Abstract
There exist two distinct approaches to achieving flame retardancy in polymers, namely the additive type and the reactive type. In this case, new modified reactive flame-retardant (FR) alkyd resins (short, medium, and long oil alkyd) were produced by means of a condensation polymerization reaction between a linseed oil fatty acid and glycerol, to produce the monoglyceride as the ingredient source of the polyol used. This then reacted with phthalic anhydride, which was partially replaced with tetrabromophthalic anhydride (TBPA), as the ingredient source of the dibasic acid. The resulting resin was characterized using FTIR and 1H NMR spectral studies. The coatings of 50 ± 5 µm thickness were applied to the surface of wood, glass panels, and mild steel strips by means of a brush. The fire retardant capacity of the modified reactive FR alkyd resins was assessed using the limiting oxygen index (LOI) test. The physical, mechanical, and chemical properties were also examined to evaluate any drawbacks associated with the modification. The results of the LOI test indicate that the modified reactive FR alkyd resins exhibit an improved flame retardancy effect following an increase in the TBPA content within the alkyd resin backbone structure. Improvement to the mechanical properties of the modified resins was also observed, but chemical resistance was not significantly changed. Finally, the prepared reactive FR alkyd resins were observed to overcome a range of problems that weaken the attraction of additive FRs namely, poor compatibility, leaching, and the reduction in mechanical properties.
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Wang, J, Xin, Z, “Flame Retardancy, Thermal, Rheological, and Mechanical Properties of Polycarbonate/Polysilsesquioxane.” J. Appl. Polym. Sci., 115 (1) 330–337 (2010)
L. Joshua Jurs, “Development and Testing of Flame Retardant Additives and Polymers.” U.S. Department of Transportation Federal Aviation Administration Air Traffic Organization Operations Planning Office of Aviation Research and Development, Washington, DC 20591, 2007
Laoutid, F, Bonnaud, L, Alexandre, M, Lopez-Cuesta, J-M, Duboisa, Ph, “New Prospects in Flame Retardant Polymer Materials: From Fundamentals to Nanocomposites.” Mater. Sci. Eng., 63 (3) 100–125 (2009)
Mouritz, AP, Gibson, AG, Fire Properties of Polymer Composite Materials Solid Mechanics and Its Applications, Vol. 143. Springer, New York, 2006
Abd El-Wahab, H, Abd El-Fattah, M, Gabr, MY, “Preparation and Characterization of Flame Retardant Solvent Base and Emulsion Paints.” Prog. Org. Coat., 69 (3) 272–277 (2010)
Abd El-Wahab, H, Abd El-Fattah, M, Abd El-Khalik, N, Sharaby, Carmen M, “Synthesis and Performance of Flame Retardant Additives Based on Cyclodiphosph(V)azane of Sulfaguanidine, 1,3-di-[N/-2-pyrimidinylsulfanilamide]-2,2,2.4,4,4-hexachlorocyclodiphosph(V)azane and 1,3-di-[N/-2-pyrimidinylsulfanilamide]-2,4-di[aminoacetic acid]-2,4-dichlorocyclodiphosph(V)azane Incorporated into Polyurethane Varnish.” Prog. Org. Coat., 74 (3) 615–621 (2012)
Na, W, “Rongjie Effects of Metal Oxides on Intumescent Flame-Retardant Polypropylene.” Polym. Adv. Technol., 22 (5) 495–501 (2011)
Hoang, D, Kim, J, Jang, B Nam, “Synthesis and Performance of Cyclic Phosphorus-Containing Flame Retardants.” Polym. Degrad. Stab., 93 (11) 2042–2047 (2008)
Giudice, CA, Benitez, JC, “Zinc Borates as Flame-Retardant Pigments in Chlorine-Containing Coatings.” Prog. Org. Coat., 42 (1–2) 82–88 (2001)
Lu, S, Hamerton, I, “Recent Developments in the Chemistry of Halogen-Free Flame Retardant Polymers.” Prog. Polym. Sci., 27 (8) 1661–1712 (2002)
