Abstracts
Niobium is a widely used micro-alloying element in steels that can retard the austenite-to-ferrite transformation primarily by solute drag when Nb remains in solution. It is critical to develop quantitative models to predict the effect of Nb on the transformation kinetics. In the present work, dedicated continuous cooling transformation (CCT) studies were performed for a low-carbon steel microalloyed with 0.047 wt pct Nb starting from fully recrystallized austenite states with the same grain size but different amounts of Nb in solution. The austenite-to-ferrite transformation kinetics is described from a fundamental perspective by assuming a mixed-mode reaction including solute drag of Nb. Using the solute drag model of Fazeli and Militzer, the intrinsic interface mobility, trans-interface diffusivity of Nb, and its binding energy to the interface have been determined from the CCT data. The interfacial parameters are critically analyzed and compared with independent measurements of diffusion and grain boundary segregation.
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A.J. DeArdo: Int. Mater. Rev., 2003, vol. 48, pp. 371-402.
R.I. Rees, J. Perdrix, T. Maurickx and H.K.D.H. Bhadeshia: Mater. Sci. Eng. A, 1995, vol. 194A, pp. 179-186.
X.Q. Yuan, Z.Y. Liu, S.H. Jiao, L.Q. Ma and G.D. Wang: ISIJ Int., 2006, vol. 46, pp. 579-585.
M.H. Thomas and G.M. Michal: in Solid-Solid Phase Transformations, H.I. Aaronson, D.E. Laughlin, R.F. Sekerka, and C.M. Wayman, eds., TMS-AIME, Warrendale, PA, 1981, pp. 469–73.
M. Suehiro, Z.K. Liu and J. Ågren: Acta Mater., 1996, vol. 44, pp. 4241-4251.
C. Fossaert, G. Rees, T. Maurickx and H.K.D.H. Bhadeshia: Metall. Mater. Trans. A, 1995, vol. 26A, pp. 21-30.
K.J. Lee and J.K. Lee: Scripta Mater., 1999, vol. 40, pp. 831-836.
T. Furuhara, T. Yamaguchi, G. Miyamoto and T. Maki: Mater. Sci. Technol., 2010, vol. 26, pp. 392-397.
G. Purdy, J. Ågren, A. Borgenstam, Y. Bréchet, M. Enomoto, T. Furuhara, E. Gamsjäger, M. Gouné, M. Hillert, C. Hutchinson, M. Militzer, and H. Zurob: Metall. Mater. Trans. A, 2011, vol. 42A, pp. 3703–18.
A. Phillion, H.S. Zurob, C.R. Hutchinson, H. Guo, D.V. Malakhov, J. Nakano and G.R. Purdy: Metall. Mater. Trans. A, 2004, Vol. 35A, pp. 1237-1242.
C.R. Hutchinson, A. Fuchsmann, H.S. Zurob and Y. Bréchet: Scripta Mater., 2004, vol. 50, pp. 285-290.
C.R. Hutchinson, H.S. Zurob and Y. Brechet: Metall. Mater. Trans. A, 2006, vol. 37A, pp. 1711-1720.
H.S. Zurob, D. Panahi, C.R. Hutchinson, Y.J.M. Bréchet and G.R. Purdy: Metall. Mater. Trans. A, 2013, vol. 44A, pp. 3456-3471.
A. Béché, H.S. Zurob and C.R. Hutchinson: Metall. Mater. Trans. A, 2007, vol. 38A, pp. 2950-2955.
C. Qiu, H.S. Zurob, D. Panahi, Y.J.M. Bréchet, G.R. Purdy and C.R. Hutchinson: Metall. Mater. Trans. A, 2013, vol. 44A, pp. 3472-3483.
M. Militzer, M.G. Mecozzi, J. Sietsma and S. van der Zwaag: Acta Mater., 2006, vol.54, pp. 3961-3972.
M.G. Mecozzi, M. Militzer, J. Sietsma, and S. van der Zwaag: Metall. Mater. Trans. A, 2008, vol. 39A, pp. 1237–47.
