Abstract
Suspension plasma spraying (SPS) enables the production of variety of microstructures with unique mechanical and thermal properties. In SPS, a liquid carrier (ethanol/water) is used to transport the sub-micrometric feedstock into the plasma jet. Considering complex deposition dynamics of SPS technique, there is a need to better understand the relationships among spray conditions, ensuing particle behavior, deposition stress evolution and resultant properties. In this study, submicron yttria-stabilized zirconia particles suspended in ethanol were sprayed using a cascaded arc plasma torch. The stresses generated during the deposition of the layers (termed evolving stress) were monitored via the change in curvature of the substrate measured using an in situ measurement apparatus. Depending on the deposition conditions, coating microstructures ranged from feathery porous to dense/cracked deposits. The evolving stresses and modulus were correlated with the observed microstructures and visualized via process maps. Post-deposition bi-layer curvature measurement via low temperature thermal cycling was carried out to quantify the thermo-elastic response of different coatings. Lastly, preliminary data on furnace cycle durability of different coating microstructures were evaluated. This integrated study involving in situ diagnostics and ex situ characterization along with process maps provides a framework to describe coating formation mechanisms, process parametrics and microstructure description.
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References
P. Fauchais and G. Montavon, Latest Developments in Suspension and Liquid Precursor Thermal Spraying, J. Therm. Spray Technol., 2010, 19(1), p 226-239
L. Pawlowski, Finely Grained Nanometric and Submicrometric Coatings by Thermal Spraying: A Review, Surf. Coat. Technol., 2008, 202(18), p 4318-4328
M. Vardelle, A. Vardelle, P. Fauchais, K.I. Li, B. Dussoubs, and N.J. Themelis, Controlling Particle Injection in Plasma Spraying, J. Therm. Spray Technol., 2001, 10(2), p 267-284
J. Fazilleau, C. Delbos, V. Rat, J.F. Coudert, P. Fauchais, and B. Pateyron, Phenomena Involved in Suspension Plasma Spraying Part 1: Suspension Injection and Behavior, Plasma. Chem. Plasma. Phy., 2006, 26(4), p 371-391
R. Vaßen, Z. Yi, H. Kaßner, and D. Stöver, Suspension Plasma Spraying of TiO2 for the Manufacture of Photovoltaic Cells, Surf. Coat. Technol., 2009, 203(15), p 2146-2149
L. Łatka, L. Pawlowski, D. Chicot, C. Pierlot, and F. Petit, Mechanical Properties of Suspension Plasma Sprayed Hydroxyapatite Coatings Submitted to Simulated Body Fluid, Surf. Coat. Technol., 2010, 205(4), p 954-960
O. Tingaud, P. Bertrand, and G. Bertrand, Microstructure and Tribological Behavior of Suspension Plasma Sprayed Al2O3 and Al2O3–YSZ Composite Coatings, Surf. Coat. Technol., 2010, 205(4), p 1004-1008
N. Curry, Z.L. Tang, N. Markocsan, and P. Nylen, Influence of Bond Coat Surface Roughness on the Structure of Axial Suspension Plasma Spray Thermal Barrier Coatings—Thermal and Lifetime Performance, Surf. Coat. Technol., 2015, 268, p 15-23
R. Hui, Z. Wang, O. Kesler, L. Rose, J. Jankovic, S. Yick, R. Maric, and D. Ghosh, Thermal Plasma Spraying for SOFCs: Applications, Potential Advantages, and Challenges, J. Power Sources, 2007, 170(2), p 308-323
K. VanEvery, M.J.M. Krane, R.W. Trice, H. Wang, W. Porter, M. Besser, D. Sordelet, J. Ilavsky, and J. Almer, Column Formation in Suspension Plasma-Sprayed Coatings and Resultant Thermal Properties, J. Therm. Spray Technol., 2011, 20(4), p 817-828
U. Schulz, B. Saruhan, K. Fritscher, and C. Leyens, Review on Advanced EB-PVD Ceramic Topcoats for TBC Applications, Int. J. App. Ceram. Technol., 2004, 1(4), p 302-315
