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Modeling of trihalomethanes (THMs) in drinking water supplies: a case study of eastern part of India

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Abstract

This study aimed at developing a model for predicting the formation of trihalomethanes (THMs) in drinking water supplies. Monitoring of THMs in five major water treatment plants situated in the Eastern part of India revealed high concentration of THMs (231–484 μg l−1). Chloroform was predominant, contributing 87–98.9 % to total THMs. Seasonal variation in THMs levels dictated that the concentration were higher in autumn than other seasons. Linear regression analysis of data indicated that TOC is the major organic precursors for THMs formation followed by DOC and UV254. Linear and non-linear predictive models were developed using SPSS software version 16.0. Validation results indicated that there is no significant difference in the predictive and observed values of THMs. Linear model performed better than non-linear one in terms of percentage prediction errors. The model developed were site specific and the predictive capabilities in the distribution systems vary with different environmental conditions.

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References

  • Abdullah MP, Yew CH, Ramli MSB (2003) Formation, modeling and validation of trihalomethanes (THM) in Malaysian drinking water: a case study in the districts of Tampin, Negeri Sembilan and Sabak Bernam, Selangor, Malaysia. Water Res 37:4637–4644

    Article  CAS  Google Scholar 

  • Amy GL, Tan L, Davis MK (1991) The effects of ozonation and activated carbon adsorption on trihalomethane speciation. Water Res 25(2):191–202

    Article  CAS  Google Scholar 

  • APHA (2012) Standard methods for the examination of water and wastewaters (22nd edn.). Washington, DC: APHA, AWWA, WEF

  • Arora H, LeChevallier MW, Dixon KL (1997) DBP occurrence survey. J Am Water Works Assoc 89(6):60–68

    CAS  Google Scholar 

  • Ates N, Kitis M, Yetis U (2007) Formation of chlorination by-products in waters with low SUVA—correlations with SUVA and differential UV spectroscopy. Water Res 41:4139–4148

    Article  CAS  Google Scholar 

  • Babcock D, Singer PC (1979) Chlorination and coagulation of humic and fulvic acids. J Am Water Works Assoc 71:149–152

    CAS  Google Scholar 

  • Biswas P, Lu C, Clark MR (1993) A model for chlorine concentration decay in pipes. Water Res 27(12):1715–1724

    Article  CAS  Google Scholar 

  • Bixiong Y, Wuyi W, Linsheng Y, Jianrong W, Xueli E (2011) Formation and modeling of disinfection by-products in drinking water of six cities in China. J Environ Monit 13:1271–1275

    Article  Google Scholar 

  • Chang EE, Chiang PC, Ko YW, Lan WH (2001) Characteristics of organic precursors and their relationship with disinfection by-products. Chemosphere 44:1231–1236

    Article  CAS  Google Scholar 

  • Chowdhury S, Champagne P (2008) An investigation on parameters for modeling THMs formation. Global NEST J 1:80–91

    Google Scholar 

  • Chowdhury S, Champagne P, McLellan PJ (2009) Models for predicting disinfection byproduct (DBP) formation in drinking waters: a chronological review. Sci Total Environ 407:4189–4206

    Article  CAS  Google Scholar 

  • Chowdhury S, Rodriguez M, Sadiq R (2011) Disinfection byproducts in Canadian provinces: associated cancer risks and associated medical expenses. J Hazard Mater 187:574–584

    Article  CAS  Google Scholar 

  • Croue JP, Gorshin GV, Leenheer JA, Benjamin MM (1998) Isolation, fractionation and characterization of natural organic matter in drinking water, AWWA RF Report

  • Di Cristo C, Esposito G, Leopardi A (2013) Modelling trihalomethanes formation in water supply systems. Environ Technol 34(1):61–70

    Article  Google Scholar 

  • Edzwald JK, Becker WC, Wattier KL (1985) Surrogate parameters for monitoring organic matter and THM precursors. J Am Water Works Assoc 77(4):122–132

    CAS  Google Scholar 

  • El-Shahat MF, Abdel-Halim SH, Hassan GA (2001) Factors influencing the formation of trihalomethanes in drinking water treatment plants. Environ Contam Toxicol 67:549–553

    Article  CAS  Google Scholar 

  • Fayad NM, Tawabini B (1991) Survey of Saudi Arabian drinking water for trihalomethanes. Bull Environ Contam Toxicol 46:305–312

    Article  CAS  Google Scholar 

  • Garcia-Villanova J, Garcia C, Gomez A, Garcia MP, Ardanuy R (1997) Formation, evolution and modelling of trihalomethanes in the drinking water of a town: II. In the distribution system. Water Res 31:1405–1413

