Abstract
Palladium nanoparticles, generated by hydrogen reduction of Pd acetate, coordinated to a stereocomplexed 2,2′-bipyridine end-functionalized poly(lactic acid)-poly(ε-caprolactone) copolymer showed enhanced catalytic activity and chemoselectivity for the partial reduction of phenylacetylene compared to the reference system which did not contain the poly(ε-caprolactone). The obtained heterogeneous catalyst proved to be recyclable and suitable for selective phenylacetylene hydrogenation to styrene in solution and under solventless conditions.
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Frediani, M., Oberhauser, W., Rosi, L. et al. Palladium nanoparticles supported onto stereocomplexed poly(lactic acid)-poly(ε-caprolactone) copolymers for selective partial hydrogenation of phenylacetylene. Rend. Fis. Acc. Lincei 28 (Suppl 1), 51–58 (2017). https://doi.org/10.1007/s12210-017-0600-8
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DOI: https://doi.org/10.1007/s12210-017-0600-8