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Derivative of iota-carrageenan as solid polymer electrolyte

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Abstract

A new type of solid polymer electrolyte based on iota (ɩ)-carrageenan derivative has been investigated. ɩ-Carrageenan was reacted with monochloroacetic acid to produce carboxymethyl ɩ-carrageenan. The produced powders were characterized by 1H nuclear magnetic resonance and attenuated total reflection Fourier transform infrared spectroscopy to confirm the substitution of targeted functional in ɩ-carrageenan. The polymer electrolytes films were prepared by solution casting technique. Thermal gravimetric analysis result shows that the modified powder and film were stable up to 300 °C. X-ray diffraction analysis shows that the chemical modification of ɩ-carrageenan increases the amorphous phase of polymer electrolyte film. Meanwhile, the scanning electron microscope observation reveals that the carboxymethyl ɩ-carrageenan film becomes smoother than ɩ-carrageenan film which supports the ionic conductivity enhancement. The ionic conductivity of ɩ-carrageenan film increases from 2.19 × 10−8 to 4.87 × 10−6 S cm−1 after chemical modification of ɩ-carrageenan to carboxymethyl ɩ-carrageenan.

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Acknowledgments

The authors would like to thank UKM and Fisheries Department for the provision of grants UKM-DLP-2012-021 and STGL-007-2010, respectively.

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Authors and Affiliations

  1. School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600, Bangi, Selangor Darul Ehsan, Malaysia

    F. N. Jumaah, N.N. Mobarak, A. Ahmad & M.A. Ghani

  2. Institute of Microengineering and Nanoelectronics, Universiti Kebangsaan Malaysia, 43600, Bangi, Selangor Darul Ehsan, Malaysia

    M. Y. A. Rahman

Authors
  1. F. N. Jumaah
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  2. N.N. Mobarak
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  3. A. Ahmad
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  4. M.A. Ghani
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Correspondence to A. Ahmad or M. Y. A. Rahman.

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Jumaah, F.N., Mobarak, N., Ahmad, A. et al. Derivative of iota-carrageenan as solid polymer electrolyte. Ionics 21, 1311–1320 (2015). https://doi.org/10.1007/s11581-014-1306-x

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  • DOI: https://doi.org/10.1007/s11581-014-1306-x

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