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Some Metallurgical Issues Concerning Austenite Conditioning in Nb-Ti and Nb-Mo Microalloyed Steels Processed by Near-Net-Shape Casting and Direct Rolling Technologies

  • Symposium: PTM 2015: Solid-Solid Phase Transformations in Inorganic Materials
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Abstract

As thin slab direct rolling technologies are moving to the production of higher quality steel grades, chemical compositions based on Nb-Ti and Nb-Mo become a good option. However, with the use of multiple microalloying additions, the as-cast austenite conditioning becomes more complex. This paper analyzes some of the microstructural features that should be taken into account during the as-cast austenite conditioning in Nb-Ti and Nb-Mo microalloyed steel grades. In the case of Nb-Ti grades, it has been observed that the process parameters during solidification and post-solidification steps affect the austenite evolution during hot rolling. This is due to the differences in the size and volume fraction of TiN particles that can be formed. Fine TiN precipitates have been shown to be able to delay recrystallization kinetics. Moreover, the solute drag effect of Ti cannot be ignored in the case of hyperstoichiometric Ti/N ratios. It is observed that Nb-Ti grades tend to have lower non-recrystallization temperatures compared to Nb grades, which means that pancaking of the austenite is more difficult for these steels. The opposite is observed for the Nb-Mo grades, although in both cases the behavior is affected by the nominal content of Nb.

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References

  1. [1] S. Vervynckt, K. Verbeken, B. Lopez and J. J. Jonas: Int. Mater. Rev., 2012, vol. 57, pp. 187-207.

    Article  Google Scholar 

  2. [2] M.A. Altuna, A. Iza-Mendia and I. Gutierrez: Metall. Mater. Trans. A, 2012, vol. 43A, pp. 4571-4586.

    Article  Google Scholar 

  3. [3] D.N. Crowther and W.B. Morrison: Titanium Technology in Microalloyed Steels, Institute of Materials, London, UK, 1997, pp. 44-64.

    Google Scholar 

  4. [4] M. Militzer, E.B. Hawbolt and T.R. Meadowcroft: Metall. Mater. Trans. A, 2000, vol. 31A, pp. 1247-1259.

    Article  Google Scholar 

  5. [5] N. Isasti, D. Jorge-Badiola, M. L. Taheri and P. Uranga: Metall. Mater. Trans. A, 2014, vol. 45A, pp. 4960-4971.

    Article  Google Scholar 

  6. [6] R. Lagneborg, T. Siwecki, S. Zajac and B. Hutchinson: Scand. J. Metall., 1999, vol. 28, pp. 186-241.

    Google Scholar 

  7. B. Bacroix, M. G. Akben and J.J. Jonas: Proc. of Microalloyed Austenite, P.J. Wray and A.J. DeArdo, eds., AIME, Warrendale, PA, 1982, pp. 293–318.

  8. [8] W.B. Lee, S.G. Hong, C.G. Park, K.H. Kim and S.H. Park: Scripta Mater., 2000, vol. 43, pp. 319-324.

    Article  Google Scholar 

  9. [9] M. G. Akben, B. Bacroix and J.J. Jonas: Acta Metall., 1983, vol. 31, pp. 161-174.

    Article  Google Scholar 

  10. [10] B. Pereda, A. Fernandez, B. López and J.M. Rodriguez-Ibabe, ISIJ Int., 2007, vol. 47, pp. 860-868.

    Article  Google Scholar 

  11. [11] M.G. Akben, I. Weiss and J.J. Jonas: Acta Metall., 1981, vol. 29, pp. 111-121.

    Article  Google Scholar 

  12. [12] J.G. Speer and S.S. Hansen: Metall. Trans. A, 1989, vol. 20A, pp. 25-38.

    Article  Google Scholar 

  13. [13] O. Kwon and A.J. DeArdo: Acta Metall. Mater., 1991, vol. 39, pp. 529-538.

    Article  Google Scholar 

  14. [14] M. D. Kashif Rehman and H. S. Zurob: Metall. Mater. Trans. A, 2013, vol. 44A, pp. 1862-1871.

    Google Scholar 

  15. [15] P. Gong, E.J. Palmiere and W.M. Rainforth: Acta Mater., 2015, vol. 97, pp. 392–403.

    Article  Google Scholar 

  16. J.M. Rodriguez-Ibabe, P. Uranga and B. López: J. Iron Steel Res. Int., 2011, vol. 18 (sup. 1), pp. 459-465.

    Google Scholar 

  17. [17] P. Uranga, A.I. Fernandez, B. Lopez and J.M. Rodriguez-Ibabe: Mater. Sci. Forum, 2005, vol. 500-501, pp. 245-252.

    Article  Google Scholar 

  18. [18] F.B. Pickering: Titanium Technology in Microalloyed Steels, Institute of Materials, London, UK, 1997, pp. 10-43.

