Skip to main content
Log in

Evaluation of Solid-Solution Hardening of Fe-27 at. pct Al by Vanadium and Comparison to Precipitation Strengthening by Vanadium Carbides

  • Published:
Metallurgical and Materials Transactions A Aims and scope Submit manuscript

Abstract

The compressive yield stress of Fe-27Al-xV(-C) (x = 0 to 4 at. pct) at 1073 K (800 °C) has been determined. The increase of the yield stress of Fe-Al by increasing vanadium content is explained by solid-solution hardening. The experimentally observed values of the yield stress at 1073 K (800 °C) are compared with the strengthening given by theories evaluating the interaction between solute atoms and dislocations. The experimental results fit well the increase of the yield stress by the interaction of the solute atoms with screw dislocations. Further increase in yield strength in similar alloys due to vanadium carbides is documented. Precipitated carbides were identified by transmission electron microscopy and Kikuchi patterns. Although precipitation of vanadium carbides increases the compressive yield stress, they also could result in premature failure in tension as their highly anisotropic shape may facilitate crack nucleation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. D. Hardwick and G. Wallwork: Rev. High Temp. Mater., 1978, vol.4, pp. 47–74.

    Google Scholar 

  2. C.G. McKamey, in Physical Metallurgy and Processing of Intermetallic Compounds, N.S. Stoloff and V.K. Sikka, eds., Chapman & Hall, New York, 1996, p. 351.

    Chapter  Google Scholar 

  3. D.G. Morris and M.A. Munoz-Morris: Adv. Eng. Mater., 2011, vol. 13, pp. 43–47.

    Article  Google Scholar 

  4. M. Palm: Intermetallics, 2005, vol. 13, pp. 1286–1295.

    Article  Google Scholar 

  5. D.G. Morris: Intermetallics, 1998, vol. 6, pp. 753–758.

    Article  Google Scholar 

  6. K. Vedula: in Intermetallic Compounds Vol. 2, Practice, J.H. Westbrook and R.L. Fleischer, eds., Wiley, Chichester, 1995, p. 199.

    Google Scholar 

  7. M.G. Mendiratta, Mat. Res. Soc. Symp. Proc., 1987, vol. 81, pp. 393–404.

    Article  Google Scholar 

  8. R.L. Fleischer: in The Strengthening of Metals, D. Peckner, ed., Reinhold, New York, 1964, p. 93.

    Google Scholar 

  9. R. Labusch: phys. status solidi (b), 1970, vol. 41(2), pp. 659–669.

    Article  Google Scholar 

  10. Y. Nishino, C. Kumada, and S. Asano: Scripta Mater., 1997, vol. 36(4), pp. 461–466.

    Article  Google Scholar 

  11. T. Maebashi, T. Kozakai, and M. Doi: Z. Metallkd., 2004, vol. 95(11), pp. 1005–1010.

    Article  Google Scholar 

  12. V. Raghavan: J. Phase Equilib. Diffus., 2006, vol. 27(3), pp. 283–283.

    Article  Google Scholar 

  13. A. Schneider, L. Falat, G. Sauthoff, and G. Frommeyer: Intermetallics, 2003, vol. 11, pp. 443–450.

    Article  Google Scholar 

  14. L. Falat, A. Schneider, G. Sauthoff, and G. Frommeyer: Intermetallics, 2005, vol. 13(12), pp. 1256–1262.

    Article  Google Scholar 

  15. D.G. Morris and M.A. Munoz-Morris: Intermetallics, 2005, vol. 13(12), pp. 1269–1274.

    Article  Google Scholar 

  16. G. Hasemann, J.H. Schneibel, and E.P. George: Intermetallics, 2012, vol. 21(9), pp. 56–61.

    Article  Google Scholar 

  17. M. Friák, J. Deges, R. Krein, G. Frommeyer, J. Neugebauer: Intermetallics, 2010, vol. 18, pp. 1310–1315.

    Article  Google Scholar 

  18. G. Gottstein, Physical Foundations of Material Science, Springer, Berlin, 2004.

    Book  Google Scholar 

  19. J.M. Rosenberg and H.R. Piehler: Metal. Trans., 1971, vol. 2(1), pp. 257–259.

    Article  Google Scholar 

  20. D.G. Morris and M.A. Munoz-Morris: Mater. Sci. Eng., 2012, vol. A552, pp. 134–144.

    Article  Google Scholar 

  21. W.L. Xu, Y.S. Sun, and S.S. Ding: Acta Metall. Sin. (Engl. Lett.), 2001, vol. 14(4), pp. 248–252.

    Google Scholar 

Download references

Acknowledgments

The paper is based on the research supported by the Grant Agency of the Czech Republic within the Project No. 108/12/1452. The FAVC 1 alloy was supplied by I. Çelikyürek of Eskişehir Osmangazi University in Turkey and by O.Torun of Afyon Kocotepi University in Turkey.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Petr Kratochvíl.

Additional information

Manuscript submitted March 2, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kratochvíl, P., Pešička, J., Král, R. et al. Evaluation of Solid-Solution Hardening of Fe-27 at. pct Al by Vanadium and Comparison to Precipitation Strengthening by Vanadium Carbides. Metall Mater Trans A 46, 5091–5094 (2015). https://doi.org/10.1007/s11661-015-3106-y

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11661-015-3106-y

Keywords

Navigation