Abstract
In this study, fluoro-functionalized hydrophobic/oleophobic hybrid nanocomposite coatings, which are highly resistant and transparent, long-lasting and mechanically stable, have been deposited on metal substrate surfaces by the sol–gel method. Organic–inorganic hybrid matrix was prepared using tetraethoxysilane and organically modified silicon alkoxide, namely 3-(glycidyloxypropyl) trimethoxysilane. Additionally, to increase hydrophobic behavior, a fluorinated silica-alkoxide precursor and AlO(OH) NPs were added to the hybrid matrix. Water and n-hexadecane contact angle, surface morphologies, thicknesses and surface roughness of the films were determined. Additionally, optical characterizations and mechanical properties of the films such as light transmittance, haze, clarity, gloss were investigated. A salt spray corrosion test and electrochemical corrosion measurements were also performed. Optimum properties were acquired in the hydrophobic hybrid nanocomposite coating containing 15 wt% of 3 nm AlO(OH) NPs.
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Altinbalik MT, Mutlu S (2014) A comparative cost analysis between conventional and progressive draw die. Int J Mod Manuf Technol VI(1). https://pdfs.semanticscholar.org/97ae/b4e3238e766e0c43c91f7b81cb01208ee179.pdf?_ga=2.44349164.951370348.1564573627-1075759943.1561727819
Arukalam IO, Oguzie EE, Li Y (2018) Nanostructured superhydrophobic polysiloxane coating for high barrier and anticorrosion applications in marine environment. J Colloid Interface Sci 512:674–685. https://doi.org/10.1016/j.jcis.2017.10.089
ASTM D523–14 (2014) Standard test method for specular gloss. ASTM Int. https://doi.org/10.1520/D0523-14.2
Ates M, Dolapdere A (2015) Electrochemical polymerization of thiophene and poly(3-hexyl)thiophene, nanocomposites with TiO2, and corrosion protection behaviors. Polym Plast Technol Eng 54(17):1780–1786. https://doi.org/10.1080/03602559.2015.1036450
Baghery P, Farzam M, Mousavi AB, Hosseini M (2010) Ni–TiO2 nanocomposite coating with high resistance to corrosion and wear. Surf Coat Technol 204(23):3804–3810. https://doi.org/10.1016/j.surfcoat.2010.04.061
Basu BJ, Hariprakash V, Aruna ST, Lakshmi RV, Manasa J, Shruthi BS (2010) Effect of microstructure and surface roughness on the wettability of superhydrophobic sol–gel nanocomposite coatings. J Sol Gel Sci Technol 56(3):278–286. https://doi.org/10.1007/s10971-010-2304-8
Corcione CE, Frigione M (2012) UV-cured polymer-boehmite nanocomposite as protective coating for wood elements. Prog Org Coat 74(4):781–787. https://doi.org/10.1016/j.porgcoat.2011.06.024
ČSN ISO 9227 (2007) Corrosion tests in artificial atmospheres—salt spray tests. European Standard EN ISO 9227:2006
D3359-09 (2013) Standard test methods for measuring adhesion by tape test. ASTM. https://doi.org/10.1520/D3359-09E02.2
Decker C, Keller L, Zahouily K, Benfarhi S (2005) Synthesis of nanocomposite polymers by UV-radiation curing. Polymer 46(17):6640–6648. https://doi.org/10.1016/j.polymer.2005.05.018
García SJ, Fischer HR, Van Der Zwaag S (2011) A critical appraisal of the potential of self healing polymeric coatings. Prog Org Coat 72(3):211–221. https://doi.org/10.1016/j.porgcoat.2011.06.016
Gerhardus K, Jeff V, Thopson N, Moghissi O, Gould M, Payer J (2016) International measures of prevention, application, and economics of corrosion technologies study. pp 1–216. http://impact.nace.org/documents/Nace-International-Report.pdf
Guo Z, Zhou F, Hao J, Liu W (2006) Effects of system parameters on making aluminum alloy lotus. J Colloid Interface Sci 303(1):298–305. https://doi.org/10.1016/j.jcis.2006.06.067
Haas KH, Wolter H (1999) Synthesis, properties and applications of inorganic–organic copolymers (ORMOCER®s). Curr Opin Solid State Mater Sci 4(6):571–580. https://doi.org/10.1016/S1359-0286(00)00009-7
