Abstract
In the present study, anorthite (CaAl2Si2O8) porcelain was fabricated using Ca(OH)2, Al(OH)3, quartz, aluminous cement and feldspar as raw materials. Two compositions were formulated (coded as CAQ and CFQ) and their physico-mechanical properties (%AP, BD, flexural strength) were studied and compared. CAQ (21.2 wt% Ca(OH)2, 44.5 wt% Al(OH)3 and 34.3 wt% quartz) shows very poor densification and strength even after heating at 1450°C, although anorthite formation is observed on heating it at various temperatures. On the other hand, CFQ (48.6 wt% aluminous cement, 29.37 wt% feldspar and 22.06 wt% quartz) achieved full densification and superior strength at 1450°C with more anorthite formation compared to CAQ. X-ray diffraction and scanning electron microscope studies were also carried out to analyse the phase and microstructure evolution. The coefficient of thermal expansion of the anorthite-based sample was found to be lower than quartz and mullite porcelain which suggests its application as cooking ware.
Similar content being viewed by others
References
Gdula R A 1971 Am. Ceram. Soc. Bull. 50 555
Kurama S and Ozel E 2004 Ceram. Int. 35 827
Correia R N 2003 Biomaterials 24 1317
Kavalci S, Yalamac E and Akkurt S 2008 Ceram. Int. 34 1629
Cheng X, Shanjun Ke, Wang Q, Wang H, Shui A and Liu P 2012 Ceram. Int. 38 3327
Tai W, Kimurab K and Jinnaic K 2002 J. Eur. Ceram. Soc. 22 463
Mergena A and Aslanog Z 2003 Ceram. Int. 29 667
Shanjun Ke, Cheng X, Wang Y, Wang Q and Wang H 2013 Ceram. Int. 39 4953
Pal M and Das S K 2012 Indoceram AIMPA 1 29
Pal M and Das S K 2013 Interceram 1 20
Hillebrand W F and Lundell G E F 1953 Applied inorganic analysis 2nd ed (New York: Wiley) p 507
Rietveld H M 1969 J. Appl. Crystallogr. 2 65
Young R A 1995 In Introduction to Rietveld method, The Rietveld method (ed) R A Young (Oxford: Oxford University Press) Chapter 1, p. 298
Goswami A P, Poddar R K, Khattry D K and Lodha A C 2000 In Refractories and furnaces — new options and new values (eds) G Banerjee and S K Das et al (Allied Publishers) ISBN 81-7764-109-3, p. 145
Marques V M F, Tulyaganov D U, Aguthopoulos S, Gataulin V K, Kothiyal G P and Ferreira J 2006 J. Eur. Ceram. Soc. 26 2503
Das S K, Pal M, Ghosh J, Pathi K V and Mondal S 2013 Trans. Indian. Inst. Met. 66 213
Acknowledgements
We thank the Director, CSIR – Central Glass and Ceramic Research Institute, for his kind permission to publish this paper. We also wish to thank SEM and XRD sections for their help in characterizing the samples.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
PAL, M., DAS, S. & DAS, S.K. Anorthite porcelain: synthesis, phase and microstructural evolution. Bull Mater Sci 38, 551–555 (2015). https://doi.org/10.1007/s12034-015-0855-6
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12034-015-0855-6