Annealing-Induced Morphological Changes in Nanocrystalline Quantum Dots and Their Impact on Charge Transport Properties
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- Biswas, S., Gosztola, D.J., Wiederrecht, G.P. et al. Journal of Elec Materi (2012) 41: 524. doi:10.1007/s11664-011-1815-6
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The effects of thermal annealing on the morphological and photoconductive properties of cadmium selenide quantum dots coated with zinc sulfide are studied. The results of transmission electron microscopy with in situ annealing show a number of events taking place simultaneously, including aggregation of dots, changes in the size and shape distribution, and reduction in interdot separation. Transient absorption results indicate that there is a small redshift of the spectrum. There is a shortening of the absorption decay lifetimes due to annealing. Higher photocurrents are measured in the annealed compared with unannealed dots at room temperature.