Synthesis and Spectral Studies of CdTe–Dendrimer Conjugates
- Srabanti GhoshAffiliated withUGC-DAE Consortium for Scientific Research
- , Abhijit SahaAffiliated withUGC-DAE Consortium for Scientific Research Email author
In order to couple high cellular uptake and target specificity of dendrimer molecule with excellent optical properties of semiconductor nanoparticles, the interaction of cysteine-capped CdTe quantum dots with dendrimer was investigated through spectroscopic techniques. NH2-terminated dendrimer molecule quenched the photoluminescence of CdTe quantum dots. The binding constants and binding capacity were calculated, and the nature of binding was found to be noncovalent. Significant decrease in luminescence intensity of CdTe quantum dots owing to noncovalent binding with dendrimer limits further utilization of these nanoassemblies. Hence, an attempt is made, for the first time, to synthesize stable, highly luminescent, covalently linked CdTe–Dendrimer conjugate in aqueous medium using glutaric dialdehyde (G) linker. Conjugate has been characterized through Fourier transform infrared spectroscopy and transmission electron microscopy. In this strategy, photoluminescence quantum efficiency of CdTe quantum dots with narrow emission bandwidths remained unaffected after formation of the conjugate.
KeywordsQuantum dots Dendrimer Conjugate Infrared spectroscopy Luminescence
- Synthesis and Spectral Studies of CdTe–Dendrimer Conjugates
- Open Access
- Available under Open Access This content is freely available online to anyone, anywhere at any time.
Nanoscale Research Letters
- Online Date
- May 2009
- Online ISSN
- Springer New York
- Additional Links
- Quantum dots
- Infrared spectroscopy