Abstract
Effect of N addition on microstructural evolutions and mechanical properties of a 201L austenitic stainless steel during the martensite thermomechanical treatment was investigated. The as-homogenized samples were cold-rolled by 90% thickness reduction followed by reversion annealing at 800-900 °C for different times of 15-1800 s. The microstructures were characterized by optical and scanning electron microscopy and magnetic measurement, while mechanical properties were determined by hardness and shear punch tests. It was found that N addition retards the kinetics of strain-induced martensitic transformation, but accelerates the martensite reversion. The hardness, yield and ultimate shear strengths were increased by N alloying at the expense of elongation in both solution-annealed and reversion-annealed specimens.
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References
M.F. McGuire, Stainless Steels for Design Engineers, ASM International, Metals Park, 2008
http://www.aws.org/w/a/wj/1998/11/kotecki. Website of American Welding Society, accessed on 15 Feb 2016
K.H. Lo, C.H. Shek, and J.K.L. Lai, Recent Developments in Stainless Steels, Mater. Sci. Eng. R, 2009, 65, p 39–104
J.W. Simmons, Overview: High-Nitrogen Alloying of Stainless Steels, Mater. Sci. Eng. A, 1996, 207, p 159–169
J. Talonen, in Effect of Strain-Induced α’-Martensite Transformation on Mechanical Properties of Metastable Austenite Stainless Steels, PhD. Dissertation, Helsinki University of Technology, Department of Mechanical Engineering, Laboratory of Engineering Materials, Helsinki, 2007
H.K.D.H. Bhadeshia and R. Honeycombe, Steels Microstructure and Properties, 3rd ed., Elsevier Science, Oxford, 2006
G.E. Dieter, Mechanical Metallurgy, 3rd ed., McGraw-Hill, New York, 1976
R. Song, D. Ponge, D. Raabe, J.G. Speer, and D.K. Matlock, Overview of Processing, Microstructure and Mechanical Properties of Ultrafine Grained BCC Steels, Mater. Sci. Eng. A, 2006, 441, p 1–17
A. Hedayati, A. Najafizadeh, A. Kermanpur, and F. Forouzan, The Effect of Cold Rolling Regime on Microstructure and Mechanical Properties of AISI, 304L Stainless Steel, J. Mater. Proc. Tech., 2010, 210, p 1017–1022
M. Eskandari, A. Najafizadeh, and A. Kermanpur, Effect of Strain-Induced Martensite on the Formation Of Nanocrystalline 316L Stainless Steel After Cold Rolling and Annealing, Mater. Sci. Eng. A, 2009, 519, p 46–50
M. Eskandari, A. Kermanpur, and A. Najafizadeh, Formation of Nano-Grained Structure in a 301 Stainless Steel Using a Repetitive Thermo-Mechanical Treatment, Mater. Lett., 2009, 30, p 1442–1444
M. Moallemi, A. Najafizadeh, A. Kermanpur, and A. Rezaee, Effect of Reversion Annealing on the Formation of Nano/Ultrafine Grained Structure in 201 Austenitic Stainless Steel, Mater. Sci. Eng. A, 2011, 530, p 378–381
A. Rezaee, A. Kermanpur, A. Najafizadeh, and M. Moallemi, Production of Nano/Ultrafine Grained AISI, 201L Stainless Steel Through Advanced Thermomechanical Treatment, Mater. Sci. Eng. A, 2011, 528, p 5025–5029
H. Samaei Baghbadorani, A. Kermanpur, A. Najafizadeha, P. Behjati, A. Rezaee, and M. Moallemi, An Investigation on Microstructure and Mechanical Properties of a Nb-Microalloyed Nano/Ultrafine Grained 201 Austenitic Stainless Steel, Mater. Sci. Eng. A, 2015, 636, p 593–599
S. Sadeghpour, A. Kermanpur, and A. Najafizadeh, Influence of Ti Microalloying on the Formation of Nanocrystalline Structure in the 201L Austenitic Stainless Steel During Martensite Thermomechanical Treatment, Mater. Sci. Eng. A, 2013, 584, p 177–183