    Article  CAS  Google Scholar 

  • Golfinopoulos SK, Arhonditsis GB (2002) Multiple regression models: a methodology for evaluating trihalomethane concentrations in drinking water from raw water characteristics. Chemosphere 47:107–1018

    Article  Google Scholar 

  • Golfinopoulos SK, Nikolaou AD (2005) Survey of disinfection by-products in drinking water in Athens, Greece. Desalination 176(1-3):13–24

  • Golfinopoulos SK, Xilourgidis K, Kostopoulou N, Lekkas TD (1998) Use of a multiple regression model for predicting trihalomethane formation. Water Res 32:2821–2829

    Article  CAS  Google Scholar 

  • Hasan A, Thacker NP, Bassin J (2010) Trihalomethane formation potential in treated water supplies in urban metro city. Environ Monit Assess 168(1-4):489–97

    Article  CAS  Google Scholar 

  • Hassani AH, Jafari MA, Torabifar B (2010) Trihalomethanes concentration in different components of water treatment plant and water distribution system in the north of Iran. Int J Environ Res 4(4):887–892

    CAS  Google Scholar 

  • Health Canada (1995) A national survey of disinfection by products in Canadian drinking water (95-EHD-197), Environmental Health Directorate, Ottawa, Ontario

  • Hellur-Grossman L, Manka J, Lamoni-Relis B, Rebhun M (2001) THM, haloacetic acids and other organic DBPs formation in disinfection of bromide rich Sea of Galilee (Lake Kinneret) water. Water Sci Technol Water Supply 1(2):259–266

    Google Scholar 

  • Imo TS, Oomori T, Toshihiko M, Tamaki F (2007) The comparative study of trihalomethanes in drinking water. Int J Environ Sci Technol 4(4):421–426

    Article  CAS  Google Scholar 

  • Kim J (2009) Fate of THMs and HAAs in low TOC surface water. Environ Res 109:158–165

    Article  CAS  Google Scholar 

  • Kim J, Chung Y, Shin D, Kim M, Lee Y, Leed D (2002) Chlorination by-products in surface water treatment process. Desalination 151:1–9

    Article  Google Scholar 

  • Krasner SW (1999) Chemistry of disinfection by-products formation on formation and control of disinfection by-products in drinking water (Chapter 2). AWWA

  • Lebel GL, Williams DT (1995) Difference in chloroform levels from drinking water samples analysed using various sampling and analytical techniques. Int J Environ Anal Chem 60:213–220

  • Lee L, Lu C, Kung S-L (2004) Spatial diversity of chlorine residual in drinking water distribution system. J Environ Eng ASCE 130(11):1263–1268

    Article  CAS  Google Scholar 

  • Liang L, Singer PC (2003) Factors influencing the formation and relative distribution of haloacetic acids and trihalomethanes in drinking water. Environ Sci Technol 37(13):2920–2928

    Article  CAS  Google Scholar 

  • McGuire MJ, Meadow RG (1988) AWWARF trihalomethane survey. J Am Water Works Assoc 80:61–68

    CAS  Google Scholar 

  • Mishra ND, Dixit SC, Srivastava HC (2012) Evaluation of trihalomethane formation potential due to anthropogenic sources in the ground water of Kanpur. Journal of Chemistry 9(2):693–696

    CAS  Google Scholar 

  • Muller U (1998) THM in distribution system. Water Supply 16(3/4):121–131

    CAS  Google Scholar 

  • Nikolaou AD, Golfinopoulo SK, Lekkas TD, Arhonditsis GB (2004) Factors affecting the formation of organic by-products during water chlorination: a bench-scale study. Water Air and Soil Poll 159:357–371

    Article  CAS  Google Scholar 

  • Pan Y, Zhang X (2013) Four groups of new aromatic halogenated disinfection byproducts: effect of bromide concentration on their formation and speciation in chlorinated drinking water. Environ Sci Technol 47(3):1265–1273

    CAS  Google Scholar 

  • Pieri P, Andra SS, Charisiadis P, Demetriou G, Zambakides N, Makris KC (2014) Variability of tap water residual chlorine and microbial counts at spatially resolved points of use. Environ Eng Sci 31(4):193–201

    Article  CAS  Google Scholar 

  • Rajan S, Azariah J, Bauer U (1990) Trihalomethane levels in Madras public drinking water supply system and its impact on public health. Zentralbl Hyg Umwletmed 189:312–32

    CAS  Google Scholar 

  • Rathbun RE (1996) Regression equations for disinfection by-products for the Mississippi, Ohio and Missouri Rivers. Sci Total Environ 191:235–244

    Article  CAS  Google Scholar 

  • Richardson SD (1998) Encyclopedia of environmental analysis and remediation, Wiley New York, 1398-1421

  • Roccaro P, Korshin GV, Cook D, Chow CWK, Drikas M (2014) Effects of pH on the speciation coefficients in models of bromide influence on the formation of trihalomethanes and haloacetic acids. Water Res 62(117-1):26

