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Influence of physico-chemical components on the consolidation behavior of soft kaolinites

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Abstract

Pore solution salinity has important bearing on engineering behavior of marine sediments as they influence electrochemical stress (AR) and differential osmotic stress (∆π) of the salt-enriched clays. The electrochemical stress (AR) is contributed by van der Waals (A) attraction and diffuse ion layer repulsion (R) , while the differential osmotic stress (∆π) is governed by the differences in dissolved salt concentrations in solutions separated by osmotic membrane. The paper examines the relative influence of differential osmotic stress (Δπ) and electrochemical stress (AR) on the consolidation behavior of slurry consolidated kaolinite specimens, which are known to be encountered in recent alluvial marine sediments. Methods are described to evaluate the magnitudes of these physico-chemical components and their incorporation in true effective stress. Results of the study demonstrate that differential osmotic stress finitely contributes to true effective stress. The contribution from differential osmotic stress enables kaolinite specimens to sustain larger void ratio during consolidation.

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References

  1. Andersson-Sköld Y, Torrance JK, Lind B, Odèn K, Stevens RL, Rankka K (2005) Quick clay—a case study of chemical perspective in southwest Sweden. Eng Geol 82:107–118

    Article  Google Scholar 

  2. Appelo CAJ, Postma D (1994) Geochemistry, ground water and pollution. CRC Press, Boca Raton

    Google Scholar 

  3. ASTM (2007a) Standard test method for particle-size analysis of soils. ASTM standard D422. American Society of Testing Materials (ASTM), Philadelphia PA

  4. ASTM (2007b) Standard test method for pore water extraction and determination of the soluble salt content of soils by refractometer. ASTM standard D4542. American Society of Testing Materials (ASTM), Philadelphia PA

  5. ASTM (2010) Standard test methods for liquid limit, plastic limit, and plasticity index of soils. ASTM standard D4318. American Society of Testing Materials (ASTM), Philadelphia PA

  6. ASTM (2013) Standard practice for the preparation of substitute ocean water. ASTM standard D1141. American Society of Testing Materials (ASTM), Philadelphia PA

  7. ASTM (2013) Standard test method for pH of soils. ASTM standard D4972. American Society of Testing Materials (ASTM), Philadelphia PA

  8. ASTM (2014) Standard test methods for specific gravity of soil solids by water pycnometer. ASTM standard D854. American Society of Testing Materials (ASTM), Philadelphia PA

  9. Barbour SL, Fredlund DG (1989) Mechanics of osmotic flow and volume change in clay soils. Can Geotech J 26:551–562

    Article  Google Scholar 

  10. Bjerrum L, Loken T, Heiberg S, Foster R (1969) A field study of factors responsible for quick clay slides. In: Proceedings of the 7th international conference on soil mechanics and foundation engineering, Mexico City, 2:531–540

  11. Budhu M (2007) Soil mechanics and foundations. Wiley, New York

    Google Scholar 

  12. Carretero S, Rapaglia J, Bokuniewicz H, Kruse E (2013) Impact of sea-level rise on salt water intrusion length into the coastal aquifer, Partido de La Costa, Argentina. Cont Shelf Res 61–62:62–70

    Article  Google Scholar 

  13. Maio Di (1996) Exposure of bentonite to salt solution: osmotic and mechanical effects. Geotechnique 46:695–707

    Article  Google Scholar 

  14. Eilertsen SR, Hansen L, Bargel HT, Solberg I-L (2008) Clay slides in the Malselv valley, northern Norway: characteristics, occurrence, and triggering mechanism. Geomorph 93:548–562

    Article  Google Scholar 

  15. Fredlund DG, Rahardjo H, Fredlund MD (2012) Unsaturated soil mechanics in engineering practice. Wiley, NY

    Book  Google Scholar 

  16. Fritz SJ (1986) Ideality of clay membranes in osmotic process: a review. Clay Clay Miner 34:214–223

    Article  Google Scholar 

  17. Fritz SJ, Marine IW (1983) Experimental support for a predictive osmotic model of clay membranes. Geochim Cosmochim Ac 47:1515–1522

    Article  Google Scholar 

  18. Gadd NR (1962) Surficial geology of the Ottawa area. Geological Survey of Canada, paper 62-16

  19. Gylland A, Long M, Emdal A, Sandven R (2013) Characterisation and engineering properties of Tiller clay. Eng Geol 164:86–100