F. Fazeli and M. Militzer: Metall. Mater. Trans. A, 2005, vol. 36A, pp. 1395-1405.
T. Jia and M. Militzer: ISIJ Int., 2012, vol. 52, pp. 644-649.
E. Gamsjäger, M. Militzer, F. Fazeli, J. Svoboda, F. D. Fischer: Comput. Mater. Sci., 2006, Vol 37, pp. 94-100.
H. Chen, B. Appolaire, S. van der Zwaag: Acta Mater., 2011, vol.59, pp. 6751-6760.
M. Gómez, S.F. Medina and G. Caruana: ISIJ Int., 2003, vol. 43, pp. 1228-1237.
J. Majta, A.K. Zurek, M. Cola, P. Hochanadel and M. Pietrzyk: Metall. Mater. Trans. A, 2002, vol. 33A, pp. 1509-1520.
E. Gamsjäger, J. Svoboda, F.D. Fischer: Comput. Mater. Sci., 2005, vol. 32, pp. 360-369.
E. Gamsjäger, H. Chen, S. van der Zwaag: Comput. Mater. Sci., 2014, vol. 83, pp. 92 - 100.
M.G. Mecozzi, J. Sietsma and S. van der Zwaag: Acta Mater., 2006, vol. 54, pp. 1431-1440.
Y. Takahama and J. Sietsma: ISIJ Int., 2008, vol. 48, pp. 512-517.
G.P. Krielaart and S. van der Zwaag: Mater. Sci. Technol., 1998, vol. 14, pp. 10-18.
H. Strandlund, J. Odqvist and J. Ågren. Comp. Mater. Sci., 2008, vol. 44, pp. 265-273.
S. Gerami: Master’s Thesis, University of British Columbia, Vancouver, 2010.
H. K. D. H. Bhadeshia, S. A. David, J. M. Vitek, R. W. Reed: Mater. Sci. Technol., 1991, vol. 7, pp.686-698.
J.S. Park, Y.S. Ha, S.J. Lee and Y.K. Lee: Metall. Mater. Trans. A., 2009, vol. 40A, pp. 560-568.
M. Militzer, R. Pandi and E.B. Hawbolt: Metall. Mater. Trans. A, 1996, vol. 27A, pp. 1547-1556.
M. Militzer, F. Fazeli and H. Azizi-Alizamini, Metallurgia Italiana, 2011, vol. 103, pp. 35-41.
M. Militzer, F. Fazeli, and T. Jia: Fundamentals and Applications of Mo and Nb Alloying in High Performance Steels: Volume 1, H. Mohrbacher, ed., CBMM/IMOA/TMS, 2014, pp. 23–36.
J. Geise and C. Herzig: Z. Metallk., 1985, vol. 76, pp. 622-626.
C. Herzig, J. Geise, and S.V. Divinski: Z. Metallk., 2002, vol. 93, pp. 1180-1187.
S. Akamatsu, T. Senuma and M. Hasebe: ISIJ Int., 1992, vol. 32, pp. 275-282.
E. Kozeschnik, E. Gamsjäger: Metall. Mater. Trans. A, 2006, vol. 37A, pp. 1791-1797.
N. Maruyama, G.D.W. Smith and A. Cerezo: Mater. Sci. Eng. A, 2003, vol. 353A, pp. 126-132.
C.W. Sinclair, C.R. Hutchinson and Y. Bréchet: Metall. Mater. Trans. A, 2007, vol. 38A, pp. 821-830.
H. Jin, I. Elfimov, and M. Militzer: J. Appl. Phys., 2014, vol. 115, pp. 093506 (8 pp).
Acknowledgments
The authors thank the Natural Sciences and Engineering Research Council (NSERC) of Canada, the National Natural Science Foundation of China (Grant No. 51204048) and the Fundamental Research Funds for the Central Universities (Grant No. N120407008) for financial support. The steel was supplied by Essar Steel Algoma.
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Manuscript submitted March 27, 2014.
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Jia, T., Militzer, M. The Effect of Solute Nb on the Austenite-to-Ferrite Transformation. Metall Mater Trans A 46, 614–621 (2015). https://doi.org/10.1007/s11661-014-2659-5
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DOI: https://doi.org/10.1007/s11661-014-2659-5