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Fundamental Investigations of Enantioselective Heterogeneous Catalysis

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Abstract

Enantioselective catalysis is an increasingly important method of providing enantiomeric compounds for the pharmaceutical and agrochemical industries. To date, heterogeneous catalysts have failed to match the industrial impact achieved by homogeneous systems. One successful approach to the creation of heterogeneous enantioselective catalysts has involved the modification of conventional metal particle catalysts by the adsorption of chiral molecules. This article examines the contribution of effects such as chiral recognition and amplification to these types of system and how insight provided by surface science model studies may be exploited in the design of more effective catalysts.

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Acknowledgments

KEW, TEJ and AGT acknowledge financial support from the Engineering and Physical Sciences Research Council. We are very grateful to Professor Neville Richardson for access to his STM/RAIRS instrument.

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Authors and Affiliations

  1. EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews, Fife, KY16 9ST, UK

    Christopher J. Baddeley, Timothy E. Jones, Aoife G. Trant & Karen E. Wilson

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  1. Christopher J. Baddeley
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  2. Timothy E. Jones
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  3. Aoife G. Trant
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  4. Karen E. Wilson
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Correspondence to Christopher J. Baddeley.

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Baddeley, C.J., Jones, T.E., Trant, A.G. et al. Fundamental Investigations of Enantioselective Heterogeneous Catalysis. Top Catal 54, 1348–1356 (2011). https://doi.org/10.1007/s11244-011-9761-3

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