Abstract
The technique of solution aerosol thermolysis (SAT) for the production of components suitable for operation of solid oxide fuel cells (SOFC) is reviewed. Major advantages of the technique include its versatility, low cost, and control of the product stoichiometry at droplet level. Progress in understanding the major physicochemical parameters that play a role in final film morphology is emphasized.
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References
Kordesch K, Simader G (1996) Fuel cells and their applications. VCH, Weinheim
Minh NQ (1993) Ceramic fuel cells. J Am Ceram Soc 76:563–588
Bagotsky VS (2009) Fuel cells problems and solutions. Wiley, New Jersey
Minh NQ, Takahashi T (1995) Science and technology of ceramic fuel cells. Elsevier Science, Amsterdam
Supramaniam Srinivasan, (2006) Fuel cells from fundamentals to applications. Springer, Science + Business Media, LLC, New York
Singhal SC, Kendall K (2003) High temperature solid oxide fuel cells: fundamentals, design and applications. Elsevier, UK
Steele BCH (2001) Material science and engineering: the enabling technology for the commercialisation of fuel cell systems. J Mater Sci 36:1053–1068
Aarva A, McPhail SJ, Moreno A (2009) In: Singhal SC, Yokokawa H (Ed), SOFC-XI ECS transactions 25. Issue 2:313–322
Will J, Mitterdorfer A, Kleinlogel C, Perednis D, Gauckler LJ (2000) Fabrication of thin electrolytes for second-generation solid oxide fuel cells. Solid State Ionics 131:79–96
Gelfond NV et al. (2009) Chemical vapor deposition of electrolyte thin films based on yttria-stabilized zirconia. Inorg Mater 45:659–665
Shim JH, Chao C-C, Huang H, Prinz FB (2007) Atomic layer deposition of Yttria stabilized zirconia for solid oxide fuel cells. Chem Mater 19:3850–3854
Johnson RW, Hultqvist A, Bent SF (2014) A brief review of atomic layer deposition: from fundamentals to applications. Materials today 17:236–246
Courtin E et al. (2012) Optimized sol–gel routes to synthesize yttria-stabilized zirconia thin films as solid electrolytes for solid oxide fuel cells. Chem Mater 24:4540–4548
Choi J-J et al. (2011) Preparation and characterization of (La0.8Sr0.2)0.95MnO3−δ (LSM) thin films and LSM/LSCF interface for solid oxide fuel cells. J Am Ceram Soc 94:3340–3345
Papastergiades E, Argyropoulos S, Rigakis N, Kiratzis NE (2009) Fabrication of ceramic electrolytic films by the method of solution aerosol thermolysis (SAT) for solid oxide fuel cells (SOFC). Ionics 15:545–554
Huang H et al. (2007) High-performance ultrathin solid oxide fuel cells for low temperature operation. J Electrochem Soc 154:B20–B24
Kuo Y-L, Chen Y-S, Lee C (2011) Growth of 20 mol% Gd-doped ceria thin films by RF reactive sputtering: the O2/Ar flow ratio effect. J Eur Ceram Soc 31:3127–3135
Nédélec R et al. (2012) Dense yttria-stabilised zirconia electrolyte layers for SOFC by reactive magnetron sputtering. J Power Sources 205:157–163
Hidalgo H et al. (2013) Optimization of DC reactive magnetron sputtering deposition process for efficient YSZ electrolyte thin film SOFC. Fuel cells 13:279–288
Heiroth S et al. (2010) Yttria-stabilized zirconia thin films by pulsed laser deposition: microstructural and compositional control. J Eur Ceram Soc 30:489–495
Rodrigo K et al. (2007) Characterization of yttria-stabilized zirconia thin films grown by pulsed laser deposition (PLD) on various substrates. Appl Surf Sci 254:1338–1342
Otani M et al. (2010) Fabrication of Gd0.5Sr0.5CoO3 film for SOFC cathode by pulsed laser deposition. Solid State Ionics 180:1667–1671
S. C et al. (2011) High power density thin film SOFCs with YSZ/GDC bilayer electrolyte. Electrochim Acta 56:5472–5477
