A DNA-based approach to the carbon nanotube sorting problem
Carbon nanotube sorting, i.e., the separation of a mixture of tubes into different electronic types and further into species with a specific chirality, is a fascinating problem of both scientific and technological importance. It is one of those problems that are easy to describe but difficult to solve. Single-stranded DNA forms stable complexes with carbon nanotubes and disperses them effectively in water. A particular DNA sequence of alternating guanine (G) and thymine (T) nucleotides ((GT) n , with n = 10 to 45) self-assembles into an ordered supramolecular structure around an individual nanotube, in such a way that the electrostatic properties of the DNA-carbon nanotube hybrid depend on tube structure, enabling nanotube separation by anion-exchange chromatography. This review provides a summary of the separation of metallic and semiconducting tubes, and purification of single (n, m) tubes using the DNA-wrapping approach. We will present our current understanding of the DNA-carbon nanotube hybrid structure and separation mechanisms, and predict future developments of the DNA-based approach.
- A DNA-based approach to the carbon nanotube sorting problem
- Open Access
- Available under Open Access This content is freely available online to anyone, anywhere at any time.
Volume 1, Issue 3 , pp 185-194
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- Tsinghua Press
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- Carbon nanotube separation
- DNA-wrapped carbon nanotubes
- metallic and semiconducting tubes
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