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Double-imprinted potentiometric sensors based on ligand exchange for the determination of dimethoate

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Abstract

This paper describes a dimethoate imprinted polymeric potentiometric sensor for the determination of dimethoate that was designed by dispersing the dimethoate-imprinted polymer in dibutyl phthalate plasticizer and then embedded in polyvinyl chloride matrix. The method is based on molecularly imprinted polymer (MIP), which can be synthesized by using dimethoate as a template molecule, chitosan-Cd(II), and 3-mercaptopropyl-trimethoxysilane as a functional monomer and TEOS, and ephychlorohydrin as a cross-linking agent. We have studied a method for the selective binding behavior of dimethoate compounds on the surface of imprinted polymers which is prepared using ligand-exchange (LE) (chitosan-Cd(II)) monomer. The MIP-LE-1 and MIP-LE-2 based membranes have shown a detection limit of 4.3×10−6 mmolL−1 and 3.5.10−5 mmolL−1, respectively. The sensor has exhibited a response time of 35min for MIP-LE-1 and 120min for MIP-LE-2. They are stable for more than three months.

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Authors and Affiliations

  1. Department of Chemistry, Eskişehir Osmangazi University, Eskişehir, Turkey

    Eyüp Bektaşoğlu & Ebru Birlik Özkütük

  2. Department of Chemistry, Anadolu University, Ankara, Turkey

    Arzu Ersöz & Rıdvan Say

Authors
  1. Eyüp Bektaşoğlu
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  2. Ebru Birlik Özkütük
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  3. Arzu Ersöz
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  4. Rıdvan Say
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Correspondence to Ebru Birlik Özkütük.

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Bektaşoğlu, E., Özkütük, E.B., Ersöz, A. et al. Double-imprinted potentiometric sensors based on ligand exchange for the determination of dimethoate. Korean J. Chem. Eng. 32, 1613–1617 (2015). https://doi.org/10.1007/s11814-014-0386-7

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  • DOI: https://doi.org/10.1007/s11814-014-0386-7

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