Haas KH, Amberg-Schwab S, Rose K, Schottner G (1999) Functionalized coatings based on inorganic–organic polymers (ORMOCER®s) and their combination with vapor deposited inorganic thin films. Surf Coat Technol 111(1):72–79. https://doi.org/10.1016/S0257-8972(98)00711-7
Hornberger H, Virtanen S, Boccaccini AR (2012) Biomedical coatings on magnesium alloys—a review. Acta Biomater 8(7):2442–2455. https://doi.org/10.1016/j.actbio.2012.04.012
ISO 1518-2:2011 (2011) Paints and varnishes—Determination of scratch resistance—part 2: variable-loading method. https://www.iso.org/standard/59596.html
ISO 15184:2012 (2012) Paints and varnishes—determination of film hardness by pencil test. https://www.iso.org/standard/55329.html
Jeong HJ, Kim DK, Lee SB, Kwon SH, Kadono K (2001) Preparation of water-repellent glass by sol–gel process using perfluoroalkylsilane and tetraethoxysilane. J Colloid Interface Sci 235(1):130–134. https://doi.org/10.1006/jcis.2000.7313
Kesmez Ö (2019) Preparation of UV-curable hybrid films via sol–gel synthesis for hydrophobic surface applications. J Sol Gel Sci Technol 91(1):1–10. https://doi.org/10.1007/s10971-019-05027-x
Kesmez Ö, Akarsu E (2017) Corrosion-resistant hybrid coatings for copper surfaces substrates by sol–gel chemistry. J Turk Chem Soc Sect A Chem 4(Sp. is. 1):1. https://doi.org/10.18596/jotcsa.324873
Kesmez Ö, Erdem Çamurlu H, Burunkaya E, Arpaç E (2009) Sol–gel preparation and characterization of anti-reflective and self-cleaning SiO2–TiO2 double-layer nanometric films. Sol Energy Mater Sol Cells 93(10):1833–1839. https://doi.org/10.1016/j.solmat.2009.06.022
Kesmez Ö, Kiraz N, Burunkaya E, Çamurlu HE, Asiltürk M, Arpaç E (2010) Effect of amine catalysts on preparation of nanometric SiO2 particles and antireflective films via sol–gel method. J Sol Gel Sci Technol. https://doi.org/10.1007/s10971-010-2290-x
Kesmez Ö, Akarsu E, Çamurlu HE, Yavuz E, Akarsu M, Arpaç E (2017) Preparation and characterization of multilayer anti-reflective coatings via sol–gel process. Ceram Int. https://doi.org/10.1016/j.ceramint.2017.11.088
Kiraz N, Burunkaya E, Kesmez Ö, Asiltürk M, Çamurlu HE, Arpaç E (2010) Sol–gel synthesis of 3-(triethoxysilyl)propylsuccinicanhydride containing fluorinated silane for hydrophobic surface applications. J Sol Gel Sci Technol. https://doi.org/10.1007/s10971-010-2289-3
Koene BE, Martin R, Goff A, Hay J (2016) Durable hydrophobic coatings for corrosion protection. Adv Mater TechConnect Briefs 2016(1):229–232
Lakshmi RV, Bharathidasan T, Basu BJ (2011) Superhydrophobic sol–gel nanocomposite coatings with enhanced hardness. Appl Surf Sci 257(24):10421–10426. https://doi.org/10.1016/j.apsusc.2011.06.122
Lakshmi RV, Bharathidasan T, Bera P, Basu BJ (2012) Fabrication of superhydrophobic and oleophobic sol–gel nanocomposite coating. Surf Coat Technol 206(19–20):3888–3894. https://doi.org/10.1016/j.surfcoat.2012.03.044
Lakshmi RV, Bera P, Anandan C, Basu BJ (2014) Effect of the size of silica nanoparticles on wettability and surface chemistry of sol–gel superhydrophobic and oleophobic nanocomposite coatings. Appl Surf Sci 320:780–786. https://doi.org/10.1016/j.apsusc.2014.09.150
Larena A, Millán F, Verdú M, Pinto G (2001) Surface roughness characterisation of multilayer polymer films for graphic arts applications. Appl Surf Sci 174(3–4):217–224. https://doi.org/10.1016/S0169-4332(01)00179-9
Liu J, Silveira J, Groarke R, Parab S, Singh H, McCarthy E, Brabazon D (2019) Effect of powder metallurgy synthesis parameters for pure aluminium on resultant mechanical properties. Int J Mater Form 12(1):79–87. https://doi.org/10.1007/s12289-018-1408-5
Maeztu JD, Rivero PJ, Berlanga C, Bastidas DM, Palacio JF, Rodriguez R (2017) Effect of graphene oxide and fluorinated polymeric chains incorporated in a multilayered sol–gel nanocoating for the design of corrosion resistant and hydrophobic surfaces. Appl Surf Sci 419:138–149. https://doi.org/10.1016/j.apsusc.2017.05.043