Shuyu Liang, N, Matthias, N, Gaan, S, “Recent Developments in Flame Retardant Polymeric Coatings.” Prog. Org. Coat., 76 (11) 1642–1665 (2013)
Lewin, M, Weil, ED, “Mechanisms and Modes of Action in Flame Retardancy of Polymers.” In: Horrocks, AR, Price, D (eds.) Fire Retardant Materials, pp. 31–68. Woodhead Publishing Limited, Cambridge, 2001
Joseph, P, Ebdon, JR, “Recent Developments in Flame-Retarding Thermoplastics and Thermosets.” In: Horrocks, AR, Price, D (eds.) Fire Retardant Materials, pp. 220–263. Woodhead Publishing Limited, Cambridge, 2001
Georlette, P, “Applications of Halogen Flame Retardants.” In: Horrocks, AR, Price, D (eds.) Fire Retardant Materials, pp. 264–292. Woodhead Publishing, Cambridge, 2001
Wilkie, CA, Morgen, AB (eds.), Fire Retardancy of Polymeric Materials, 2nd ed. CRC Press, Taylor & Francis Group, Boca Raton, 2010
Adewale, KO, “Synthesis, Characterization and Evaluation of Chlorinated Albizia Benth Medium Oil Alkyd.” Prog. Org. Coat., 50 (2) 138–143 (2004)
Gündüz, G, Kisakürek, D, Kayadan, S, “Flame Retardant Alkyd Paint.” Polym. Degrad. Stab., 64 (3) 501–504 (1999)
Ikhuoria, EU, Maliki, M, Okieimen, FE, Aigbodion, AI, Obaze, EO, Bakare, IO, “Synthesis and Characterization of Chlorinated Rubber Seed Oil Alkyd Resins.” Prog. Org. Coat., 59 (2) 134–137 (2007)
Favstritsky, NA, Wang, JL, “Flame-retardant brominated styrene-based polymers. X. Dibromostyrene grafted latexes.” J. Coat. Technol., 69 (868) 39–44 (1997)
Pearce, EM, Weil, ED, Barinov, VY, “Fire and Polymers.” In: Nelson, GL, Wilkie, CA (eds.) Materials and Solutions for Hazard Prevention, pp. 37–49. American Chemical Society, Washington, DC, 2001
Alaee, M, Arias, P, Sjödin, A, Bergman, Å, “An Overview of Commercially Used Brominated Flame Retardants, Their Applications, Their Use Patterns in Different Countries/Regions and Possible Modes of Release.” Environ. Int., 29 683–689 (2003)
Kroschwitz, JI, Howe-Grant, M (eds.) Encyclopedia of Chemical Technology, Kirk-Othmer. Wiley, New York, 2007
U.S. Geological Survey, Mineral Commodity Summaries. U.S. Geological Survey, Washington, DC, pp. 36–37, 2009
Spatz, SM, Stone, H, Koral, M, Steiner, RI, Ackerman, HW, Jr, “Use of Tetrabromophthalic Anhydride (TBPA) in the Construction of Fire-Retardant Polyester and Epoxy Resins.” Ind. Eng. Chem., 8 (4) 381–391 (1969)
Pape, PG, Sanger, JE, Nametz, RC, “Tetrabromophthalic Anhydride in Flame-Retardant Urethane Foams.” J. Cell. Plast., 4 (11) 438–442 (1968)
Patton, TC, Alkyd Resin Technology, Formulating and Calculations. Wiley, New York, 1962
Fenimore, CP, Martin, FJ, “Flammability and Sensitivity of Materials in Oxygen-Enriched Atmospheres.” Mod. Plast, 44 (3) 141–148 (1966)
Camino, G, Costa, L, Casorati, E, Bertelli, G, Locatelli, R, “The Oxygen Index Method in Fire Retardance Studies of Polymeric Materials.” J. Appl. Polym. Sci., 35 (7) 1863–1876 (1988)
McCrum, NG, Buckley, CP, Bucknall, CB, Principles of Polymer Engineering, 2nd ed. Oxford Science Publications, Oxford, 1997
Levin, M, Atlas, SM, Pearce, EM, Flame-Retardant Polymeric Materials, p. 376. Plenum Press, New York, 1975
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Abd El-Wahab, H., Abd El-Fattah, M., Abd El-Khalik, N. et al. Synthesis and performance of new modified reactive flame-retardant alkyd resin based on tetrabromophthalic anhydride as varnish for surface coatings. J Coat Technol Res 12, 97–105 (2015). https://doi.org/10.1007/s11998-014-9615-6
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DOI: https://doi.org/10.1007/s11998-014-9615-6