Abstract
A method for a quick testing of transport properties of samples of a zeolite catalyst has been developed. The method is based on the application of gas-phase chromatography, where the tested sample is used as the stationary phase. Cyclopentene, cyclohexane, and 1,3,5-trimethylcyclohexane were used as the testing molecules. A retention indexes for samples comparison were introduced. The method is sensitive even to small changes in the zeolite structures caused by binding agents and/or alkali metals.
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References
Ackmann T, de Haart LGJ, Lehnert W, Stolten DJ (2003) Modeling of mass and heat transport in planar substrate type SOFCs. J Electrochem Soc 150:783–789. doi:10.1149/1.1574029
Brader WH (1965) US Patent 3056788. U.S. Patent and Trademark Office, Washington, D.C.
Brader WH, Rowton RL (1967) US Patent 3297701. U.S. Patent and Trademark Office, Washington, D.C.
Čapek P, Veselý M, Hejtmánek V (2014) On the measurement of transport parameters of porous solids in permeation and Wicke-Kallenbach cells. Chem Eng Sci 118:192–207. doi:10.1016/j.ces.2014.07.039
Disteldorf J, Finke N, Hubel W (1989) European Patent 0313753. European Patent Office, Munich
Duncan WL, Möller KP (2000) On the diffusion of cyclohexane in ZSM-5 measured by zero-length-column chromatography. Ind Eng Chem Res 39:2105–2113. doi:10.1021/ie9907573
Hesse M, Lermer H, Steck W, Fischer R, Muller H, Scharf E (1990) European Patent 0382055. European Patent Office, Munich
Holderich W, Schneider K (1988) European Patent 0263463. European Patent Office, Munich
Holderich W, Scheider K, Ruge B (1988) European Patent 0290862. European Patent Office, Munich
Hou K, Fowles M, Hughes R (1999) Effective Diffusivity measurements on porous catalyst pellets at elevated temperature and pressure. Chem Eng Res Des 77:55–56. doi:10.1205/026387699525873
Imre L, Horstman W, Leopold HG (1980) DE Patent 2846813. German Patent and Trade Mark Office, Munich
King SW (1991) European Patent 0476781. European Patent Office, Munich
Kolaczkowski ST (2003) Measurement of effective diffusivity in catalyst-coated monoliths. Catal Today 83:85–95. doi:10.1016/S0920-5861(03)00218-9
Krause JH (1961) US Patent 3985658. U.S. Patent and Trademark Office, Washington, D.C.
Kubín M (1965) Beitrag zur theorie der chromatographie. Collect Czech Chem Commun 30:1104–1118. doi:10.1135/cccc19651104
Kučera E (1965) Contribution to the theory of chromatography: linear nonequilibrium elution chromatography. J Chromatogr 9:237–248. doi:10.1016/S0021-9673(01)99457-9
Li H, Santiestaban J, Armor JN (1998) European Patent 0831096. European Patent Office, Munich
Li H, Santiestaban J, Emig LN, Armor JN (1999) European Patent 0952152. European Patent Office, Munich
Mascioli RL (1961) US Patent 2977364. U.S. Patent and Trademark Office, Washington, D.C.
Masciolli RL (1965) US Patent 3166558. U.S. Patent and Trademark Office, Washington, D.C.
Mori S, Barth HG (1999) Size exclusion chromatography. Springer, Berlin
Ohayon D, Le Van Mao R, Ciaravino D, Hazel H, Cochennec A, Rolland N (2001) Methods for pore size engineering in ZSM-5 zeolite. Appl Catal A: Gen 217:241–251. doi:10.1016/S0926-860X(01)00611-1
Pašek J, Petrisko M, Hula J, Havel M (1998) CZ Patent 287431. Czech Patent and Trademark Office, Prague
Santiestaban J, Li H, Armor JN (1998) European Patent 0842936. European Patent Office, Munich
Sato H, Tsuzuki M (1991) US Patent 5041548. U.S. Patent and Trademark Office, Washington, D.C.
Thomas W, Hausen M (1968) DE Patent 1445578. European Patent Office, Munich
Trejbal J, Pašek J, Petrisko M, Maršolek P (2005) CZ Patent 300798. Czech Patent and Trademark Office, Prague
Trejbal J, Pašek J, Petrisko M (2007) Side products formation in the synthesis of Diazabicyclo[2.2.2]octane on zeolite ZSM-5. Chem Eng Technol 30:1506–1511. doi:10.1002/ceat.200700189
Trejbal J, Pašek J, Petrisko M (2008) Effect of zeolite ZSM-5 particle size in the synthesis of 1,4-Diazabicyclo[2.2.2]octane. Collect Czech Chem Commun 73:956–966. doi:10.1135/cccc20080956
Tsukasa O (1993) JP Patent 5017460. Japan Patent Office, Tokyo
Tsukasa O (2002) European Patent 1192993. European Patent Office, Munich
Weber RW, Moller KP, O’Connor CT (2000) The chemical vapour and liquid deposition of tetraethoxysilane on ZSM-5, mordenite and beta. Microporous Mesoporous Mater 35:533–543. doi:10.1016/S1387-1811(99)00248-6
Weitkamp J, Puppe L (1999) Catalysis and zeolites. Springer, Berlin
Weitkamp J, Ernst S, Lindner D, Buysch HJ, Botta A, Puppe L (1991) European Patent 0423526. European Patent Office, Munich
Wells JE, Eskinazi V (1983) European Patent 0069322. European Patent Office, Munich
Zhu X, Wang H, Lin YS (2010) Effect of the membrane quality on gas permeation and chemical vapor deposition modification of MFI-Type zeolite membranes. Ind Eng Chem Res 49:10026–10033. doi:10.1021/ie101101z
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Trejbal, J., Zapletal, M. A method for estimation of transport properties of ZSM-5 zeolite. Chem. Pap. 71, 795–801 (2017). https://doi.org/10.1007/s11696-016-0083-6
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DOI: https://doi.org/10.1007/s11696-016-0083-6