Milošev I, Kapun B, Rodič P, Iskra J (2015) Hybrid sol–gel coating agents based on zirconium(IV) propoxide and epoxysilane. J Sol Gel Sci Technol 74(2):447–459. https://doi.org/10.1007/s10971-015-3620-9
Ming W, Melis F, Van de Grampel RD, Van Ravenstein L, Tian M, Van der Linde R (2003) Low surface energy films based on partially fluorinated isocyanates: the effects of curing temperature. Prog Org Coat 48(2–4):316–321. https://doi.org/10.1016/S0300-9440(03)00107-3
Mishra T, Mohanty AK, Tiwari SK (2013) Recent development in clay based functional coating for corrosion protection. Key Eng Mater 571(July):93–109. https://doi.org/10.4028/www.scientific.net/KEM.571.93
Mohamed AMA, Abdullah AM, Younan NA (2015) Corrosion behavior of superhydrophobic surfaces: a review. Arabian J Chem 8(6):749–765. https://doi.org/10.1016/j.arabjc.2014.03.006
Montemor MF (2014) Functional and smart coatings for corrosion protection: a review of recent advances. Surf Coat Technol 258:17–37. https://doi.org/10.1016/j.surfcoat.2014.06.031
Phani AR, Santucci S (2006) Evaluation of structural and mechanical properties of aluminum oxide thin films deposited by a sol–gel process: comparison of microwave to conventional anneal. J Noncryst Solids 352(38–39):4093–4100. https://doi.org/10.1016/j.jnoncrysol.2006.06.013
Plueddemann EP (1983) Silane adhesion promoters in coatings. Prog Org Coat 11(3):297–308. https://doi.org/10.1016/0033-0655(83)80012-0
Purcar V, Stamatin I, Cinteza O, Petcu C, Raditoiu V, Ghiurea M, Andronie A (2012) Fabrication of hydrophobic and antireflective coatings based on hybrid silica films by sol–gel process. Surf Coat Technol 206(21):4449–4454. https://doi.org/10.1016/j.surfcoat.2012.04.094
Rivero P, Maeztu J, Berlanga C, Miguel A, Palacio J, Rodriguez R (2018) Hydrophobic and corrosion behavior of sol–gel hybrid coatings based on the combination of TiO2 NPs and fluorinated chains for aluminum alloys protection. Metals 8(12):1076. https://doi.org/10.3390/met8121076
Schmidt H, Karnieli A (2000) Remote sensing of the seasonal variability of vegetation in a semi-arid environment. J Arid Environ 45(1):43–59. https://doi.org/10.1006/jare.1999.0607
Seok SI, Kim JH, Choi KH, Hwang YY (2006) Preparation of corrosion protective coatings on galvanized iron from aqueous inorganic–organic hybrid sols by sol–gel method. Surf Coat Technol 200(11):3468–3472. https://doi.org/10.1016/j.surfcoat.2005.01.012
Sheen YC, Huang YC, Liao CS, Chou HY, Chang FC (2008) New approach to fabricate an extremely super-amphiphobic surface based on fluorinated silica nanoparticles. J Polym Sci Part B Polym Phys. https://doi.org/10.1002/polb.21535
Shi Z, Jia JX, Atrens A (2012) Galvanostatic anodic polarisation curves and galvanic corrosion of high purity Mg in 3.5% NaCl saturated with Mg(OH) 2. Corros Sci 60:296–308. https://doi.org/10.1016/j.corsci.2011.12.002
Shi X, Yu K, Jiang L, Li C, Li Z, Zhou X (2018) Microstructural characterization of Ni-201 weld cladding onto 304 stainless steel. Surf Coat Technol 334(November 2017):19–28. https://doi.org/10.1016/j.surfcoat.2017.11.023
Tang C, Liu W, Ma S, Wang Z, Hu C (2010) Synthesis of UV-curable polysiloxanes containing methacryloxy/fluorinated side groups and the performances of their cured composite coatings. Prog Org Coat 69(4):359–365. https://doi.org/10.1016/j.porgcoat.2010.07.009
Tatar P, Kiraz N, Asiltürk M, Sayilkan F, Sayilkan H, Arpaç E (2007) Antibacterial thin films on glass substrate by sol–gel process. J Inorg Organomet Polym Mater 17(3):525–533. https://doi.org/10.1007/s10904-007-9142-3
Tavandashti NP, Sanjabi S (2010) Corrosion study of hybrid sol–gel coatings containing boehmite nanoparticles loaded with cerium nitrate corrosion inhibitor. Prog Org Coat 69(4):384–391. https://doi.org/10.1016/j.porgcoat.2010.07.012