Coddet P, Liao H, Coddet C (2014) A review on high power SOFC electrolyte layer manufacturing using thermal spray and physical vapour deposition technologies. Adv Manuf 2:212–221
Tikkanen H et al. (2011) Examination of the co-sintering process of thin 8YSZ films obtained by dip-coating on in-house produced NiO–YSZ. J Eur Ceram Soc 31:1733–1739
Hanifi AR et al. (2012) Development of monolithic YSZ porous and dense layers through multiple slip casting for ceramic fuel cell applications. Int J Appl Ceram Technol 9:1011–1021
Zhitomirsky I, Petric A (2000) Electrophoretic deposition of ceramic materials for fuel cell applications. J Eur Ceram Soc 20:2055–2061
Zou Y et al. (2011) Electrophoretic deposition of YSZ thin-film electrolyte for SOFCs utilizing electrostatic-steric stabilized suspensions obtained via high energy ball milling. Int J Hydrog Energy 36:9195–9204
Das D, Basu RN (2014) Electrophoretic deposition of zirconia thin film on nonconducting substrate for solid oxide fuel cell application. J Am Ceram Soc 97:3452–3457
Schoonman J (2000) Nanostructured materials in solid state ionics. Solid State Ionics 135:5–19
Lee S, Son T, Yun J, Kwon H, Messing GL, Jun B (2004) Preparation of BaTiO3 nanoparticles by combustion spray pyrolysis. Mater Lett 58:2932–2936
Messing GL, Zhang S-C, Jayanthi GV (1993) Ceramic powder synthesis by spray pyrolysis. J Am Ceram Soc 76(11):2707–2726
Viguìé JC, Spitz J (1975) Chemical vapor deposition at low temperatures. J Electrochem Soc 122:585–588
Chamberlin RR, Skarman JS (1966) Chemical spray deposition process for inorganic films. J Electrochem Soc 113:86–89
Hunt AT, Carter WB, Cochran JK Jr (1993) Combustion chemical vapor deposition: a novel thin-film deposition technique. Appl Phys Lett 63:266–268
Choy KL, Charojrochkul S, Steele BCH (1997) Fabrication of cathode for solid oxide fuel cells using flame assisted vapour deposition technique. Solid State Ionics 96:49–54
Jayanthi GV, Zhang SC, Messing GL (1993) Modeling of solid particle formation during solution aerosol thermolysis. Aerosol Sci Technol 19:478–490
Chopra KL, Kainthla RC, Pandya DK, and Thakoor AP (1982) Physics of thin films. In: Hass G, Francombe MH, Vossen JL (eds) Chemical solution deposition of inorganic films academic press Inc, New York, Vol.12 pp 168–172
Beckel D, Dubach A, Studart AR, Gauckler LJ (2006) Spray pyrolysis of La0.6Sr0.4Co0.2Fe0.8O3-δ thin film cathodes. J Electroceram 16:221–228
Vasu V, Subrahmanyam A (1990) Reaction kinetics of the formation of indium tin oxide films grown by spray pyrolysis. Thin Solid Films 193(194):696–703
Arya SPS, Hintermann HE (1990) Growth of Y–Ba–Cu–O superconducting thin films by ultrasonic spray pyrolysis. Thin Solid Films 193(194):841–846
van Zomeren AA, Kelder EM, Marijnissen JCM, Schoonman J (1994) The production of thin films of LiMn2O4 by electrospraying. J Aerosol Sci 25(6):1229–1235
Chen CH, Buysman AAJ, Kelder EM, Schoonman J (1995) Fabrication of LiCoO2 thin film cathodes for rechargeable lithium battery by electrostatic spray pyrolysis. Solid State Ionics 80:1–4
Chen CH, Yuan FL, Schoonman J (1998) Spray pyrolysis routes to electroceramic powders and thin films. Eur J Solid State Inorg Chem 35:189–196
Taniguchi I, van Landschoot RC, Schoonman J (2003) Fabrication of La1–xSrxCo1–yFeyO3 thin films by electrostatic spray deposition. Solid State Ionics 156:1–13
Taniguchi I, van Landschoot RC, Schoonman J (2003) Electrostatic spray deposition of Gd0.1Ce0.9O1.95 and La0.9Sr0.1Ga0.8Mg0.2O2.87 thin films. Solid State Ionics 160:271–279
Lampkin CM (1979) Aerodynamics of nozzles used in spray pyrolysis. Prog Crystal Growth Charact 1:405–416
