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Application of named reactions in polymer synthesis

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  • SPECIAL TOPIC Progress in Synthetic Polymer Chemistry
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Abstract

In recent years, with the rapid development of polymer science, the application of classical named reactions has transferred from small-molecule compounds to polymers. The versatility of named reactions in terms of monomer selection, solvent envi-ronment,reaction temperature, and post-modification permits the synthesis of sophisticated macromolecular structures under conditions where other reaction processes will not operate. In this review, we divided the named reactions employed in polymer-chain synthesis into three types: transition metal-catalyzed cross-coupling reactions, metal-free cross-coupling reactions,and multi-components reactions. Thus, we focused our discussion on the progress in the utilization of these named reactionsin polymer synthesis

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Authors and Affiliations

  1. Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Chinese Academy of Sciences; Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, China

    Xue Jiang, Chun Feng, Guolin Lu & Xiaoyu Huang

  2. State Key Laboratory of Molecular Engineering of Polymers; Department of Macromolecular Science, Fudan University, Shanghai, 200433, China

    Guolin Lu

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  1. Xue Jiang
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  4. Xiaoyu Huang
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Correspondence to Chun Feng or Xiaoyu Huang.

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Jiang, X., Feng, C., Lu, G. et al. Application of named reactions in polymer synthesis. Sci. China Chem. 58, 1695–1709 (2015). https://doi.org/10.1007/s11426-015-5447-1

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