S. Sampath, U. Schulz, M.O. Jarligo, and S. Kuroda, Processing Science of Advanced Thermal-Barrier Systems, MRS Bull., 2012, 37(10), p 903-910
K. VanEvery, M.J.M. Krane, and R.W. Trice, Parametric Study of Suspension Plasma Spray Processing Parameters on Coating Microstructures Manufactured from Nanoscale Yttria-Stabilized Zirconia, Surf. Coat. Technol., 2012, 206(8–9), p 2464-2473
E.M. Cotler, D.Y. Chen, and R.J. Molz, Pressure-Based Liquid Feed System for Suspension Plasma Spray Coatings, J. Therm. Spray Technol., 2011, 20(4), p 967-973
S. Kuroda and T.W. Clyne, The Quenching Stress in Thermally Sprayed Coatings, Thin Solid Films, 1991, 200(1), p 49-66
J. Matejicek, S. Sampath, D. Gilmore, and R. Neiser, In Situ Measurement of Residual Stresses and Elastic Moduli in Thermal Sprayed Coatings: Part 2: Processing Effects on Properties of Mo Coatings, Acta Mater., 2003, 51(3), p 873-885
J. Matejicek and S. Sampath, In Situ Measurement of Residual Stresses and Elastic Moduli in Thermal Sprayed Coatings: Part 1: Apparatus and Analysis, Acta Mater., 2003, 51(3), p 863-872
S. Sampath, V. Srinivasan, A. Valarezo, A. Vaidya, and T. Streibl, Sensing, Control, and In Situ Measurement of Coating Properties: An Integrated Approach Toward Establishing Process-Property Correlations, J. Therm. Spray Technol., 2009, 18(2), p 243-255
Y. Liu, T. Nakamura, V. Srinivasan, A. Vaidya, A. Gouldstone, and S. Sampath, Non-linear Elastic Properties of Plasma-Sprayed Zirconia Coatings and Associated Relationships with Processing Conditions, Acta Mater., 2007, 55(14), p 4667-4678
Y. Liu, T. Nakamura, G. Dwivedi, A. Valarezo, and S. Sampath, Anelastic Behavior of Plasma-Sprayed Zirconia Coatings, J. Am. Ceram. Soc., 2008, 91(12), p 4036-4043
G. Dwivedi, T. Nakamura, and S. Sampath, Controlled Introduction of Anelasticity in Plasma-Sprayed Ceramics, J. Am. Ceram. Soc., 2011, 94, p 104-111
V. Viswanathan, G. Dwivedi, and S. Sampath, Engineered Multilayer Thermal Barrier Coatings for Enhanced Durability and Functional Performance, J. Am. Ceram. Soc., 2014, 97(9), p 2770-2778
V. Viswanathan, G. Dwivedi, and S. Sampath, Multilayer, Multimaterial Thermal Barrier Coating Systems: Design, Synthesis, and Performance Assessment, J. Am. Ceram. Soc., 2015, 98(6), p 1769-1777
C.S. Ramachandran, V. Balasubramanian, and P.V. Ananthapadmanabhan, Multiobjective Optimization of Atmospheric Plasma Spray Process Parameters to Deposit Yttria-Stabilized Zirconia Coatings Using Response Surface Methodology, J. Therm. Spray Technol., 2011, 20(3), p 590-607
T. Streibl, A. Vaidya, M. Friis, V. Srinivasan, and S. Sampath, A Critical Assessment of Particle Temperature Distributions During Plasma Spraying: Experimental Results for YSZ, Plasma. Chem. Plasma. Phy., 2006, 26(1), p 73-102
V. Rat, C. Delbos, C. Bonhomme, J. Fazilleau, J.F. Coudert, and P. Fauchais, Understanding of Suspension Plasma Spraying, High. Temp. Mater., 2004, 8(1), p 95-117
P. Fauchais, V. Rat, J.F. Coudert, R. Etchart-Salas, and G. Montavon, Operating Parameters for Suspension and Solution Plasma-Spray Coatings, Surf. Coat. Technol., 2008, 202(18), p 4309-4317
J. Oberste Berghaus, J.-G. Legoux, C. Moreau, F. Tarasi, and T. Chráska, Mechanical and Thermal Transport Properties of Suspension Thermal-Sprayed Alumina-Zirconia Composite Coatings, J. Therm. Spray Technol., 2008, 17(1), p 91-104
C. Delbos, J. Fazilleau, V. Rat, J.-F. Coudert, P. Fauchais, and B. Pateyron, Phenomena Involved in Suspension Plasma Spraying Part 2: Zirconia Particle Treatment and Coating Formation, Plasma. Chem. Plasma. Phy., 2006, 26(4), p 393-414
