Nano Research

, Volume 5, Issue 1, pp 20–26

Sulfur-doped zinc oxide (ZnO) Nanostars: Synthesis and simulation of growth mechanism

  • Jinhyun Cho
  • Qiubao Lin
  • Sungwoo Yang
  • Jay G. SimmonsJr.
  • Yingwen Cheng
  • Erica Lin
  • Jianqiu Yang
  • John V. Foreman
  • Henry O. Everitt
  • Weitao Yang
  • Jungsang Kim
  • Jie Liu
Research Article

DOI: 10.1007/s12274-011-0180-3

Cite this article as:
Cho, J., Lin, Q., Yang, S. et al. Nano Res. (2012) 5: 20. doi:10.1007/s12274-011-0180-3

Abstract

We present a bottom-up synthesis, spectroscopic characterization, and ab initio simulations of star-shaped hexagonal zinc oxide (ZnO) nanowires. The ZnO nanostructures were synthesized by a low-temperature hydrothermal growth method. The cross-section of the ZnO nanowires transformed from a hexagon to a hexagram when sulfur dopants from thiourea [SC(NH2)2] were added into the growth solution, but no transformation occurred when urea (OC(NH2)2) was added. Comparison of the X-ray photoemission and photoluminescence spectra of undoped and sulfur-doped ZnO confirmed that sulfur is responsible for the novel morphology. Large-scale theoretical calculations were conducted to understand the role of sulfur doping in the growth process. The ab initio simulations demonstrated that the addition of sulfur causes a local change in charge distribution that is stronger at the vertices than at the edges, leading to the observed transformation from hexagon to hexagram nanostructures. https://static-content.springer.com/image/art%3A10.1007%2Fs12274-011-0180-3/MediaObjects/12274_2011_180_Fig1_HTML.gif

Keywords

ZnO nanostarhexagramthioureasulfur dopinggrowth mechanismab initio simulation

Supplementary material

12274_2011_180_MOESM1_ESM.pdf (226 kb)
Supplementary material, approximately 225 KB.

Copyright information

© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2012

Authors and Affiliations

  • Jinhyun Cho
    • 1
  • Qiubao Lin
    • 2
    • 3
  • Sungwoo Yang
    • 2
  • Jay G. SimmonsJr.
    • 2
  • Yingwen Cheng
    • 2
  • Erica Lin
    • 2
  • Jianqiu Yang
    • 2
  • John V. Foreman
    • 4
  • Henry O. Everitt
    • 4
    • 5
  • Weitao Yang
    • 2
  • Jungsang Kim
    • 1
  • Jie Liu
    • 2
  1. 1.Department of Electrical and Computer Engineering, Fitzpatrick Institute for PhotonicsDuke UniversityDurhamUSA
  2. 2.Department of Chemistry, French Family Science CenterDuke UniversityDurhamUSA
  3. 3.School of ScienceJimei UniversityXiamenChina
  4. 4.U.S. Army Aviation and Missile Research, Development, and Engineering CenterWeapons Sciences DirectorateRedstone ArsenalUSA
  5. 5.Department of PhysicsDuke UniversityDurhamUSA