    Google Scholar 

  • Rodriguez MJ, Vinette Y, Serodes JB, Bouchard C (2003) Trihalomethanes in drinking water of greater Quebec region (Canada): occurrence, variations and modelling. Environ Monit Assess 89:69–93

    Article  CAS  Google Scholar 

  • Sadallah H (2014) Effectiveness of water supply disinfection system in Um Al- Nasser village as a marginal rural community. M Sc Thesis, University of Gaza

  • Scheili A, Rodriguez MJ, Sadiq R (2015) Seasonal and spatial variations of source and drinking water quality in small municipal systems of two Canadian regions. Sci Total Environ 508(1):514–524

    Article  CAS  Google Scholar 

  • Simpson KL, Hayes KP (1998) Drinking water disinfection by-products: an Australian perspectives. Water Res 32:1522–1528

    Article  CAS  Google Scholar 

  • Singer PC, Reckhow DA (1999) Chemical oxidation, in: R.D Letterman (Ed.), Water quality and treatment, (5th Edition), American Water Works Association, McGraw- Hill, New York, NY.

  • Stevens AA, Slocum CJ, Seeger DR, Robert GG (1976) Chlorination of organics in drinking water. J Am Water Works Assoc 68:615–620

    CAS  Google Scholar 

  • Summerhayes RJ, Morgan GG, Lincoln D, Edwards HP, Earnes A, Rahman Md B, Byleveld P, Cowie CT, Beard JR (2011) Spatio-temporal variation in trihalomethanes in New South Wales. Water Res 45:5715–5726

    Article  CAS  Google Scholar 

  • Sung W, Matthews BR, O’Day DK, Horrigan K (2000) Modeling DBP formation. J Am Water Works Assoc 92:53–63

    CAS  Google Scholar 

  • Trang VN, Phuong LD, Dan NP, Thanh BX, Visvanathan C (2012) Assessment on the trihalomethanes formation potential of Tan Hiep Water Treatment Plant. J Water Sustain 2(1):43–53

    CAS  Google Scholar 

  • Trussell AR, Umphries MD (1978) The formation of trihalomethanes. J Am Water Works Assoc 70:604–12

    CAS  Google Scholar 

  • USEPA (1995) Method 551. Determination of chlorinated disinfection by-products and chlorinated solvents in drinking water by liquid–liquid extraction and gas chromatography with electron-capture detection. Environmental Monitoring Systems Laboratory, Office of Research and Development, US Environmental Protection Agency, Cincinnati, Ohio

  • Uyak V, Ozdemir K, Toroz I (2007) Multiple linear regression modeling of disinfection by-products formation in Istanbul drinking water reservoirs. Sci Total Environ 378:269–280

    Article  CAS  Google Scholar 

  • Wei J, Ye B, Wang W, Tao J, Yang L, Hang Z (2010) Spatial and temporal evaluations of disinfection by-products in drinking water distribution systems in Beijing, China. Sci Total Environ 408:4600–4606

    Article  CAS  Google Scholar 

  • Westerhoff P, Debroux J, Amy GL, Gatel D, Mary V, Cavard J (2000) Applying DBP models to full-scale plants. J Am Water Works Assoc 92(3):89–102

    CAS  Google Scholar 

  • Williams DT, LeBel GL, Benoit FM (1995) A national survey of chlorinated disinfection by-products in Canadian drinking water. Health Canada, Ottawa

  • Won G, Kline TR, LeJeune JT (2013) Spatial-temporal variations of microbial water quality in surface reservoirs and canals used for irrigation. Agric Water Manag 116(1):73–78

    Article  Google Scholar 

  • Ye B, Wang W, Yang L, Wei J, Xueli E (2009) Factors influencing disinfection by-products formation in drinking water of six cities in China. J Hazard Mater 171:147–152

    Article  CAS  Google Scholar 

  • Zhang J, Yu J, Wei A, Juan L, Wang Y, Chen Y, Jia T, Min Y (2011) Characterization of disinfection byproduct formation potential in 13 source waters in China. J Environ Sci 23(2):183–188

    Article  CAS  Google Scholar 

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Acknowledgement

The authors thank the financial support from Indian School of Mines, Dhanbad, under Junior Research Fellowship scheme funded by Ministry of Human Resource Development (MHRD), Government of India, New Delhi, for carrying out the this study.

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Correspondence to S. K. Gupta.

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Responsible editor: Michael Matthies

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Kumari, M., Gupta, S.K. Modeling of trihalomethanes (THMs) in drinking water supplies: a case study of eastern part of India. Environ Sci Pollut Res 22, 12615–12623 (2015). https://doi.org/10.1007/s11356-015-4553-0

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