A. Kisko, J. Talonnen, D.A. Porter, and L.P. Karjalainen, Effect of Nb Microalloying on Reversion and Grain Growth in a High-Mn 204Cu Austenitic Stainless Steel, ISIJ Int., 2015, 55, p 2217–2224
W. Conshohocken, Steel Products Manual Stainless Steels (ISS Publications, USA, 1999)
J. Rawers and G. Slavens, Strengthening Characteristics of Nitrogen-Alloyed 201 Stainless Steel, J. Mater. Eng. Perform., 1995, 4, p 697–708
L. Sun, J. Li, L. Zhang, S. Yang, and Y. Chen, Production of Nitrogen-Bearing Stainless Steel by Injecting Nitrogen Gas, J. Iron. Steel Res. Int., 2011, 18, p 07–11
X.P. Ma, L.J. Wang, B. Qin, C.M. Liu, and S.V. Subramanian, Effect of N on Microstructure and Mechanical Properties of 16Cr5Ni1Mo Martensitic Stainless Steel, Mater. Des., 2012, 34, p 74–81
T.H. Lee, E. Shin, Ch.S. Oh, H.Y. Ha, and S.J. Kim, Correlation Between Stacking Fault Energy and Deformation Microstructure in High-Interstitial-Alloyed Austenitic Steels, Acta Mater., 2010, 58, p 3173–3186
J.Y. Choi, J.H. Ji, S.W. Hwang, and K.-T. Park, Strain Induced Martensitic Transformation of Fe-20Cr-5Mn-0.2Ni Duplex Stainless Steel During Cold Rolling: Effects of Nitrogen Addition, Mater. Sci. Eng. A, 2011, 528, p 6012–6019
R.D.K. Misra, Z. Zhang, P.K.C. Venkatasurya, M.C. Somani, and L.P. Karjalainen, The Effect of Nitrogen on the Formation of Phase Reversion-Induced Nanograined/Ultrafine-Grained Structure and Mechanical Behavior of a Cr–Ni–N Steel, Mater. Sci. Eng. A, 2011, 528, p 1889–1896
S. Rajasekhara and P.J. Ferreira, Martensite → Austenite Phase Transformation Kinetics in an Ultrafine-Grained Metastable Austenitic Stainless Steel, Acta Mater., 2011, 59, p 738–748
P. Behjati, A. Kermanpur, A. Najafizadeh, H. Samaei Baghbadorani, L.P. Karjalainen, J.-G. Jung, and Y.-K. Lee, Effect of Nitrogen Content on Grain Refinement and Mechanical Properties of a Reversion Treated Ni-Free 18Cr-12Mn Austenitic Stainless Steel, Metall. Mater. Trans. A, 2014, 45, p 6317–6328
R.D.K. Misra, Z. Zhang, P.K.C. Venkatasurya, M.C. Somani, and L.P. Karjalainen, Martensite Shear Phase Reversion-Induced Nanograined/Ultrafine-Grained Fe-16Cr-10Ni Alloy: The Effect of Interstitial Alloying Elements and Degree of Austenite Stability on Phase Reversion, Mater. Sci. Eng. A, 2010, 527, p 7779–7792
S. Goyal, V. Karthik, K.V. Kasiviswanathan, M. Valsan, K. Bhanu, S. Rao, and B. Raj, Finite Element Analysis of Shear Punch Testing and Experimental Validation, Mater. Des., 2010, 31, p 2546–2552
V. Karthik, K.V. Kasiviswanathan, K. Laha, and B. Raj, Determination of Gradients in Mechanical Properties of 2.25Cr-1Mo Weldments Using Shear-Punch Tests, Weld J. Suppl., 2002, 3, p 265–272
M. Eskandari, A. Zarei-Hanzaki, and H.R. Abedi, An Investigation into the Room Temperature Mechanical Properties of Nanocrystalline Austenitic Stainless Steels, Mater. Des., 2013, 45, p 674–681
S.M. Hosseini, A. Kermanpur, A. Najafizadeh, and M. Alishahi, Effect of Process Parameters on Microstructures and Mechanical Properties of a Nano/Ultrafine Grained Low Carbon Steel Produced by Martensite Treatment Using Plane Strain Compression, Iron Steel Inst. Jpn., 2012, 52, p 464–470
T. Angel, Formation of Martensite in Austenitic Stainless Steel, J. Iron Steel Inst. Jpn., 1954, 5, p 165–174
Q.X. Dai, A.D. Wang, X.N. Cheng, and X.M. Luo, Stacking Fault Energy of Cryogenic Austenitic Steels, Chin. Phys., 2002, 11, p 596–600
P. Behjati, A. Kermanpur, A. Najafizadeh, and H. Samaei, Baghbadorani, Microstructural Investigation on Deformation Behavior of High Purity Fe–Cr–Ni Austenitic Alloys During Tensile Testing at Different Temperatures, Mater. Sci. Eng. A, 2014, 618, p 16–21
L. Kaufman, The Free-Energy Changes Attending the Martensitic Transformation in the Iron-Chromium and Iron-Chromium-Nickel Systems, Trans. Met. Soc., 1959, 215, p 218–227