    Google Scholar 

  19. [19] M.A. Linaza, J.M. Rodriguez-Ibabe and J.J. Urcola: Fatigue Fract. Eng. Mater. Struct., 1997, vol. 20, pp. 619-632.

    Article  Google Scholar 

  20. [20] D.P. Fairchild, D.G. Howden and W.A.T. Clark: Metall. Mater. Trans. A, 2000, vol. 31A, pp. 653-667.

    Article  Google Scholar 

  21. [21] V. Descotes, S. Migot, F. Robaut, J-P. Bellot, V. Perrin-Guérin, S. Witzke and A. Jardyet: Metall. Mater. Trans. A, 2015, vol. 46A, pp. 2793-2795.

    Article  Google Scholar 

  22. [22] P. Rocabois, J. Lehmann, H. Gaye and M. Wintz: J. Cryst. Growth, 1999, vol. 198/199, pp. 838-843.

    Article  Google Scholar 

  23. J. Stock, C.M. Enloe, R.J. O`Malley, K.O. Findley and J.G. Speer: Iron & Steel Technol., 2014, vol. 11 (June), pp. 180-186.

    Google Scholar 

  24. A. M. Sage, R. C. Cochrane, D. Howse: Proc. Intern. Conf. on Processing, Microstructure and Properties of Microalloyed and other Modern HSLA Steels, Pittsburgh, PA, USA, 1992, pp. 443–60.

  25. V. Leroy and J.C. Herman: Microalloying 95 Conference Proceedings, 1995, pp. 213–23.

  26. [26] M. Arribas, B. López and J.M. Rodriguez-Ibabe: Mater. Sci. Eng. A, 2008, vol. 485, pp. 383-394.

    Article  Google Scholar 

  27. [27] H. Luo, L.P. Karjalainen, D.A. Porter, H-M. Liimatainen and Y. Zhang: ISIJ Int., 2002, vol. 42, pp. 273-282.

    Article  Google Scholar 

  28. [28] M. T. Nagata, J. G. Speer and D. K. Matlock: Metall. Mater. Trans. A, 2002, vol. 33A, pp. 3099-3110.

    Article  Google Scholar 

  29. [29] M. Bai, D. Liu, Y. Lou, X. Mao, L. Li and X. Huo: J. Univ. Science Technol. Beijing, 2006, vol. 13, pp. 230-234.

    Article  Google Scholar 

  30. L. A. Leduc and C. M. Sellars: Proc. Int. Conference on Thermomechanical Processing of Microalloyed Austenite, Pittsburgh, PA, USA, 1982, pp. 641–54.

  31. [31] M.I. Vega, S. F. Medina, A. Quispe, M. Gómez and P.P. Gómez: Mater. Sci. Eng. A, 2006, vol. 423, pp. 253-261.

    Article  Google Scholar 

  32. [32] W. Roberts, A. Sandberg, T. Siwecki and T. Werlefors: HSLA Steels. Technology and Applications, ASM, Ohio, PA, USA, 1984, pp. 67-84.

    Google Scholar 

  33. K. Kunishige and N. Nagao: ISIJ Int., 1989, vol. 29, pp. 940-946.

    Article  Google Scholar 

  34. [34] A.I. Fernández, P. Uranga, B. López and J.M. Rodriguez-Ibabe: ISIJ Int., 2000, vol. 40, pp. 893-901.

    Article  Google Scholar 

  35. [35] Z. Aretxabaleta, B. Pereda and B. López: Mater. Sci. Eng. A, 2014, vol. 600, pp. 37-46.

    Article  Google Scholar 

  36. [36] P. Uranga, A. I. Fernández, B. López and J. M. Rodriguez-Ibabe: Thermomechanical Processing of Steels, Institute of Materials, London, 2000, vol. 1, pp. 204-213.

    Google Scholar 

  37. [37] B. Dutta, E. Valdes and C.M. Sellars: Acta Mater., 1992, vol. 40, pp. 653-662.

    Article  Google Scholar 

  38. [38] E.J. Palmiere, C.I. Garcia and A.J. DeArdo: Metall. Trans. A, 1996, vol. 27A, pp. 951-960.

    Article  Google Scholar 

  39. [39] Q.Y. Sha, D.A. Li and G.Y. Li: J. Iron Steel Research Int., 2014, vol. 21, pp. 232–239.

    Article  Google Scholar 

  40. [40] Q.Y. Sha, Z.Q Sun and L.F. Li: Ironmaking Steelmaking, 2015, vol. 42, pp. 74-80.

    Article  Google Scholar 

  41. [41] X. P. Mao, Q. L. Chen and X. J. Sun: J. Iron Steel Research Int., 2014, vol. 21, pp. 30-40.

