Research Article

Nano Research

, Volume 1, Issue 5, pp 412-419

Open Access This content is freely available online to anyone, anywhere at any time.

Nanotrains and self-assembled two-dimensional arrays built from carboranes linked by hydrogen bonding of dipyridones

  • Takashi SasakiAffiliated withDepartment of Chemistry, Department of Mechanical Engineering and Materials Science, Rice University
  • , Jason M. GuerreroAffiliated withDepartment of Chemistry, Department of Mechanical Engineering and Materials Science, Rice University
  • , Ashley D. LeonardAffiliated withDepartment of Chemistry, Department of Mechanical Engineering and Materials Science, Rice University
  • , James M. TourAffiliated withDepartment of Chemistry, Department of Mechanical Engineering and Materials Science, Rice University Email author 

Abstract

The strong hydrogen bonding ability of 2-pyridones were exploited to build nanotrains on surfaces. Carborane wheels on axles difunctionalized with 2-pyridone hydrogen bonding units were synthesized and displayed spontaneous formation of linear nanotrains by self-assembly on SiO2 or mica surfaces. Imaging using atomic force microscopy confirmed linear formations with lengths up to 5 µm and heights within the range of the molecular height of the carborance-tipped axles.

http://static-content.springer.com/image/art%3A10.1007%2Fs12274-008-8041-4/MediaObjects/12274_2008_8041_Fig1_HTML.jpg

Keywords

Nanovehicles nanotrains 2-pyridone hydrogen bonding self-assembly