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Two highly porous single-crystalline zirconium-based metal-organic frameworks

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  • Special Topic ∙ Metal-Organic Frameworks (MOFs)
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Abstract

Herein we report two highly porous Zr-based metal-organic frameworks (MOFs, 1 and 2) constructed by the truncated octahedral secondary building unit (SBU) of Zr6O4(OH)4(CO2)12 and the organic linear ligand of 4,4'-stilbenedicarboxylic acid (H2sbdc) or 4,4'-azobenezenedicarboxylic acid (H2abdc). Both Zr-based MOFs are obtained as single crystals of suitable size for single-crystal X-ray diffraction analysis. Furthermore, these two Zr-based MOFs have been fully characterized by powder X-ray diffraction (PXRD) studies, thermogravimetric analysis (TGA), infrared spectroscopy (IR) and gas adsorption analysis. In particular, their CO2 gas adsorption behaviors have been investigated and discussed.

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Authors and Affiliations

  1. Department of Chemistry, University of South Florida, Florida, 33620, USA

    Wen-Yang Gao, Timmy Thiounn, Lukasz Wojtas & Shengqian Ma

  2. ChemMatCARS, Center for Advanced Radiation Sources, University of Chicago, Chicago, Illinois, 60439, USA

    Yu-Sheng Chen

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  1. Wen-Yang Gao
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  2. Timmy Thiounn
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  3. Lukasz Wojtas
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  4. Yu-Sheng Chen
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  5. Shengqian Ma
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Correspondence to Shengqian Ma.

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Gao, WY., Thiounn, T., Wojtas, L. et al. Two highly porous single-crystalline zirconium-based metal-organic frameworks. Sci. China Chem. 59, 980–983 (2016). https://doi.org/10.1007/s11426-016-0071-8

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  • DOI: https://doi.org/10.1007/s11426-016-0071-8

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