Science China Chemistry

, Volume 55, Issue 6, pp 910–913

Solvothermal preparation of iron phosphonate cages

Communications Special Topic · Molecular Magnetism

DOI: 10.1007/s11426-012-4571-4

Cite this article as:
Zheng, Y. & Winpenny, R.E.P. Sci. China Chem. (2012) 55: 910. doi:10.1007/s11426-012-4571-4

Abstract

Three new iron(III) phosphonate cage-like complexes with [Fe4], [Fe9] and [Fe14] cores have been synthesized by solvothermal reaction with various starting materials. Magnetic studies show overall antiferromagnetic interaction presented in these cages.

Keywords

polynuclear iron coordination phosphonate magnetic properties 

Copyright information

© Science China Press and Springer-Verlag Berlin Heidelberg 2012

Authors and Affiliations

  1. 1.School of ChemistryUniversity of ManchesterManchesterUK
  2. 2.Center for Applied Chemical Research, Frontier Institute of Science and TechnologyXi’an Jiaotong UniversityXi’anChina
  3. 3.The Photon Science InstituteUniversity of ManchesterManchesterUK