Review Article

Frontiers of Chemical Science and Engineering

, Volume 7, Issue 2, pp 233-248

First online:

Mesoporous zeolites as efficient catalysts for oil refining and natural gas conversion

  • Jie ZhuAffiliated withDepartment of Chemistry, Zhejiang UniversityCollege of Biological, Chemical Sciences and Engineering, Jiaxing University
  • , Xiangju MengAffiliated withDepartment of Chemistry, Zhejiang University
  • , Fengshou XiaoAffiliated withDepartment of Chemistry, Zhejiang University Email author 


Zeolites have been regarded as one of the most important catalysts in petrochemical industry due to their excellent catalytic performance. However, the sole micropores in zeolites severely limit their applications in oil refining and natural gas conversion. To solve the problem, mesoporous zeolites have been prepared by introducing mesopores into the zeolite crystals in recent years, and thus have the advantages of both mesostructured materials (fast diffusion and accessible for bulky molecules) and microporous zeolite crystals (strong acidity and high hydrothermal stability). In this review, after giving a brief introduction to preparation, structure, and characterization of mesoporous zeolites, we systematically summarize catalytic applications of these mesoporous zeolites as efficient catalysts in oil refining and natural gas conversion including catalytic cracking of heavy oil, alkylation, isomerization, hydrogenation, hydrodesulfurization, methane dehydroaromatization, methanol dehydration to dimethyl ether, methanol to olefins, and methanol to hydrocarbons.


mesoporous zeolite catalysis oil refining natural gas conversion