See references [25, 27] as taken from Chopra KL, Kainthla RC, Pandya DK, and Thakoor AP (1982) Physics of thin films. In: Hass G, Francombe MH, Vossen JL (eds) Chemical solution deposition of inorganic films academic press Inc, New York, Vol.12 pp 168–232
Chopra KL, Kainthla RC, Pandya DK, and Thakoor AP (1982) In: Hass G, Francombe MH, Vossen JL (eds) Physics of thin films, academic press Inc, New York, Vol.12 pp 178–192
Muecke UP, Messing GL, Gauckler LJ (2009) The Leidenfrost effect during spray pyrolysis of nickel oxide-gadolinia doped ceria composite thin films. Thin Solid Films 517:1515–1521
Choy KL (1995) Fabrication of ceramic coatings using flame assisted vapour deposition. In: Lee WE (ed) Brit. Ceram. Proc. No.54, The Institute of Materials, London, pp 65–74
Charojrochkul S, Choy KL, Steele BCH (2004) Flame assisted vapour deposition of cathode for solid oxide fuel cells. 1. Microstructure control from processing parameters. J Eur Ceram Soc 24:2515–2526
Perednis D, Wilhelm O, Pratsinis SE, Gauckler LJ (2005) Morphology and deposition of thin yttria-stabilized zirconia films using spray pyrolysis. Thin Solid Films 474:84–95
Perednis D, Gauckler LJ (2004) Solid oxide fuel cells with electrolytes prepared via spray pyrolysis. Solid State Ionics 166:229–239
Choy K, Bai W, Charojrochkul S, Steele BCH (1998) The development of intermediate-temperature solid oxide fuel cells for the next millennium. J Power Sources 71:361–369
Perednis D, Gauckler LJ (2005) Thin film deposition using spray pyrolysis. J Electroceram 14:103–111
Chen C, Kelder EM, Schoonman J (1998) Effects of additives in electrospraying for materials preparation. J Eur Ceram Soc 18(10):1439–1443
Kim S, Choi JH, Eun HJ, Kim HJ, Hwang CS (2000) Effects of additives on properties of MgO thin films by electrostatic spray deposition. Thin Solid Films 377:694–698
Aranovich J, Ortiz A, Bube RH (1979) Optical and electrical properties of ZnO films prepared by spray pyrolysis for solar cell applications. J Vac Sci Technol 16:994–1003
Chopra KL, Kainthla RC, Pandya DK, Thakoor AP (1982) In: Hass G, Francombe MH, Vossen JL (eds) Physics of thin films, academic press Inc, New York. Vol. 12:178–181
Hamedani HA et al. (2008) Fabrication of gradient porous LSM cathode by optimizing deposition parameters in ultrasonic spray pyrolysis. Mater Sci Eng B 153:1–9
Sears WM, Gee MA (1988) Mechanics of film formation during the spray pyrolysis of tin oxide. Thin Solid Films 165:265–277
Choy KL, Su B (2001) Growth behavior and microstructure of CdS thin films deposited by an electrostatic spray assisted vapor deposition (ESAVD) process. Thin Solid Films 388:9–14
Wiedmann I, Choy K-L and Derby B (1994) Flame-assisted deposition of lead titanate-based thin films: correlation of deposition process, microstructure and electrical properties. In: Brit. Ceram. Proc. No.53, The Institute of Materials, London, pp 133–141
Vasu V, Subrahmanyam A (1990) Electrical and optical properties of sprayed SnO2 films: dependence on the oxiding agent in the starting material. Thin Solid Films 193(194):973–980
Leong KH (1987) Morphological control of particles generated from the evaporation of solution droplets: theoretical considerations. J Aerosol Sci 18:511–524
Leong KH (1987) Morphological control of particles generated from the evaporation of solution droplets: experiment. J Aerosol Sci 18:525–552
Nesic S, Vodnic J (1991) Kinetics of droplet evaporation. Chem Eng Sci 46:527–537
Scherer GW (1992) Crack-tip stress in gels. J Non-Cryst Solids 144:210–216
See reference [47] of the review by Messing et al. [32]
