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Synthesis of new series of 4, 5-dihydroisoxazole-5-carboxylate derivatives for the study of their liquid crystalline properties

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Abstract

A new series of 4,5-dihydroisoxazole-5-carboxylate derivatives were synthesized via [3 + 2] cycloaddition reaction between ethyl acrylate and nitrile oxide generated in situ in presence of Chloramine-T. The synthesized derivatives were characterized by Mass, IR and NMR Spectroscopy and their mesomorphic behavior were studied using DSC and Polarising Optical Microscopy.

Synthesis and characterization of a few isoxazoline derivatives and their liquid crystalline properties are described.

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Acknowledgements

The authors would like to acknowledge University with Potential for Excellence (UPE), UGC for the financial support and University of Mysore for the laboratory facilities. Authors would also like to acknowledge Institute of Excellence, University of Mysore for the instrumentation facilities.

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Authors and Affiliations

  1. Department of Chemistry, University of Mysore, Manasagangotri, Mysuru, Karnataka, India

    SUMANA Y KOTIAN, NARAYANA U KUDVA N & K M LOKANATHA RAI

  2. Center for Materials Science and Technology, Vijnana Bhavan, University of Mysore, Manasagangotri, Mysuru, Karnataka, India

    K BYRAPPA

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  1. SUMANA Y KOTIAN
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  2. NARAYANA U KUDVA N
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  3. K M LOKANATHA RAI
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Correspondence to SUMANA Y KOTIAN.

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Supporting Information (SI)

1H and 13C NMR, Mass, XRD and POM images are available in Supplementary Information at www.ias.ac.in/chemsci.

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KOTIAN, S.Y., KUDVA N, N.U., LOKANATHA RAI, K.M. et al. Synthesis of new series of 4, 5-dihydroisoxazole-5-carboxylate derivatives for the study of their liquid crystalline properties. J Chem Sci 128, 1033–1036 (2016). https://doi.org/10.1007/s12039-016-1114-0

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  • DOI: https://doi.org/10.1007/s12039-016-1114-0

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