June 2009, Volume 4, Issue 6, pp 574-577,
Open Access This content is freely available online to anyone, anywhere at any time.
Date: 04 Mar 2009
A Temperature Window for the Synthesis of Single-Walled Carbon Nanotubes by Catalytic Chemical Vapor Deposition of CH4 over Mo2-Fe10/MgO Catalyst
A temperature window for the synthesis of single-walled carbon nanotubes by catalytic chemical vapor deposition of CH4 over Mo2-Fe10/MgO catalyst has been studied by Raman spectroscopy. The results showed that when the temperature is lower than 750 °C, there were few SWCNTs formed, and when the temperature is higher than 950 °C, mass amorphous carbons were formed in the SWCNTs bundles due to the self-decomposition of CH4. The temperature window of SWCNTs efficient growth is between 800 and 950 °C, and the optimum growth temperature is about 900 °C. These results were supported by transmission electron microscope images of samples formed under different temperatures. The temperature window is important for large-scale production of SWCNTs by catalytic chemical vapor deposition method.
S.C. Lyu, B.C. Liu, T.J. Lee, Z.Y. Liu, C.W. Yang, C.Y. Park, C.J. Lee, Chem. Commun. 734 (2003)
- A Temperature Window for the Synthesis of Single-Walled Carbon Nanotubes by Catalytic Chemical Vapor Deposition of CH4 over Mo2-Fe10/MgO Catalyst
- Open Access
- Available under Open Access This content is freely available online to anyone, anywhere at any time.
Nanoscale Research Letters
Volume 4, Issue 6 , pp 574-577
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- Single-walled carbon nanotubes
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- Raman spectroscopy
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