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Glass fiber fabric mat as the separator for lithium-ion battery with high safety performance

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Abstract

Separator plays an important role in the safety performance of lithium-ion battery since many accidents have been caused by internal shorting of battery due to the failure of the separators. Herein, thermal stable and flexible glass fiber fabric was reported to be a promising candidate for separators with high safety. The thermal stability, mechanical, and electrochemical performance of the glass fiber fabrics were studied and compared with traditional commercialized separators in details. Our results show that the glass fiber fabrics can be a successful separator for lithium-ion battery with high safety performance due to its greatly improved thermal stability, high mechanical strength, and matched electrochemical performance.

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References

  1. Wu H, Zhuo D, Kong DS, Cui Y (2014) Improving battery safety by early detection of internal shorting with a bifunctional separator. Nat Commun 5:5193–5198

    Article  CAS  Google Scholar 

  2. Doughty D, Roth EP (2012) A general discussion of Li ion battery safety. J Electrochem Soc 20:37–44

    Google Scholar 

  3. Zhang JQ, Sun B, Huang XD, Chen SQ, Wang GX (2014) Honeycomb-like porous gel polymer electrolyte membrane for lithium ion batteries with enhanced safety. Scientific Rep 4:6007–6013

    Article  CAS  Google Scholar 

  4. Hassoun J, Panero S, Reale P, Scrosati B (2009) A new, safe, high-rate and high-energy polymer lithium-ion battery. Adv Mater 21:4807–4810

    Article  CAS  Google Scholar 

  5. Wang QS, Ping P, Zhao XJ, Chu GQ, Sun JH, Chen CH (2012) Thermal runaway caused fire and explosion of lithium ion battery. J Power Sources 208:210–224

    Article  CAS  Google Scholar 

  6. Orendorff CJ (2012) The role of separators in lithium-ion cell safety. J Electrochem Soc 20:61–65

    Google Scholar 

  7. Huang XS (2011) Separator technologies for lithium-ion batteries. J Solid State Electrochem 15:649–662

    Article  CAS  Google Scholar 

  8. Lee H, Yanilmaz M, Toprakci O, Fu K, Zhang XW (2014) A review of recent developments in membrane separators for rechargeable lithium-ion batteries. Energy Environ Sci 7:3857–3886

    Article  CAS  Google Scholar 

  9. Zhang SS (2007) A review on the separators of liquid electrolyte Li-ion batteries. J Power Sources 164:351–364

    Article  CAS  Google Scholar 

  10. Yang M, Hou JB (2012) Membranes in lithium ion batteries. Membranes 2:367–383

    Article  CAS  Google Scholar 

  11. Fu D, Luan B, Argue S, Bureau MN, Davidson IJ (2012) Nano SiO2 particle formation and deposition on polypropylene separators for lithium-ion batteries. J Power Sources 206:325–333

    Article  CAS  Google Scholar 

  12. Chen JC, Sun T, Qi Y, Li XD (2014) A coupled penetration-tension method for evaluating the reliability of battery separators. ECS ELECTROCHEM LETT 3:A41–A44

    Article  CAS  Google Scholar 

  13. Huang XS (2014) Performance evaluation of a non-woven lithium ion battery separator prepared through a paper-making process. J Power Sources 256:96–101

    Article  CAS  Google Scholar 

  14. Jeong HS, Noh JH, Hwang CG, Kim SH, Lee SY (2010) Effect of solvent–nonsolvent miscibility on morphology and electrochemical performance of SiO2/PVdF-HFP-based composite separator membranes for safer lithium-ion batteries. Macromol Chem Phys 211:420–425

    Article  CAS  Google Scholar 

  15. Kim M, Park JH (2012) Inorganic thin layer coated porous separator with high thermal stability for safety reinforced Li-ion battery. J Power Sources 212:22–27

    Article  CAS  Google Scholar 

  16. Jiang W, Liu ZH, Kong QS, Yao JH, Zhang CJ, Han PX, Cui GL (2013) A high temperature operating nanofibrous polyimide separator in Li-ion battery. Solid State Ionics 232:44–48

    Article  CAS  Google Scholar 

  17. Lee JR, Won JH, Kim JH, Kim KJ, Lee SY (2012) Evaporation-induced self-assembled silica colloidal particle-assisted nanoporous structural evolution of poly(ethylene terephthalate) nonwoven composite separators for high-safety/high-rate lithium-ion batteries. J Power Sources 216:42–47

    Article  CAS  Google Scholar 

  18. Kang SM, Ryou MH, Choi JW, Lee H (2012) Mussel- and Diatom-inspired silica coating on aeparators yields improved power and safety in Li-ion batteries. Chem Mater 24:3481–3485

    Article  CAS  Google Scholar 

  19. Choi JA, Kim SH, Kim DW (2010) Enhancement of thermal stability and cycling performance in lithium-ion cells through the use of ceramic-coated separators. J Power Sources 195:6192–6196

    Article  CAS  Google Scholar 

  20. Song JC, Ryou MH, Son B, Lee JN, Lee DJ, Lee YM, Choi JW, Park JK (2012) Co-polyimide-coated polyethylene separators for enhanced thermal stability of lithium ion batteries. Electrochimica Acta 85:524–530

    Article  CAS  Google Scholar 

  21. Ryou MH, Lee YM, Park JK, Choi JW (2011) Mussel-inspired polydopamine-treated polyethylene separators for High-power Li-ion batteries. Adv Mater 23:3066–3070

    Article  CAS  Google Scholar 

  22. He MN, Zhang XJ, Jiang KY, Wang J, Wang Y (2015) Pure inorganic separator for lithium ion batteries. ACS Appl Mater Interfaces 7:738–742

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Basic Research of China (Grant Nos. 2015CB932500 and 2013CB632702) and NSF of China (Grant No. 51302141). H. W. acknowledges the support from the 1000 Youth Talents Plan of China.

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Correspondence to Hui Wu.

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Luo, X., Pan, W., Liu, H. et al. Glass fiber fabric mat as the separator for lithium-ion battery with high safety performance. Ionics 21, 3135–3139 (2015). https://doi.org/10.1007/s11581-015-1540-x

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  • DOI: https://doi.org/10.1007/s11581-015-1540-x

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