M.C. Somani, P. Juntunen, L.P. Karjalainen, R.D.K. Misra, and A. Kyröläinen, Enhanced Mechanical Properties Through Reversion in Metastable Austenitic Stainless Steels, Metall. Mater. Trans. A, 2009, 4, p 729–744
S. Saeedipour, A. Kermanpur, A. Najafizadeh, and M. Abbasi, Microstructures and Mechanical Properties of Nano/Ultrafine-Grained N-Bearing, Low-Ni Austenitic Stainless Steels, J. Mater. Eng. Perform., 2015, 24, p 1018–1025
G. Dini, A. Najafizadeh, S.M. Monir-Vaghefi, and R. Ueji, Grain Size Effect on the Martensite Formation in a High-Manganese TWIP Steel by the Rietveld Method, J. Mater. Sci. Technol., 2010, 26, p 181–186
H. Azizi-Alizamini, M. Militzer, and W.J. Poole, A Novel Technique for Developing Bimodal Grain Size Distributions in Low Carbon Steels, Scripta Mater., 2007, 57, p 1065–1068
K. Tomimura, S. Takaki, and Y. Tokuna, Reversion Mechanism from Deformation Induced Martensite in Metastable Austenitic Stainless Steels, ISIJ Int., 1991, 31, p 1431–1437
L. Kaufman, E.V. Clougherty, and R.J. Weiss, The Lattice Stability of Metals—III, Iron, Acta Metall., 1963, 11, p 323–335
M. Karimi, A. Najafizadeh, A. Kermanpur, and M. Eskandari, Effect of Martensite to Austenite Reversion on the Formation of Nano/Submicron Grained AISI, 301 Stainless Steel, Mater. Charact., 2009, 60, p 1220–1223
M. Eskandari, A. Najafizadeh, A. Kermanpur, and M. Karimi, Potential Application of Nanocrystalline 301 Austenitic Stainless Steel in Lightweight Vehicle Structures, Mater. Des., 2009, 30, p 3869–3872
G.H. Eichelmann and F.C. Hull, The Effect of Composition of Spontaneous Transformation of Austenite to Martensite in 18-8-Type Stainless Steel, Trans. Am. Soc. Metall., 1953, 45, p 77–95
H. Berns, F. Krafft, Influence of a thermomechanic treatment on the mechanical properties of creep resistant steel alloyed with nitrogen under pressure. Proceedings of 2nd International Conference on High Nitrogen Steels, 1999, pp. 338–342
C.-K. Lee, Ch.-S. Yoo, A. Kermanpur, and Y.-K. Lee, The Effects of Multi-Cyclic Thermo-Mechanical Treatment on the Grain Refinement and Tensile Properties of a Metastable Austenitic Steel, J. Alloys Compd., 2014, 583, p 357–360
S. Rajasekhara, L.P. Karjalainen, A. Kyrolainen, and P.J. Ferreira, Microstructure Evolution in Nano/Submicron Grained AISI, 301LN Stainless Steel, Mater. Sci. Eng. A, 2010, 527, p 1986–1996
S. Fréchard, A. Redjϊmia, E. Lach, and A. Lichtenberger, Mechanical Behaviour of Nitrogen-Alloyed Austenitic Stainless Steel Hardened by Warm Rolling, Mater. Sci. Eng. A, 2006, 415, p 219–224
D.W. Kim, Influence of Nitrogen-Induced Grain Refinement on Mechanical Properties of Nitrogen Alloyed Type 316LN Stainless Steel, J. Nucl. Mater., 2012, 420, p 473–478
P. Shankar, D. Sundararaman, and S. Ranganathan, Clustering and Ordering of Nitrogen in Nuclear Grade 316LN Austenitic Stainless Steel, J. Nucl. Mater., 1998, 254, p 1–8
W.F. Hosford, Mechanical Behavior of Materials, Cambridge University Press, Cambridge, 2005
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The authors would like to express their thanks to Dr. P. Behjati and Mr. M. Fadavi for their kind collaborations.
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Saeedipour, S., Kermanpur, A. & Najafizadeh, A. Effect of N on Phase Transformations During Martensite Thermomechanical Processing of the Nano/Ultrafine-Grained 201L Steel. J. of Materi Eng and Perform 25, 5502–5512 (2016). https://doi.org/10.1007/s11665-016-2387-7
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DOI: https://doi.org/10.1007/s11665-016-2387-7