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The dual role of hydrogen peroxide in fuel cells

  • Review
  • Engineering Sciences
  • Published:
Science Bulletin

Abstract

Clean and highly efficient energy production has long been sought after, as a way to solve global energy and environmental problems. Fuel cells, which convert the chemical energy stored in fuel directly into electricity, are expected to be a key enabling technology for the pressing energy issues that plague our planet. Fuel cells require oxygen as an oxidant and require oxygen tank containers when used in air-free environments such as outer space and underwater. Hydrogen peroxide has been extensively utilized as an alternative liquid oxidant in place of gaseous oxygen. In addition to being an oxidant, hydrogen peroxide can donate electrons in the oxidation reaction to act as a fuel. This article provides an overview of the dual role of hydrogen peroxide in fuel-cell applications, including working principle, system design, and cell performance. Recent innovations and future perspectives of fuel cells that use hydrogen peroxide are particularly emphasized.

摘要

发展新的能源技术是解决全球能源与环境问题的关键. 作为新一代能源转换技术, 燃料电池可将燃料中的化学能直接转换为电能, 它是一种高效、清洁的能源转换系统, 必将在未来得到广泛应用. 燃料电池需要氧气作为氧化剂, 为此在诸如太空、水下等无氧环境中, 电池系统需要携带高压氧气储存系统. 因此, 常压下液态过氧化氢已经被广泛地应用在燃料电池中代替气态氧作为氧化剂. 另外, 过氧化氢还可以在燃料电池中通过氧化反应释放电子, 从而可以作为燃料. 本文着重介绍了过氧化氢燃料电池的最新进展, 包括工作原理、系统设计、及电池性能, 并展望了今后的研究方向

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Acknowledgments

This work was fully supported by a grant from the Research Grants Council of the Hong Kong Special Administrative Region, China (HKUST9/CRF/11G).

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The authors declare that they have no conflict of interest.

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Authors and Affiliations

  1. Department of Mechanical and Aerospace Engineering, The Hong Kong University of Science and Technology, Hong Kong, China

    Liang An, Tianshou Zhao, Xiaohui Yan, Xuelong Zhou & Peng Tan

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  1. Liang An
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Correspondence to Tianshou Zhao.

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An, L., Zhao, T., Yan, X. et al. The dual role of hydrogen peroxide in fuel cells. Sci. Bull. 60, 55–64 (2015). https://doi.org/10.1007/s11434-014-0694-7

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