A. Joulia, W. Duarte, S. Goutier, M. Vardelle, A. Vardelle, and S. Rossignol, Tailoring the Spray Conditions for Suspension Plasma Spraying, J. Therm. Spray Technol., 2015, 24(1–2), p 24-29
H. Kassner, R. Siegert, D. Hathiramani, R. Vassen, and D. Stoever, Application of Suspension Plasma Spraying (SPS) for Manufacture of Ceramic Coatings, J. Therm. Spray Technol., 2008, 17(1), p 115-123
S. Sampath, X.Y. Jiang, J. Matejicek, A.C. Leger, and A. Vardelle, Substrate Temperature Effects on Splat Formation, Microstructure Development and Properties of Plasma Sprayed Coatings Part I: Case Study for Partially Stabilized Zirconia, Mater. Sci. Engg. A., 1999, 272(1), p 181-188
M. Marr and O. Kesler, Permeability and Microstructure of Suspension Plasma-Sprayed YSZ Electrolytes for SOFCs on Various Substrates, J. Therm. Spray Technol., 2012, 21(6), p 1334-1346
A. Ganvir, N. Curry, S. Björklund, N. Markocsan, and P. Nylén, Characterization of Microstructure and Thermal Properties of YSZ Coatings Obtained by Axial Suspension Plasma Spraying (ASPS), J. Therm. Spray Technol., 2015, 24(7), p 1195-1204
A. Vaidya, V. Srinivasan, T. Streibl, M. Friis, W. Chi, and S. Sampath, Process Maps for Plasma Spraying of Yttria-Stabilized Zirconia: An Integrated Approach to Design, Optimization and Reliability, Mater. Sci. Eng. A., 2008, 497(1), p 239-253
A. Valarezo, W.B. Choi, W. Chi, A. Gouldstone, and S. Sampath, Process Control and Characterization of NiCr Coatings by HVOF-DJ2700 System: A Process Map Approach, J. Therm. Spray Technol., 2010, 19(5), p 852-865
R. Vaßen, H. Kaßner, G. Mauer, and D. Stöver, Suspension Plasma Spraying: Process Characteristics and Applications, J. Therm. Spray Technol., 2010, 19(1), p 219-225
M. Mutter, G. Mauer, R. Mücke, R. Vaßen, H.C. Back, and J. Gibmeier, Investigations on the Initial Stress Evolution During Atmospheric Plasma Spraying of YSZ by In Situ Curvature Measurement, J. Therm. Spray Technol., 2016, 25(4), p 672-683
K. Shinoda, J. Colmenares-Angulo, A. Valarezo, and S. Sampath, Effect of Deposition Rate on the Stress Evolution of Plasma-Sprayed Yttria-Stabilized Zirconia, J. Therm. Spray Technol., 2012, 21(6), p 1224-1233
A. Valarezo and S. Sampath, An Integrated Assessment of Process-Microstructure-Property Relationships for Thermal-Sprayed NiCr Coatings, J. Therm. Spray Technol., 2011, 20(6), p 1244-1258
M. Gupta, G. Dwivedi, P. Nylen, A. Vackel, and S. Sampath, An Experimental Study of Microstructure-Property Relationships in Thermal Barrier Coatings, J. Therm. Spray Technol., 2013, 22(5), p 659-670
C.G. Levi, J.W. Hutchinson, M.-H. Vidal-Sétif, and C.A. Johnson, Environmental Degradation of Thermal-Barrier Coatings by Molten Deposits, MRS Bull., 2012, 37(10), p 932-941
Acknowledgments
This work was supported in part by the National Science Foundation—Partnership for Innovation (NSF-PFI Grant No. IIP-1114205) and The Consortium for Thermal Spray Technology of Stony Brook University. The authors appreciate the Oerlikon Metco Team: Jose Colmenares-Angulo, Riston Rocchio-Heller, Jing Liu, Jonathan Gutleber, Ronald Molz, David Hawley, Montia Nestler, Michael Tobin and Richard Schmid for the help and support in setting up a suspension spray system at Stony Brook.
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Chidambaram Seshadri, R., Dwivedi, G., Viswanathan, V. et al. Characterizing Suspension Plasma Spray Coating Formation Dynamics through Curvature Measurements. J Therm Spray Tech 25, 1666–1683 (2016). https://doi.org/10.1007/s11666-016-0460-2
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DOI: https://doi.org/10.1007/s11666-016-0460-2