Fukui T, Oobuchi T, Ikuhara Y, Ohara S, Kodera K (1997) Synthesis of (La,Sr)MnO3–YSZ composite particles by spray pyrolysis. J Am Ceram Soc 80:261–263
Heel A, Vital A, Holtappels P, Graule T (2009) Flame spray synthesis and characterisation of stabilised ZrO2 and CeO2 electrolyte nanopowders for SOFC applications at intermediate temperatures. J Electroceram 22:40–46
Barringer EA, HK B (1982) Formation, packing, and sintering of monodisperse TiO2 powders. J. Am. Ceram. Soc 65:C-199–C-201
Tian Y-L, Dewan HS, Brodwin ME and Johnson DL (1990) MICROWAVE SINTERING BEHAVIOR OF ALUMINA CERAMICS. In Handwerker C, Blendell J and Kaysser W (eds) Ceramic transactions, American ceramic society, Vol. 7 pp 391–401
Slamovich EB and Lange FF (1988) Spherical zirconia particles via electrostatic atomization: fabrication and sintering characteristics. In Brinker CJ et al (eds) Materials research society symposium proceedings, better ceramics through chemistry III, Materials Research Society, Vol. 121 pp 257–262
Niesen TP, Guire MRDE (2002) Review : deposition of ceramic thin films at low temperatures from aqueous solutions. Solid State Ionics 151:61–68
Setoguchi T, Sawano M, Eguchi K, Arai H (1990) Application of the stabilized zirconia thin film prepared by spray pyrolysis method to SOFC. Solid State Ionics 40(41):502–505
Kelder EM, Nijs OCJ, Schoonman J (1994) Low-temperature synthesis of thin films of YSZ and BaCeO3using electrostatic spray pyrolysis (ESP). Solid State Ionics 68:5–7
Stelzer NHJ, Schoonman J (1996) Synthesis of terbia-doped Yttria-stabilized zirconia thin films by electrostatic spray deposition (ESD) J. Mater Synth Process 4(6):429–438
Jadhav LD et al. (2012) Synthesis and characterization of YSZ by spray pyrolysis technique. Appl Surf Sci 258:9501–9504
Halmenschlager CM et al. (2013) Influence of the process parameters on the spray pyrolysis technique, on the synthesis of gadolinium doped-ceria thin film. Mater Res Bull 48:207–213
Reolon RP et al. (2014) Electrochemical performance of gadolinia-doped ceria (CGO) electrolyte thin films for ITSOFC deposited by spray pyrolysis. J. Power Sour 261:348–355
Chourashiya MG, Jadhav LD (2011) Synthesis and characterization of 10%Gd doped ceria (GDC) deposited on NiO-GDC anode-grade-ceramic substrate as half cell for IT-SOFC. Int. J. Hydrogen energy 36:14984–14995
Van Gestel T, Sebold D, Buchkremer HP (2015) Processing of 8YSZ and CGO thin film electrolyte layers for intermediate- and low-temperature SOFCs. J Eur Ceram Soc 35:1505–1515
Rupp JLM, Drobek T, Rossi A, Gauckler LJ (2007) Chemical analysis of spray pyrolysis Gadolinia-doped ceria electrolyte thin films for solid oxide fuel cells. Chem Mater 19:1134–1142
Scherrer B et al. (2012) Microstructures of YSZ and CGO thin films deposited by spray pyrolysis: influence of processing parameters on the porosity. Adv Funct Mater 22:3509–3518
Tsoga A, Naoumidis A, Stöver D (2000) Total electrical conductivity and defect structure of ZrO2–CeO2–Y2O3–Gd2O3 solid solutions. Solid State Ionics 135:403–409
Murray EP, Sever MJ, Barnett SA (2002) Electrochemical performance of (La,Sr)(Co,Fe)O3–(Ce,Gd)O3 composite cathodes. Solid State Ionics 148:27–34
Marina OA, Bagger C, Primdahl S, Mogensen M (1999) A solid oxide fuel cell with a gadolinia-doped ceria anode: preparation and performance. Solid State Ionics 123:199–208
Ruiz-Morales JC et al. (2007) LSCM–(YSZ–CGO) composites as improved symmetrical electrodes for solid oxide fuel cells. J Eur Ceram Soc 27:4223–4227
Stoermer AO, Rupp JLM, Gauckler LJ (2006) Spray pyrolysis of electrolyte interlayers for vacuum plasma-sprayed SOFC. Solid State Ionics 177:2075–2079
