Abstract

We present a chemical vapor deposition (CVD) method for the growth of uniform single-walled carbon nanotube (SWNT) arrays on a stable temperature (ST)-cut single crystal quartz substrate using a mixture of methanol and ethanol as carbon source. It is found that introducing methanol during the growth can improve the density and the length of the well-aligned SWNTs in the arrays as well as increase the SWNT/quartz interaction. Obvious “up-shifts” of G-band frequencies in the Raman spectra have been found for the aligned SWNTs. A welldesigned control experiment shows that the G-band “up-shifts” originate from the strong interaction between SWNTs and the quartz substrate. It is believed that exploring this interaction will help to elucidate the growth mechanism; ultimately, this will help realize the promise of controlling the chirality of SWNTs.

Keywords

Single-walled carbon nanotube quartz wafer Raman spectroscopy G-band “up-shift” chemical vapor deposition (CVD)

Supplementary material

12274_2009_9093_MOESM1_ESM.pdf (433 kb)
Supplementary material, approximately 340 KB.

Copyright information

© Tsinghua University Press and Springer Berlin Heidelberg 2009