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FeP nanoparticles derived from metal-organic frameworks/GO as high-performance anode material for lithium ion batteries

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Abstract

Double carbon coated FeP composite (FeP@NC@rGO) was in situ fabricated via the phosphorization process of the as-prepared Prussian blue@graphene oxide (PB@GO) precursor. The FeP nanocrystals were successfully embedded in the nitrogen-doped porous carbon matrix. When used as the anode for lithium ion batteries (LIBs), the FeP@NC@rGO anode shows superior lithium storage properties, delivering a high specific capacity of 830 mA h g−1 after 100 cycles at 100 mA g−1 and excellent rate capability of 359 mA h g−1 at 5 A g−1. The outstanding performance mainly ascribes to the synergistic effect of the double carbon coating and porous structure design. The introduction of porous carbon and graphene coating on FeP nanoparticles greatly enhance the electronic conductivity of the active material and well accommodates the large volume variation of FeP during the cycling process.

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Acknowledgements

This work was supported by the National Key R&D Program of China (2016YFB0100305), the National Natural Science Foundation of China (51622210), and the Fundamental Research Funds for the Central Universities (WK3430000004).

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Authors and Affiliations

  1. Key Laboratory of Materials for Energy Conversion, Chinese Academy of Sciences (CAS), Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, 230026, China

    Man Gao, Xiaowu Liu, Hai Yang & Yan Yu

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  1. Man Gao
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  2. Xiaowu Liu
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  3. Hai Yang
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  4. Yan Yu
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Corresponding author

Correspondence to Yan Yu.

Electronic supplementary material

11426_2018_9278_MOESM1_ESM.docx

FeP Nanoparticles Derived from Metal-Organic Frameworks/GO and Phosphorization as High-Performance Anode Material for Lithium Ion Batteries

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Gao, M., Liu, X., Yang, H. et al. FeP nanoparticles derived from metal-organic frameworks/GO as high-performance anode material for lithium ion batteries. Sci. China Chem. 61, 1151–1158 (2018). https://doi.org/10.1007/s11426-018-9278-5

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  • DOI: https://doi.org/10.1007/s11426-018-9278-5

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