Abstract
The behavior of binary mixtures of glycoside-based surfactants in combination with didecyldimethylammonium chloride (DDAC) has been studied using surface tension measurements. The three glycoside-based surfactants are nonionic decyl glycoside (APG), nonionic dodecyl ethoxy glycoside (AEG) and anionic disodium dodecyl ethoxy glycoside citrate (AEG-EC). Lower critical micelle concentrations (CMC) and minimum molecular area (A min) values were obtained for all the mixed systems. The pC20 values of APG/DDAC and AEG-EC/DDAC mixtures are larger than pure surfactants, while the values of AEG/DDAC are between those of AEG and DDAC. Interactions between the monomers have also been investigated by determining the interaction parameters. Negative β m and β s values indicate synergistic effects in both the mixed micelle and monolayer formation. For different mixed systems, interaction in the mixed micelle formation becomes stronger in the order: AEG/DDAC < AEG-EC/DDAC < APG/DDAC. The degree of synergism in the mixed monolayer formation follows the order: AEG/DDAC < APG/DDAC < AEG-EC/DDAC.
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Rauwel G, Leclercq L, Criquelion J, Aubry J-M, Nardello-Rataj V (2012) Aqueous mixtures of di-n-decyldimethylammonium chloride/polyoxyethylene alkyl ether: dramatic influence of tail/tail and head/head interactions on co-micellization and biocidal activity. J Colloid Interface Sci 374:176–186
Shiloach A, Blankschtein D (1998) Measurement and prediction of ionic/nonionic mixed micelle formation and growth. Langmuir 14:7166–7182
Tucker I, Penfold J, Thomas RK, Tildesley DJ (2009) Interplay between the surface adsorption and solution-phase behavior in dialkyl chain cationic-nonionic surfactant mixtures. Langmuir 25:3924–3931
Grillo I, Penfold J, Tucker I, Cousin F (2009) Spontaneous formation of nanovesicles in mixtures of nonionic and dialkyl chain cationic surfactants studied by surface tension and SANS. Langmuir 25:3932–3943
Penfold J, Staples E, Ugazio S, Tucker I, Soubiran L, Hubbard J, Noro M, O’Malley B, Ferrante A, Ford G, Buron H (2005) The microstructure of di-alkyl chain cationic/nonionic surfactant mixtures: observation of coexisting lamellar and micellar phases and depletion induced phase separation. J Phys Chem B 109:18107–18116
Mohammadi MS (2006) Colloidal stability of di-chain cationic and ethoxylated nonionic surfactant mixtures used in commercial fabric softeners. Colloids Surf A 288:96–102
Nilsson F, Söderman O, Hansson P (1998) Physical-chemical properties of C9G1 and C10G1 β-alkylglucosides. phase diagrams and aggregate size/structure. Langmuir 14:4050–4058
Balzer D (1993) Cloud point phenomena in the phase behavior of alkyl polyglucosides in water. Langmuir 9:3375–3384
Fukuda K, Söderman O, Lindman B, Shinoda K (1993) Microemulsions formed by alkyl polyglucosides and an alkyl glycerol ether. Langmuir 9:2921–2925
Ryan LD, Kaler EW (2001) Alkyl polyglucoside microemulsion phase behavior. Colloids Surf A 176:69–83
Balzer D (1991) Alkylpolyglucosides, their physico-chemical properties and their uses. Tenside Surfactants Deterg 28:419–427
Matsumura S, Imai K, Yoshikawa S, Kawada K, Uchibori T (1990) Surface activities, biodegradability and antimicrobial properties of n-alkyl glucosides, mannosides and galactosides. J Am Oil Chem Soc 67:996–1001
O’Lenick Jr. AJ (2004) Alkoxylated surfactants based upon alkyl polyglycoside. US Patent 6,800,741 B1
Platz G, Pölike J, Thunig C (1995) Phase behavior, lyotropic phases, and flow properties of alkyl glycosides in aqueous solution. Langmuir 11:4250–4255
Zhang YJ, Yang XQ, Yang QL, Cheng YM (2009) Preparation and complex properties of alkylethoxyglucoside. Chem Res Appl 21:1108–1113
Niu SY, Yang XQ, Bai L, Zhou Y, Zhang J (2012) Preparation and performance of citrate monoesters salt of ethoxylated fatty alcohols glucoside. Appl Chem Ind 41:984–987
Weil I (1989) Method for synthesizing a salt of a monoester of citric acid. US Patent 4,866,202
Weil I (1991) Skin treatment composition containing monoester of citric acid. US Patent 5,047,166
Griffiths PC, Stilbs P, Paulsen K, Howe AM, Pitt AR (1997) FT-PGSE NMR study of mixed micellization of an anionic and a sugar-based nonionic surfactant. J Phys Chem B 101:915–918
Hines JD, Thomas RK, Garrett PR, Rennie GK, Penfold J (1997) Investigation of mixing in binary surfactant solutions by surface tension and neutron reflection: anionic/nonionic and zwitterionic/nonionic mixtures. J Phys Chem B 101:9215–9223
Kameyama K, Muroya A, Takagi T (1997) Properties of a mixed micellar system of sodium dodecyl sulfate and octylglucoside. J Colloid Interface Sci 196:48–52
Arai T, Takasugi K, Esumi K (1998) Mixed micellar properties of nonionic saccharide and anionic fluorocarbon surfactants in aqueous solution. J Colloid Interface Sci 197:94–100
Sierra ML, Svensson M (1999) Mixed micelles containing alkylglycosides: effect of the chain length and the polar head group. Langmuir 15:2301–2306
Li F, Rosen MJ, Sulthana SB (2001) Surface properties of cationic gemini surfactants and their interaction with alkylglucoside or-maltoside surfactants. Langmuir 17:1037–1042
Hong B, Lai J, Leclercq L, Collinet-Fressancourt M, Aubry J-M, Bauduin P, Nardello-Rataj V (2013) Binary and ternary phase behaviors of short double-chain quaternary ammonium amphiphiles: surface tension, polarized optical microscopy, and SAXS investigations. J Phys Chem B 117:14732–14742
Zhou Q, Rosen MJ (2003) Molecular interactions of surfactants in mixed monolayers at the air/aqueous solution interface and in mixed micelles in aqueous media: the regular solution approach. Langmuir 19:4555–4562
Saien J, Asadabadi S (2010) Adsorption and interfacial properties of individual and mixtures of cationic/nonionic surfactants in toluene + water chemical systems. J Chem Eng Data 55:3817–3824
Clint JH (1975) Micellization of mixed nonionic surface active agents. J Chem Soc Faraday Trans 1(71):1327–1334
Nandni D, Mahajan RK (2013) Micellar and interfacial behavior of cationic benzalkonium chloride and nonionic polyoxyethylene alkyl ether based mixed surfactant systems. J Surfactants Deterg 16:587–599
Acknowledgments
We are grateful to the Ministry of Science and Technology of the People’s Republic of China (2014BAE03B01) for financial support. We thank the National Engineering Research Center of Surfactants, China Research Institute of Daily Chemical Industry, for sample analysis.
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Han, Z., Yang, X. & Liu, Y. Micellar and Interfacial Behavior of Mixed Systems Containing Glycoside-Based Surfactant and Cationic Didecyldimethylammonium Chloride. J Surfact Deterg 18, 873–880 (2015). https://doi.org/10.1007/s11743-015-1705-7
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DOI: https://doi.org/10.1007/s11743-015-1705-7