    Article  Google Scholar 

  42. [42] B. Pereda, B. López and J.M. Rodriguez-Ibabe: Mater. Sci. Forum, 2010, vol. 638-642, pp. 687-692.

    Article  Google Scholar 

  43. [43] N. Isasti, B. Pereda, B. López, J.M. Rodriguez-Ibabe and P. Uranga: Fundamentals and applications of Mo and Nb Alloying in High Performance Steels, vol. 2, CBMM, IMOA and TMS, 2015, pp. 1-28.

    Google Scholar 

  44. [44] B. Dutta and C. M. Sellars: Mater. Sci. Technol., 1987, vol. 3, pp. 197-206.

    Article  Google Scholar 

  45. [45] B. Pereda, J.M. Rodriguez-Ibabe and B. López: ISIJ Int., 2008, vol. 48, pp. 1457-1466.

    Article  Google Scholar 

  46. [46] C. Klinkenberg, C. Bilgen, J.M. Rodriguez Ibabe, B. López and P. Uranga: Mater. Sci. Forum, 2012, vol. 706-709, pp. 2752-2757.

    Article  Google Scholar 

  47. R. Abad, B. López and J.M. Rodriguez-Ibabe: J. Mater. Proc. Technol., 117/3, CD-ROM Section C4.

  48. Ceit, unpublished work.

  49. [49] S.G. Hong, K.B. Kang and C.G. Park: Scripta Mater., 2002, vol. 46, pp. 163-168.

    Article  Google Scholar 

  50. [50] Y. Lee and B.C. De Cooman: ISIJ Int., 2014, vol. 54, pp. 893-899.

    Article  Google Scholar 

  51. [51] Z. Wang, Q. Yong, X. Sun, Z. Yang, Z. Li, Ch. Zhang and Y. Weng: ISIJ Int., 2012, vol. 52, pp. 1661-1669.

    Article  Google Scholar 

  52. [52] J-G. Jung, J-S. Park, J. Kim and Y-K. Lee: Mater. Sci. Eng. A, 2011, vol. 528, pp. 5529-5535.

    Article  Google Scholar 

  53. B. Pereda, B. López and J.M. Rodriguez-Ibabe: Proc. Int. Conf. on Microalloyed Steels, AIST, Warrendale, USA, 2007, pp. 151–59.

  54. B. Pereda, Doctoral Thesis, University of Navarra, 2009.

  55. [55] S-Q. Yuan, G-L. Liang and X-J. Guo: J. Iron Steel Research Int., 2010, vol. 17, pp. 60-63.

    Article  Google Scholar 

  56. [56] C.M. Enloe, K.O. Findley, C.M. Parish, M.K. Miller, B.C. De Cooman and J.G. Speer: Scripta Mater., 2013, vol. 68, pp. 55–58.

    Article  Google Scholar 

  57. C-P. Reip, M. Frommert and M. Reifferscheid: Baosteel BAC Conference, 2013, J-47.

  58. [58] M. Olasolo, P. Uranga, J.M. Rodriguez Ibabe, B. López: Mater. Sci. Eng. A, 2011, vol. 528, pp. 2559-2569.

    Google Scholar 

  59. [59] N. Isasti, D. Jorge-Badiola, M. L. Taheri, B. López and P. Uranga: Metall. Mater. Trans. A, 2011, vol. 42A, pp. 3729-3742.

    Article  Google Scholar 

  60. [60] N. Isasti, D. Jorge-Badiola, M. L. Taheri and P. Uranga: Metall. Mater. Trans. A, 2014, vol. 45A, pp. 4972-4982.

    Article  Google Scholar 

  61. [61] P. Cizek, B.P. Wynne, C.H.J. Davies and P.D. Hodgson: Metall. Mater. Trans. A, 2015, vol. 46A, pp. 407-425.

    Article  Google Scholar 

  62. [62] K. Kamibayashi, Y. Tanabe, Y. Takemoto, I. Shimizu and T. Senuma: ISIJ Int., 2012, vol. 52, pp. 151–157.

    Article  Google Scholar 

  63. [63] A. Ray, S. Sivaprasad and D. Chakrabarti: Int. J. Fract., 2012, vol. 173, pp. 215-222.

    Article  Google Scholar 

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Acknowledgment

Partial financial support of this work by the Basque Government (Elkartek KK-2015/00049 project) is gratefully acknowledged.

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Correspondence to Jose M. Rodriguez-Ibabe.

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Manuscript submitted January 15, 2016.

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López, B., Rodriguez-Ibabe, J.M. Some Metallurgical Issues Concerning Austenite Conditioning in Nb-Ti and Nb-Mo Microalloyed Steels Processed by Near-Net-Shape Casting and Direct Rolling Technologies. Metall Mater Trans A 48, 2801–2811 (2017). https://doi.org/10.1007/s11661-016-3727-9

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