    Article  Google Scholar 

  20. Karnlan O (1997) Bentonite swelling pressure in strong NaCl solutions. Correlations between model calculations and experimental data. SKB technical report 97-31

  21. Keijzer ThJS (2000) Chemical osmosis in natural clayey materials. Geologica Ultraiectina 196. Ph. D. thesis, Utrecht University

  22. Kerr PF (1979) Quick clay and other slide forming clays. Eng Geol 14:173–181

    Article  Google Scholar 

  23. Kharaka YK, Berry FAF (1973) Simultaneous flows of water and solutes through geological membranes: I. Experimental INVESTIGATION. Geochim Cosmochim Ac 37:2577–2603

    Article  Google Scholar 

  24. Marcus Y (1997) Ion properties. Marcel Dekker, New York

    Google Scholar 

  25. Marine IW, Fritz SJ (1981) Osmotic model to explain anomalous hydraulic heads. Water Resour Res 17:73–82

    Article  Google Scholar 

  26. Melloul AJ, Goldenberg LC (1997) Monitoring of Seawater intrusion in coastal aquifers: basics and local concerns. J Environ Manag 51:73–86

    Article  Google Scholar 

  27. Mitchell JK, Soga K (2005) Fundamentals of soil behavior, 3rd edn. Wiley, Hoboken

    Google Scholar 

  28. Ohtsubo M, Higashi T, Kanayama M (2007) Depositional geochemistry and geotechnical properties of marine clays in the Ariake bay area Japan. In: Tan TS et al (eds) Characterisation and engineering properties of natural soils, vol 3. Talor & Francis, Milton Park, pp 1893–1938

    Google Scholar 

  29. Pulido-Leboeuf P (2004) Seawater intrusion and associated processes in a small coastal complex aquifer (Castell de Ferro, Spain). Appl Geochem 19:1517–1527

    Article  Google Scholar 

  30. Rao SM, Shivananda P (2005) Role of curing temperature in progress of lime-soil reactions. Geot Geol Eng 23:79–85

    Article  Google Scholar 

  31. Rao SM, Sridharan A (1985) Mechanisms controlling volume change behaviour of kaolinite. Clay Clay miner 34:323–328

    Article  Google Scholar 

  32. Rao SM, Thyagaraj T (2007) Swell compression behavior of compacted clays under chemical gradients. Can Geotech J 44(5):520–532

    Article  Google Scholar 

  33. Rao SM, Thyagaraj T, Thomas HR (2006) Swelling of compacted clay under osmotic gradients. Geotechnique 56(10):707–713

    Article  Google Scholar 

  34. Ryan PC (2014) Cation exchange capacity of tropical soil clays as a function of time and precipitation. 2014 GSA annual meeting, Vancouver, British Columbia

  35. Solberg I-L (2003) Geological development and stability along the Mortenelva river in the Malselv valley, Troms. Diploma thesis, Department of Geology and Mineral Resources Engineering, Faculty of Engineering Science and Technology, NTNU, Trondheim (in Norwegian)

  36. Sridharan A, Rao SM, Murthy NS (1985) Free swell index of soils: a need for re-definition. Indian Geotech J 15:94–95

    Google Scholar 

  37. Sumner ME, Miller WP (1996) Cation exchange capacity, and exchange coefficients. In: Sparks DL (ed) Methods of soil analysis. Part 2: chemical properties (3rd edn). ASA, SSSA, CSSA, Madison, WI

  38. Thyagaraj T, Rao SM (2013) Osmotic swelling and osmotic consolidation behavior of compacted expansive clay. Geotech Geol Eng 31:435–445

    Article  Google Scholar 

  39. Van Olphen H (1963) Clay colloid chemistry. Wiley, London

    Google Scholar 

  40. Yong RN, Warkentin BP (1975) Soil properties and behavior. Elsevier, Amsterdam

    Google Scholar 

  41. Zghibi A, Tarhouni J, Zouhri L (2013) Assessment of sea water intrusion and nitrate contamination on the ground water quality in the Korba costal plain of Cap-Bon, North- east of Tunisia. J Afr Earth Sci 87:1–12

    Article  Google Scholar 

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Correspondence to Sudhakar Rao.

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Rao, S., Deepak, G.B., Raghuveer Rao, P. et al. Influence of physico-chemical components on the consolidation behavior of soft kaolinites. Acta Geotech. 12, 441–451 (2017). https://doi.org/10.1007/s11440-016-0478-0

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  • DOI: https://doi.org/10.1007/s11440-016-0478-0

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