Original Paper

Journal of the American Oil Chemists' Society

, Volume 88, Issue 9, pp 1275-1283

Open Access This content is freely available online to anyone, anywhere at any time.

Direct Determination of Glycidyl Esters of Fatty Acids in Vegetable Oils by LC–MS

  • Michael R. BlumhorstAffiliated withResearch Division, Archer Daniels Midland Company, James R. Randall Research Center
  • , Padmesh VenkitasubramanianAffiliated withResearch Division, Archer Daniels Midland Company, James R. Randall Research Center
  • , Mark W. CollisonAffiliated withResearch Division, Archer Daniels Midland Company, James R. Randall Research Center Email author 

Abstract

An LC–MS method using a single quadrupole mass spectrometer was developed for direct analysis of glycidyl esters of fatty acids in vegetable oils. Without any sample clean-up, this method provided acceptable recovery of seven glycidyl esters, comparable results to a previously-published method utilizing two solid-phase extraction steps, and consistent detection parameters after greater than 200 injections without any cleaning operations performed. This method could readily be implemented as a screening assay for glycidyl esters in most oil laboratories.

Keywords

Monochloropropanediol 3-MCPD MCPD Glycidol Glycidyl esters LC–MS Vegetable oil