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Benign Preparation of Metal–Organic Frameworks of Trimesic Acid and Cu, Co or Ni for Potential Sensor Applications

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Abstract

Metal–organic frameworks (MOFs) have been constructed using trimesic acid (TMA) as organic linker and Co(II), Ni(II) or Cu(II) metal ions from their corresponding aqueous chloride salts at room temperature. The prepared TMA–M (M: Co, Ni, and Cu) MOFs have been characterized in terms of their porosity and optical, thermal, electrical, and structural properties. The prepared MOFs were characterized in terms of their porosity through Brunauer–Emmett–Teller measurements, yielding a value of 330 m2/g for the TMA–Cu MOF. Structural analysis and thermal characterization of the prepared MOFs were done by using Fourier-transform infrared (FT-IR) spectroscopy, x-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), and thermogravimetric analysis (TGA), respectively. The optical properties were analyzed by fluorescence spectroscopy. Additionally, TMA–M MOF disks were prepared and their conductivities determined by room-temperature I–V measurements. The conductivity of the TMA–M MOFs was calculated to be between 7.97 × 10−7 S/cm and 5.39 × 10−9 S/cm.

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Acknowledgements

The project was supported by King Saud University, Deanship of Scientific Research, Research Chair.

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Authors and Affiliations

  1. Nanoscience and Technology Research and Application Center (NANORAC), Faculty of Sciences and Arts, Canakkale Onsekiz Mart University, Terzioglu Campus, Canakkale, 17100, Turkey

    Kivanc Sel & Nurettin Sahiner

  2. Departments of Physics, Canakkale Onsekiz Mart University, Terzioglu Campus, Canakkale, 17100, Turkey

    Kivanc Sel

  3. Departments of Chemistry, Canakkale Onsekiz Mart University, Terzioglu Campus, Canakkale, 17100, Turkey

    Sahin Demirci, Engin Meydan, Sema Yildiz, Omer Faruk Ozturk & Nurettin Sahiner

  4. Surfactants Research Chair, Department of Chemistry, College of Science, King Saud University, Riyadh, Saudi Arabia

    Hamad Al-Lohedan & Nurettin Sahiner

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  1. Kivanc Sel
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  2. Sahin Demirci
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  3. Engin Meydan
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  7. Nurettin Sahiner
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Correspondence to Nurettin Sahiner.

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Sel, K., Demirci, S., Meydan, E. et al. Benign Preparation of Metal–Organic Frameworks of Trimesic Acid and Cu, Co or Ni for Potential Sensor Applications. J. Electron. Mater. 44, 136–143 (2015). https://doi.org/10.1007/s11664-014-3444-3

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  • DOI: https://doi.org/10.1007/s11664-014-3444-3

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