. Xu, S.; Qin, Y.; Xu, C.; Wei, Y.; Yang, R.; Wang, Z. L. Self-powered nanowire devices. Nat. Nanotechnol. 2010, 5, 366–373.

    Article  Google Scholar 

  5. Yang, Y.; Lin, L.; Zhang, Y.; Jing, Q.; Hou, T. C.; Wang, Z. L. Self-powered magnetic sensor based on a triboelectric nanogenerator. ACS Nano 2012, 6, 10378–10383.

    Article  Google Scholar 

  6. Li, Z.; Wang, Z. L. Air/liquid-pressure and heartbeat-driven flexible fiber nanogenerators as a micro/nano-power source or diagnostic sensor. Adv. Mater. 2011, 23, 84–89.

    Article  Google Scholar 

  7. Yu, A.; Jiang, P.; Wang, Z. L. Nanogenerator as self-powered vibration sensor. Nano Energy 2012, 1, 418–423.

    Article  Google Scholar 

  8. Dai, Y.; Zhang, Y.; Wang, Z. L. The octa-twin tetraleg ZnO nanostructures. Solid State Commun. 2003, 126, 629–633.

    Article  Google Scholar 

  9. Yang, Y.; Qi, J.; Liao, Q.; Li, H.; Wang, Y.; Tang, L.; Zhang, Y. High-performance piezoelectric gate diode of a single polar-surface dominated ZnO nanobelt. Nanotechnology 2009, 20, 125201.

    Article  Google Scholar 

  10. Dai, Y.; Zhang, Y.; Bai, Y. Q.; Wang, Z. L. Bicrystalline zinc oxide nanowires. Chem. Phys. Lett. 2003, 375, 96–101.

    Article  Google Scholar 

  11. Yang, Y.; Liao, Q.; Qi, J.; Guo, W.; Zhang, Y. Synthesis and transverse electromechanical characterization of single crystalline ZnO nanoleaves. Phys. Chem. Chem. Phys. 2010, 12, 552–555.

    Article  Google Scholar 

  12. Zhang, X.; Yan, X.; Zhao, J.; Qin, Z.; Zhang, Y. Structure and photoluminescence of S-doped ZnO nanorod arrays. Mater. Lett. 2009, 63, 444–446.

    Article  Google Scholar 

  13. Wang, Z. L. Nanopiezotronics. Adv. Mater. 2007, 19, 889–892.

    Article  Google Scholar 

  14. Wang, Z. L. Piezopotential gated nanowire devices: Piezotronics and piezo-phototronics. Nano Today 2010, 5, 540–552.

    Article  Google Scholar 

  15. Zhang, Y.; Yan, X.; Yang, Y.; Huang, Y.; Liao, Q.; Qi, J. Scanning probe study on the piezotronic effect in ZnO nanomaterials and nanodevices. Adv. Mater. 2012, 24, 4647–4655.

    Article  Google Scholar 

  16. Zhou, J.; Gu, Y.; Fei, P.; Mai, W.; Gao, Y.; Yang, R.; Bao, G.; Wang, Z. L. Flexible piezotronic strain sensor. Nano Lett. 2008, 8, 3035–3040.

    Article  Google Scholar 

  17. Yang, Y.; Qi, J. J.; Gu, Y. S.; Wang, X. Q.; Zhang, Y. Piezotronic strain sensor based on single bridged ZnO wires. Physica Status Solidi (RRL) — Rapid Research Letters 2009, 3, 269–271.

    Article  Google Scholar 

  18. Gullapalli, H.; Vemuru, V. S.; Kumar, A.; Botello-Mendez, A.; Vajtai, R.; Terrones, M.; Nagarajaiah, S.; Ajayan, P. M. Flexible piezoelectric ZnO-paper nanocomposite strain sensor. Small 2010, 6, 1641–1646.

    Article  Google Scholar 

  19. Wang, X.; Zhou, J.; Song, J.; Liu, J.; Xu, N.; Wang, Z. L. Piezoelectric field effect transistor and nanoforce sensor based on a single ZnO nanowire. Nano Lett. 2006, 6, 2768–2772.