Thomas S, Birbilis N, Venkatraman MS, Cole IS (2013) Self-repairing oxides to protect zinc: review, discussion and prospects. Corros Sci 69:11–22. https://doi.org/10.1016/j.corsci.2013.01.011
Scratch Hardness Tester acc. to Model 291 Description, Technical Instructions, Operating (2019). https://www.iso.org/standard/55329.html
Umoren SA, Solomon MM (2019) Protective polymeric films for industrial substrates: a critical review on past and recent applications with conducting polymers and polymer composites/nanocomposites. Prog Mater Sci 104(March):380–450. https://doi.org/10.1016/j.pmatsci.2019.04.002
Valipour Motlagh N, Birjandi FC, Sargolzaei J, Shahtahmassebi N (2013) Durable, superhydrophobic, superoleophobic and corrosion resistant coating on the stainless steel surface using a scalable method. Appl Surf Sci 283:636–647. https://doi.org/10.1016/j.apsusc.2013.06.160
Vazirinasab E, Jafari R, Momen G (2018) Application of superhydrophobic coatings as a corrosion barrier: a review. Surf Coat Technol 341(November 2017):40–56. https://doi.org/10.1016/j.surfcoat.2017.11.053
Vivar Mora L, Taylor A, Paul S, Dawson R, Wang C, Taleb W, Barker R (2018) Impact of silica nanoparticles on the morphology and mechanical properties of sol–gel derived coatings. Surf Coat Technol 342(August 2017):48–56. https://doi.org/10.1016/j.surfcoat.2018.02.080
Wankhede RG, Morey S, Khanna AS, Birbilis N (2013) Development of water-repellent organic–inorganic hybrid sol–gel coatings on aluminum using short chain perfluoro polymer emulsion. Appl Surf Sci 283:1051–1059. https://doi.org/10.1016/j.apsusc.2013.07.066
Yeganeh M, Nguyen TA (2019) Methods for corrosion protection of metals at the nanoscale. Kenk Nanotec Nanosci 5:37–44. https://doi.org/10.31872/2019/KJNN-100123
Yu Q, Xu J (2012) Structure and surface properties of fluorinated organic–inorganic hybrid films. J Sol Gel Sci Technol 61(1):243–248. https://doi.org/10.1007/s10971-011-2620-7
Zhang Z, Zhu X, Yang J, Xu X, Men X, Zhou X (2012) Facile fabrication of superoleophobic surfaces with enhanced corrosion resistance and easy repairability. Appl Phys A Mater Sci Process 108(3):601–606. https://doi.org/10.1007/s00339-012-6937-z
Zhang Y, Ge D, Yang S (2014) Spray-coating of superhydrophobic aluminum alloys with enhanced mechanical robustness. J Colloid Interface Sci 423:101–107. https://doi.org/10.1016/j.jcis.2014.02.024
Zheludkevich ML, Serra R, Montemor MF, Yasakau KA, Salvado IMM, Ferreira MGS (2005a) Nanostructured sol–gel coatings doped with cerium nitrate as pre-treatments for AA2024-T3 Corrosion protection performance. Electrochim Acta 51(2):208–217. https://doi.org/10.1016/j.electacta.2005.04.021
Zheludkevich ML, Serra R, Montemor MF, Ferreira MGS (2005b) Oxide nanoparticle reservoirs for storage and prolonged release of the corrosion inhibitors. Electrochem Commun 7(8):836–840. https://doi.org/10.1016/j.elecom.2005.04.039
Zheludkevich ML, Serra R, Montemor MF, Miranda Salvado IM, Ferreira MGS (2006) Corrosion protective properties of nanostructured sol–gel hybrid coatings to AA2024-T3. Surf Coat Technol 200(9):3084–3094. https://doi.org/10.1016/j.surfcoat.2004.09.007
Zheng S, Li J (2010) Inorganic–organic sol gel hybrid coatings for corrosion protection of metals. J Sol Gel Sci Technol 54(2):174–187. https://doi.org/10.1007/s10971-010-2173-1
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I gratefully acknowledge financial support of the Akdeniz University Research Found. Help of Dr. Edip Bayram (Akdeniz University) for electrochemical analysis is gratefully acknowledged.
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Kesmez, Ö. Hydrophobic, organic–inorganic hybrid sol–gel coatings containing boehmite nanoparticles for metal corrosion protection. Chem. Pap. 74, 673–688 (2020). https://doi.org/10.1007/s11696-019-00931-6
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DOI: https://doi.org/10.1007/s11696-019-00931-6