Sahibzada M et al. (1996) Investigations on intermediate temperature (500–650 °C) PEN structures incorporating Ce(Gd)O2-x electrolytes. In: Thorsensen B (ed) Proceedings of the 2nd European solid oxide fuel cell forum. European Solid Oxide Fuel Cell Forum, Switzerland, pp. 687–696
Beckel D et al. (2007) Electrochemical performance of LSCF based thin film cathodes prepared by spray pyrolysis. Solid State Ionics 178:407–415
Marrero-López D et al. (2014) Effect of the deposition temperature on the electrochemical properties of La0.6Sr0.4Co0.8Fe0.2O3–δ cathode prepared by conventional spray-pyrolysis. J Power Sources 255:308–317
Hsu CS, Hwang BH (2006) Microstructure and properties of the La0.6Sr0.4Co0.2Fe0.8O3 cathodes prepared by electrostatic-assisted ultrasonic spray pyrolysis method. J Electrochem Soc 153:A1478
Chang C-L, Hsu C-S, Hwang B-H (2008) Unique porous thick Sm0.5Sr0.5CoO3 solid oxide fuel cell cathode films prepared by spray pyrolysis. J Power Sources 179:734–738
Marrero-López D et al. (2014) Stability and performance of nanostructured La0.8Sr0.2MnO3 cathodes deposited by spray-pyrolysis. Electrochim Acta 134:159–166
Angoua BF, Slamovich EB (2012) Single solution spray pyrolysis of La0.6Sr0.4Co0.2Fe0.8O3–δ–Ce0.8Gd0.2O1.9 (LSCF–CGO) thin film cathodes. Solid State Ionics 212:10–17
Angoua BF et al., (2011) Crystallization and electrochemical performance of La0.6Sr0.4Co0.2Fe0.8O3– δ–Ce0.8Gd0.2O1.9 thin film cathodes processed by single solution spray pyrolysis. Solid State Ionics doi:10.1016/j.ssi.2011.08.017
Silva PLB et al. (2015) Low temperature synthesis by spray pyrolysis of La0.9Sr0.1Co0.2Fe0.8O3 thin films using ethanol and water as a solvent and their microstructural characterization. Ceramics International 41:13304–13309
Fukui T, Ohara S, Naito M, Nogi K (2003) Synthesis of NiO–YSZ composite particles for an electrode of solid oxide fuel cells by spray pyrolysis. Powder Technol 132:52–56
Hwang B-H et al. (2007) Electrostatic spray deposition of NiO/CGO films. J Phys D Appl Phys 40:3448–3455
Chen J-C et al. (2007) Deposition of Ni-CGO composite anodes by electrostatic assisted ultrasonic spray pyrolysis method. Mater Res Bull 42:1674–1682
Chen J-H, Hwang B-H (2008) Microstructure and properties of the Ni-CGO composite anodes prepared by the electrostatic-assisted ultrasonic spray pyrolysis method. J Am Ceram Soc 91:97–102
Liu L, Kim G-Y, Chandra A (2010) Fabrication of solid oxide fuel cell anode electrode by spray pyrolysis. J Power Sources 195:7046–7053
Liu L et al. (2011) Microstructural and electrochemical impedance study of nickel Ce0.9Gd0.1O1.95 anodes for solid oxide fuel cells fabricated by ultrasonic spray pyrolysis. J Power Sources 196:3026–3032
Liu L et al. (2012) Modeling of Ni–CGO anode in a solid oxide fuel cell deposited by spray pyrolysis. J Power Sources 210:129–137
Acknowledgments
The author thanks the European Union (European Social Fund ESF) and Greek National funds through the Operational Program “Education and Lifelong Learning” of the National Strategic Reference Framework (NSRF) Research Funding Program: ARCHIMEDES III. Investing in knowledge society through the European Social Fund. The help of G. Tsimekas (PhD candidate at the Department of Chemistry, University of St. Andrews) with literature search is also appreciated.
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Kiratzis, N.E. Applications of the technique of solution aerosol thermolysis (SAT) in solid oxide fuel cell (SOFC) component fabrication. Ionics 22, 751–770 (2016). https://doi.org/10.1007/s11581-016-1704-3
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DOI: https://doi.org/10.1007/s11581-016-1704-3