    Article  Google Scholar 

  20. Buchine, B. A.; Hughes, W. L.; Degertekin, F. L.; Wang, Z. L. Bulk acoustic resonator based on piezoelectric ZnO belts. Nano Lett. 2006, 6, 1155–1159.

    Article  Google Scholar 

  21. Law, M.; Greene, L. E.; Johnson, J. C.; Saykally, R.; Yang, P. D. Nanowire dye-sensitized solar cells. Nat. Mater. 2005, 4, 455–459.

    Article  Google Scholar 

  22. Zhang, Z.; Yao, K.; Liu, Y.; Jin, C.; Liang, X.; Chen, Q.; Peng, L. M. Quantitative analysis of current-voltage characteristics of semiconducting nanowires: Decoupling of contact effects. Adv. Func. Mater. 2007, 17, 2478–2489.

    Article  Google Scholar 

  23. Freeouf, J. L. Schottky barriers: An effective work function model. Appl. Phys. Lett. 1981, 39, 727–729.

    Article  Google Scholar 

  24. Mora-Sero, I.; Bertoluzzi, L.; Gonzalez-Pedro, V.; Gimenez, S.; Fabregat-Santiago, F.; Kemp, K. W.; Sargent, E. H.; Bisquert, J. Selective contacts drive charge extraction in quantum dot solids via asymmetry in carrier transfer kinetics. Nat. Commun. 2013, 4, 2272.

    Google Scholar 

  25. Bora, T.; Kyaw, H. H.; Sarkar, S.; Pal, S. K.; Dutta, J. Highly efficient ZnO/Au schottky barrier dye-sensitized solar cells: Role of gold nanoparticles on the charge-transfer process. Beilstein Journal of Nanotechnology 2011, 2, 681–690.

    Article  Google Scholar 

  26. Sze, S.; Ng, K. K. Metal-semiconductor contacts. Phys. Sem. Dev. 2006, 134–196.

    Google Scholar 

  27. Yang, R.; Qin, Y.; Dai, L.; Wang, Z. L. Power generation with laterally packaged piezoelectric fine wires. Nat. Nanotechnol. 2009, 4, 34–39.

    Article  Google Scholar 

  28. Wang, Z. L. Piezotronic and piezophototronic effects. J. Phys. Chem. Lett. 2010, 1, 1388–1393.

    Article  Google Scholar 

  29. Zhang, Y.; Liu, Y.; Wang, Z. L. Fundamental theory of piezotronics. Adv. Mater. 2011, 23, 3004–3013.

    Article  Google Scholar 

  30. Zimmermann, A.; Fuller, E. R.; Rödel, J. Residual stress distributions in ceramics. J. Am. Ceram. Soc. 1999, 82, 3155–3160.

    Article  Google Scholar 

  31. Gao, Z.; Zhou, J.; Gu, Y.; Fei, P.; Hao, Y.; Bao, G.; Wang, Z. L. Effects of piezoelectric potential on the transport characteristics of metal-ZnO nanowire-metal field effect transistor. J. Appl. Phys. 2009, 105, 113707.

    Article  Google Scholar 

  32. Yang, Y.; Qi, J.; Zhang, Y.; Liao, Q.; Tang, L.; Qin, Z. Controllable fabrication and electromechanical characterization of single crystalline Sb-doped ZnO nanobelts. Appl. Phys. Lett. 2008, 92, 183117.

    Article  Google Scholar 

  33. Pan, C.; Li, Z.; Guo, W.; Zhu, J.; Wang, Z. L. Fiber-based hybrid nanogenerators for/as self-powered systems in biological liquid. Angew. Chem. Int. Edit. 2011, 50, 11192–11196.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yue Zhang.

Additional information

These two authors contributed equally to this work.

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhang, Z., Liao, Q., Yan, X. et al. Functional nanogenerators as vibration sensors enhanced by piezotronic effects. Nano Res. 7, 190–198 (2014). https://doi.org/10.1007/s12274-013-0386-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12274-013-0386-7

Keywords

Navigation