Skip to main content
Log in

Supercritical fluid extraction of jojoba oil

  • Published:
Journal of the American Oil Chemists' Society

Abstract

Supercritical fluid extraction of jojoba oil from Simmondsia chinensis seeds using CO2 as the solvent is presented in this study. The effects of process parameters such as pressure and temperature of extraction, particle size of jojoba seeds, flow rate of CO2, and concentration of entrainer (hexane) on the extraction yield were examined. Increases in the supercritical CO2 flow rate, temperature, and pressure generally improved the performance. The extraction yield increased as the particle size decreased, indicating the importance of decreasing intraparticle diffusional resistance. The maximum extraction yield obtained was 50.6 wt% with a 0.23-mm particle size and a 2 mL/min CO2 flow rate at 90°C and 600 bar. Use of an entrainer at a concentration of 5 vol% improved the yield to 52.2 wt% for the same particle size and also enabled the use of relatively lower pressure and temperature, i.e., 300 bar and 70°C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Wisniak, J., J. Hillel, and O. Katz, Holdup and Extraction Characteristics of Jojoba Meal, J. Am. Oil Chem. Soc. 64:1352–1354 (1987).

    CAS  Google Scholar 

  2. Schultz, K., E.E. Martinelli, and G.A. Mansoori, Supercritical Fluid Extraction and Retrograde Concentration. Application in Biotechnology, in Supercritical Fluid Technology: Reviews in Modern Theory and Applications, edited by T.J. Bruno, and J.F. Ely, CRC Press, Boca Raton, FL, 1991, pp. 451–478.

    Google Scholar 

  3. Abu-Arabi, M.K., Allawzi, M.A., A.H. Al-Zoubi, and A. Tamimi, Extraction of Jojoba Oil by Pressing and Leaching, Chem. Eng. J. 76:61–65 (2000).

    Article  CAS  Google Scholar 

  4. Radunz, A., and G.H. Schmid, Wax Esters and Triglycerides as Storage Substances in Seeds of Baxus sempervirens, in Joint International Congress and Expo: Lipids, Fats and Oils: Opportunities and Responsibilities in the New Century, Würzburg, Germany, October 8–10, 2000, p. 94.

  5. Salgin, U, A. Çalimli, and B.Z. Uysal, Supercritical Fluid Extraction of Jojoba Oil from Simmondsia chinesis Seeds, in First International Congress on the Chemistry of Natural Products (ICNP-2002), edited by N. Yayh, Trabzon, Turkey, October 16–19, 2002, p. 112.

  6. Dawoud, U.M., Y. Disli, Y. Yildirir, and B.Z. Uysal, Structural Elucidation of Jojoba Plant (Simmondsia chinesis) Oil from Saudi Arabia, J. Fac. Pham. Ankara Univ. 31:223–229 (2002).

    CAS  Google Scholar 

  7. Mukhopadhyay, M, Natural Extracts Using Supercritical Carbon Dioxide, CRC Press, Boca Raton, FL, 2000, 339 pp.

    Google Scholar 

  8. Salunkhe, D.K., J.K. Chavan, R.N. Adsule, S.S. Kadam, World Oil Seeds: Chemistry, Technology, and Utilization, 2nd edn., Van Nostrand Reinhold, New York, 1992, 554 pp.

    Google Scholar 

  9. Stahl, E., K.W. Quirin, and D. Gerard, Dense Gases for Extraction and Refining, Springer-Verlag, Berlin, 1988.

    Google Scholar 

  10. del Valla, J.M., and E.L. Uquiche, Particle Size Effect on Supercritical CO2 Extraction of Oil-Containing Seeds, J. Am. Oil Chem. Soc. 79:1261–1266 (2002).

    Article  Google Scholar 

  11. Fattori, M., N.R. Bulley, and A. Meisen, Carbon Dioxide Extraction of Canola Seed: Oil Solubility and Effect of Seed Treatment, 65:968–974 (1988).

    CAS  Google Scholar 

  12. Snyder, J.M., J.P. Friedrich, and D.D. Christianson, Effect of Moisture and Particle Size on the Extractability of Oil from Seeds with Supercritical CO2, 61:1851–1856 (1984).

    CAS  Google Scholar 

  13. Official Methods and Recommended Practices of the American Oil Chemists' Society, 4th edn., Vol. 1, AOCS Press, Champaign, 1993, Method Ca 2c-25.

  14. Reverchon, E., and M. Poletto, Mathematical Modelling of Supercritical CO2 Fractionation of Flower Concretes, Chem. Eng. Sci. 51:3741–3753 (1996).

    Article  CAS  Google Scholar 

  15. Roy, B.C., M. Goto, and T. Hirose, Extraction of Ginger Oil with Supercritical Carbon Dioxide: Experiments and Modeling, Ind. Eng. Chem. Res. 35:607–612 (1996).

    Article  CAS  Google Scholar 

  16. Perrut, M., J.Y. Clavier, M. Poletto, and E. Reverchon, Mathematical Modeling of Sunflower Seed Extraction by Supercritical CO2, 36:430–435 (1997).

    Article  CAS  Google Scholar 

  17. Akgün, M., N.A. Akgün, and S. Dinçer, Extraction and Modeling of Lavender Flower Essential Oil Using Supercritical Carbon Dioxide, 39:473–477 (2000).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ayla Çalimli.

About this article

Cite this article

Salgin, U., Çalimli, A. & Zühtü Uysal, B. Supercritical fluid extraction of jojoba oil. J Amer Oil Chem Soc 81, 293–296 (2004). https://doi.org/10.1007/s11746-004-0898-3

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11746-004-0898-3

Key Words

Navigation